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The quasi-static modulus of partially crystallized copolymers of ethylene at small strains

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Physik der Duroplaste und anderer Polymerer

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 64))

Abstract

Transferring the basic principles of the theory of rubber elasticitiy of a Gaussian network, an analogous description of crystal-networks is presented. This treatment is based on defining equivalent subsystems of deformation the properties of which are related to basic parameters of the microstructure in the partially crystallized systems as well as to essential parameters of the chain structure. The quasi static moduli of various random copolymers of ethylene can be computed quantitatively dependent on the temperature employing also a known thermodynamic theory of melting of such polymer systems. The discussion of the results yields an interesting classification of the deformation mechanism at small strains in partially crystallized polymer systems with different degrees of crystallinity.

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Authors and Affiliations

  1. University of Concepción, Concepción, Chile

    H. -G. Kilian & D. Klattenhoff

  2. Abetilung Experimentelle Physik I, Universität Ulm Oberer Eselsberg, D-7900, Ulm/Donau

    H. -G. Kilian & D. Klattenhoff

Authors
  1. H. -G. Kilian
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  2. D. Klattenhoff
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Editor information

E. W. Fischer F. Horst Müller R. Bonart

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© 1978 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Kilian, H.G., Klattenhoff, D. (1978). The quasi-static modulus of partially crystallized copolymers of ethylene at small strains. In: Fischer, E.W., Müller, F.H., Bonart, R. (eds) Physik der Duroplaste und anderer Polymerer. Progress in Colloid & Polymer Science, vol 64. Steinkopff. https://doi.org/10.1007/BFb0117537

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  • DOI: https://doi.org/10.1007/BFb0117537

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1806-3

  • Online ISBN: 978-3-7985-1807-0

  • eBook Packages: Springer Book Archive

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