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Thermodynamics of adsorption from non-aqueous solutions

  • D. H. Everett
Nichtwässerige Systeme
Part of the Progress in Colloid & Polymer Science book series (PROGCOLLOID, volume 65)

Abstract

This paper presents a review of some recent theoretical and expreimental work on adsorption from organic liquid mixtures by graphitised carbon blacks. Several relatively simple systems conform reasonably well to approximate theoretical models, but for systems involving higher alkanes and alkanols adsorbed from solution in a lower alkane, complex phenomena are observed which indicate molecular structuring of the higher molecular weight component near the surface. Some preliminary data on very dilute solutions are also reported which again show strong co-operative adsorption at low temperatures.

Keywords

Adsorption Isotherm Activity Coefficient Surface Phase Preferential Adsorption Graphitised Carbon Black 
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Copyright information

© Dr. Dietrich Steinkopff Verlag GmbH & Co. KG 1978

Authors and Affiliations

  • D. H. Everett
    • 1
  1. 1.Dept. of Physicalchemistry School of ChemistryUniversity of BristolBristolEngland

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