Skip to main content

Surfactant/foam process for improved efficiency of aquifer remediation

  • Colloidal Systems In Environmental Science
  • Conference paper
  • First Online:
Structure, Dynamics and Properties of Disperse Colloidal Systems

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 111))

Abstract

Results of laboratory studies and preliminary results of a field demonstration are presented for a surfactant/foam process for remediation of ground water aquifers contaminated with organic liquid contaminants, especially chlorinated solvents. Injection of air with the surfactant solution generates foam in zones of high permeability or hydraulic conductivity. As the foam has a high resistance to flow of liquid, surfactant solution is diverted to zones of low permeability, thereby improving sweep efficiency of the process. This behavior was confirmed by laboratory experiments using a two-dimensional model packed with two layers of sands having different permeabilities. These experiments utilized sodium dihexyl sulfosuccinate as the surfactant at its optimal salinity with trichloroethylene (TCE) as a model contaminant. The same surfactant was used in the field at a site at Hill Air Force Base in Utah which had a TCE-rich contaminant. The surfactant/foam process reduced the amount of this contaminant in a line-drive pattern about 6.1 m long to a very low average saturation of 0.03%.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Pankow J, Cherry J (1996) Dense Chlorinated Solvents, Waterloo Press, Portland, OR

    Google Scholar 

  2. Fountain J, Starr R, Middleton T, Beikirch M, Taylor C, Hodge D (1996) Ground Water 34:910–916

    Article  CAS  Google Scholar 

  3. Pennell K, Pope G, Abriola L (1996) Env Sci Technol 30:1328–1335

    Article  CAS  Google Scholar 

  4. Miller C, Qutubuddin S (1987) In: Eicke H, Parfitt G (eds) Interfacial Phenomena in Apolar Systems. Marcel Dekker, New York, pp 117–185

    Google Scholar 

  5. Chambers T, Radke C (1991) In: Morrow N (ed) Interfacial Phenomena in Petroleum Recovery. Marcel Dekker, New York, pp 191–255

    Google Scholar 

  6. Hirasaki G (1989) J Petrol Technol 41:449–456

    CAS  Google Scholar 

  7. Rossen W (1996) In: Prud'homme R, Khan S (eds) Foams. Marcel Dekker, New York, pp 413–464

    Google Scholar 

  8. Baran J, Pope G, Wade W, Weerasooriya V, Yapa A (1994) Env Sci Technol 28:1361–1366

    Article  CAS  Google Scholar 

  9. Szafranski R (1997) Laboratory Development of the Surfactant/Foam Process for Aquifer Remediation. PhD Thesis, Rice University

    Google Scholar 

  10. Bourrel M, Schechter R (1988) Microemulsions and Related Systems. Marcel Dekker, New York

    Google Scholar 

  11. Miller C, Ghosh O, Benton W (1986) Colloids and Surfaces 19:197–223

    Article  CAS  Google Scholar 

  12. Benton W, Baijal S, Ghosh O, Qutubuddin S, Miller C (1987) SPE Res Eng 2:664–670

    CAS  Google Scholar 

  13. Hirasaki G (1982) SPEJ 22:181–192

    CAS  Google Scholar 

  14. Hirasaki G, Miller C, Szafranski R, Lawson J, Akiya N (1997) SPE Preprint 37257 presented at Intl Symp Oilfield Chem, Houston

    Google Scholar 

  15. Hirasaki G, Miller C, Szafranski R, Tanzil D, Lawson J, Meinardus H, Jin M, Londergan J, Jackson R (1997) SPE Preprint 39292 presented at Ann Tech Conf, San Antonio

    Google Scholar 

  16. Jin M, Delshad M, Dwarakanath V, McKinney D, Pope G, Sephernoori K, Tilburg C, Jackson R (1995) Water Resour Res 31:1201–1211

    Article  CAS  Google Scholar 

  17. Brown C, Delshad M, Dwarakanath V, Jackson R, Londergan J, Meinardus H, McKinney D, Oolman T, Pope G (1998) Demonstration of surfactant flooding of an alluvial aquifer contaminated with DNAPL, to appear in ACS Symp Ser

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Heinz Rehage Gerhard Peschel

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

About this paper

Cite this paper

Szafranski, R. et al. (1998). Surfactant/foam process for improved efficiency of aquifer remediation. In: Rehage, H., Peschel, G. (eds) Structure, Dynamics and Properties of Disperse Colloidal Systems. Progress in Colloid & Polymer Science, vol 111. Steinkopff. https://doi.org/10.1007/BFb0118126

Download citation

  • DOI: https://doi.org/10.1007/BFb0118126

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1118-7

  • Online ISBN: 978-3-7985-1652-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics