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Particle interactions in colloidal dispersions of PMMA-latex in benzene

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Book cover Mechanisches Verhalten von Polymeren Wechselwirkung in Polymeren bzw. kolloiden Systemen

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 67))

Abstract

The preparation of monodispers crosslinked PMMA-latex by aqueous emulsion polymerization is described. Light scattering of these particles in benzene as a function of scattering angle showed structure formation at higher latex concentrations. The results are discussed in terms of the structure function, S(K), and are compared with liquid state theory for a hard sphere repulsion. Viscosity and sedimentation experiments as a function of concentration gave independently information on the swelling and type of interaction of these microgel particles.

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References

  1. Brown, J. C., P. N. Pusey, J. W. Goodwin, and R. H. Ottewill, J. Phys. A: Math. Gen. 8, 664 (1975).

    Article  CAS  Google Scholar 

  2. Van Megen, W. and I. Snook, J. Chem. Phys. 66, 813 (1977).

    Article  Google Scholar 

  3. Schaefer, D., J. Chem. Phys. 66, 3980 (1977).

    Article  CAS  Google Scholar 

  4. Hiltner, P. A. and I. M. Krieger, J. Phys. Chem. 73, 2386 (1969).

    Article  CAS  Google Scholar 

  5. Takano, K. and S. Hachisu, J. Chem. Phys. 67, 2604 (1977).

    Article  CAS  Google Scholar 

  6. Williams, R., R. S. Crandall, and P. J. Wojtowicz, Phys. Rev. Letters 37, 348 (1976).

    Article  Google Scholar 

  7. Ottewill, R. H., Progr. Colloid Polymer Sci. 59, 14 (1976).

    Article  CAS  Google Scholar 

  8. Hiltner, P. A., Y. S. Papir, and I. M. Krieger, J. Phys. Chem. 75, 1881 (1971).

    Article  CAS  Google Scholar 

  9. Kose, A. and S. Hachisu, J. Colloid Interface Sci. 46, 460 (1974).

    Article  CAS  Google Scholar 

  10. Vincent, B., J. Colloid Interface Sci. 68, 190 (1979).

    Article  Google Scholar 

  11. Agterof, W. G. M., J. A. J. van Zomeren, and A. Vrij, Chem. Phys. Letters 43, 363 (1976).

    Article  CAS  Google Scholar 

  12. Caljé, A. A., W. G. M. Agterof, and A. Vrij, Micellization, Solubilization and Microemulsions, ed. K. L. Mittal, vol. 2, p.779 (Plenum Press, New York 1977).

    Google Scholar 

  13. De Hek, H. and A. Vrij, J. Colloid Interface Sci. 70, 592 (1979).

    Article  Google Scholar 

  14. Van Helden, A. K. and A. Vrij (to be published).

    Google Scholar 

  15. Pathmamanoharan, C., E. A. Nieuwenhuis, and A. Vrij, Colloid & Polymer Sci. 257, 1005 (1979).

    Article  CAS  Google Scholar 

  16. Fijnaut, H. M., C. Pathmamanoharan, E. A. Nieuwenhuis, and A. Vrij, Chem. Phys. Letters 59, 351 (1978).

    Article  CAS  Google Scholar 

  17. Vrij, A., E. A. Nieuwenhuis, H. M. Fijnaut, and W. G. M. Agterof, Faraday Disc. 65, 101 (1978).

    Article  CAS  Google Scholar 

  18. McMillan, W. G. and J. E. Mayer, J. Chem. Phys. 13, 276 (1945).

    Article  CAS  Google Scholar 

  19. Kirkwood, J. G. and F. P. Buff, J. Chem. Phys. 19, 774 (1954).

    Article  Google Scholar 

  20. Barker, J. A. and D. Henderson, Rev. Mod. Phys. 48, 587 (1976).

    Article  CAS  Google Scholar 

  21. Fitch, R. M. and C. H. Tsai, Polymer Colloids, p. 103, 103, ed. R. M. Fitch (Plenum Press, New York 1971).

    Google Scholar 

  22. Kotera, A., K. Furusuwa, and Y. Takeda, Kolloid-Z. u. Z. Polymere 239, 677 (1970).

    Article  CAS  Google Scholar 

  23. Ono, H. and H. Saeki, Colloid & Polymer Sci. 253, 744 (1975).

    Article  CAS  Google Scholar 

  24. Berne, B. J. and R. Pecora, Dynamic light scattering (Wiley, New York 1976).

    Google Scholar 

  25. Van den Hul, H. J. and J. W. Vanderhoff, Polymer Colloids, p. 29, ed. R. M. Fitch (Plenum Press, New York 1971).

    Google Scholar 

  26. Shashoua, V. E. and R. G. Beaman, J. Polymer Sci. 33, 101 (1958).

    Article  CAS  Google Scholar 

  27. Riley, D. P. and G. Oster, Disc. Faraday Soc. 11, 107 (1951).

    Article  Google Scholar 

  28. Debye, P. J. W., J. Phys. Chem. 51, 18 (1947).

    Article  CAS  Google Scholar 

  29. Carnahan, N. F. and K. E. Starling, J. Chem. Phys. 51, 635 (1969).

    Article  CAS  Google Scholar 

  30. Rowe, A. J., Biopolymers 16, 2595 (1977).

    Article  CAS  Google Scholar 

  31. Batchelor, G. K., J. Fluid Mechanics 52, 245 (1972).

    Article  Google Scholar 

  32. Altenberger, A. R., J. Chem. Phys. 70, 1994 (1977).

    Article  Google Scholar 

  33. Peterson, J. M. and M. Fixman, J. Chem. Phys. 39, 2516 (1963).

    Article  CAS  Google Scholar 

  34. Puyn, C. W. and M. Fixman, J. Chem. Phys. 41, 937 (1964).

    Article  Google Scholar 

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H. Rupprecht R. Bonart F. H. Müller A. Weiss

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© 1980 Dr. Dietrich Steinkopff Verlag

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Nieuwenhuis, E.A., Pathmamanoharan, C., Vrij, A. (1980). Particle interactions in colloidal dispersions of PMMA-latex in benzene. In: Rupprecht, H., Bonart, R., Müller, F.H., Weiss, A. (eds) Mechanisches Verhalten von Polymeren Wechselwirkung in Polymeren bzw. kolloiden Systemen. Progress in Colloid & Polymer Science, vol 67. Steinkopff. https://doi.org/10.1007/BFb0117388

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  • DOI: https://doi.org/10.1007/BFb0117388

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  • Print ISBN: 978-3-7985-1812-4

  • Online ISBN: 978-3-7985-1813-1

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