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The one-dimensional synthesis of the small-angle scattering pattern of high-density polyethylene

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Physik der Duroplaste und anderer Polymerer

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 64))

Abstract

Adhering to the one-dimensional characterization of small angle X-ray pattern of melt-crystallized high density polyethylene with the aid of the one-dimensional paracrystalline theory we arrive at the model of a heterogeneous microstructure represented by a cluster ensemble with locally fluctuating average distances of neighbouring crystal lamellae. These characteristics can be verified from stained electron-micrographs the rotated light-diffraction pattern of which are in excellent agreement with the SAXS-pattern. Moreover, the slope of caloric measurements (c p (T)-curves) on well-annealed HDPE samples can quantitatively be computed employing the crystal-thickness distribution gained from the synthesis of the SAXS-pattern.

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E. W. Fischer F. Horst Müller R. Bonart

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© 1978 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Meyer, H., Kilian, H.G. (1978). The one-dimensional synthesis of the small-angle scattering pattern of high-density polyethylene. In: Fischer, E.W., Müller, F.H., Bonart, R. (eds) Physik der Duroplaste und anderer Polymerer. Progress in Colloid & Polymer Science, vol 64. Steinkopff. https://doi.org/10.1007/BFb0117517

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  • DOI: https://doi.org/10.1007/BFb0117517

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1806-3

  • Online ISBN: 978-3-7985-1807-0

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