Skip to main content
SpringerLink
Log in
Book cover

Polymere Aspekte pp 201–210Cite as

Applications of polymer solution theory to monolayers

  • Conference paper
  • First Online:

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 58))

Abstract

A recently derived theoretical equation of state for linear polymers in monolayers is applied to experimental measurements of the dependence of surface area on surface pressure for monolayers of poly(methyl methacrylate) and polypropylene grafted with methyl acrylate, at water/air, water/n-hexane, water/toluene, and water/(petroleum ether) interfaces at 20°, 25° and 30°C. The experimental and theoretical curves are in satisfactory agreement for pressures up to those corresponding to the limiting area for stability of the monolayers. The theoretical parameters derived from the experimental data measure the molecular and intermolecular properties that determine the Gibbs free energies of the monolayers.

This is a preview of subscription content, log in via an institution.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Gabrielli, G., M. Puggelli and E. Ferroni, J. Colloid Interface Sci. 32, 242 (1970).

    Article  CAS  Google Scholar 

  2. Gabrielli, G., M. Puggelli and E. Ferroni, J. Colloid Interface Sci. 33, 133 (1970).

    Article  CAS  Google Scholar 

  3. Gabrielli, G. and M. Puggelli, J. Colloid Interface Sci. 35, 460 (1971).

    Article  CAS  Google Scholar 

  4. Singer, S. I., J. Chem. Physics 16, 872 (1948).

    Article  CAS  Google Scholar 

  5. Saraga, L. T. and I. Prigogine, Mem. Ser. Chim. Etat (Paris) 38, 109 (1953).

    Google Scholar 

  6. Davies, J. T. and J. Llopis, Proc. Roy. Soc. A227, 537 (London, 1955).

    CAS  Google Scholar 

  7. Frisch, H. L. and R. Simha, J. Chem. Physics 27, 702 (1957).

    Article  CAS  Google Scholar 

  8. Kawai, T., J. Polymer Sci. 35, 401 (1959).

    Article  CAS  Google Scholar 

  9. Motomura, K. and R. Matuura, J. Colloid Sci. 18, 12 (1963).

    Google Scholar 

  10. Huggins, M. L., J. Phys. Chem. 74, 371 (1970).

    Article  CAS  Google Scholar 

  11. Huggins, M. L., Polymer 12, 357 (1971); 13, 554 (1972).

    Article  Google Scholar 

  12. Huggins, M. L., J. Phys. Chem. 75, 1255 (1971).

    Article  CAS  Google Scholar 

  13. Huggins, M. L., Kolloid-Z. u. Z. Polymere 25, 29 (1973).

    Google Scholar 

  14. Huggins, M. L., Makromol. Chem. 87, 119 (1965).

    Article  CAS  Google Scholar 

  15. Gabrielli, G., M. Puggelli and R. Faccioli, J. Colloid Interface Sci. 37, 213 (1971).

    Article  CAS  Google Scholar 

  16. Gabrielli, G., M. Puggelli and R. Faccioli, J. Colloid Interface Sci. 41, 63 (1972).

    Article  CAS  Google Scholar 

  17. Gabrielli, G., M. Puggelli and E. Ferroni, Berichte vom VI. Internationalen Kongreß für grenzflächenaktive Stoffe, Band BII 329 (1973).

    Google Scholar 

  18. Gabrielli, G., M. Puggelli and E. Ferroni, J. Colloid Interface Sci. 47, 145 (1974).

    Article  CAS  Google Scholar 

  19. Natta, G., F. Severini, M. Pegoraro and C. Tavazzini, Makromol. Chem. 119, 201 (1968).

    Article  CAS  Google Scholar 

  20. Gabrielli, G. and M. Puggelli, J. Colloid Interface Sci. 45, 217 (1973).

    Article  CAS  Google Scholar 

  21. Crisp, D. J., J. Colloid Sci. 1, 49, 161 (1946).

    Article  CAS  Google Scholar 

  22. Isemura, T. and K. Hamaguchi, Bull. Chem. Soc. Japan 25, 49 (1952).

    Article  Google Scholar 

  23. Davies, J. T. and K. Rideal, Interfacial Phenomena, p. 246 (New York, 1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Fisica, Università di Firenze, Italia

    G. Gabrielli & E. Ferroni

  2. Arcadia Institute for Scientific Research, 135 Northridge Lane, 94062, Woodside, California, U.S.A.

    M. L. Huggins

Authors
  1. G. Gabrielli
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Ferroni
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. L. Huggins
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1975 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

About this paper

Cite this paper

Gabrielli, G., Ferroni, E., Huggins, M.L. (1975). Applications of polymer solution theory to monolayers. In: Polymere Aspekte. Progress in Colloid & Polymer Science, vol 58. Steinkopff. https://doi.org/10.1007/BFb0117142

Download citation

  • DOI: https://doi.org/10.1007/BFb0117142

  • Received:

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1796-7

  • Online ISBN: 978-3-7985-1797-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation