Abstract
We examine the relevance of the strong-fragile classification scheme for glass-forming polymeric systems using results from Brillouin and photon correlation spectroscopy. The dynamics of salt doped polypropylene oxide (PPO) have been investigated in relation to induced local structural ordering. It is accomplished by forming complexes of NaCF3SO3-PPO in which the cations act as transient cross-links between chains. The amount of cross-links depends on salt concentration and temperature. This allows for a test of the suggested relation between structural properties and some characteristics of the relaxation function such as its non-exponential time decay and non-Arrhenius temperature dependence.
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References
Angell CA (1985) In: Ngai K, Wright GB (eds) Relaxation in Compl. Systems. National Technical Information Service, U.S. Department of Commerce, Springfield, VA22161, 1
Angell CA (1988) Phys Chem Solids 49:8634
Wetton RE, James DB, Whithing W (1976) Polym Sci Polym Lett Ed 14:577; (1979) Polymer 20:187
Berthier C, Gorechi W, Minier M, Armand M, Chakagno J, Rigaud P (1983) Solid State Ionics 11:19
Papke B, Ratner M, Scriver D (1981) J Phys Chem Solids 42:493
Ratner M (1988) In: MacCallum JR, Vincent CA (eds) Polymer Electrolyte Review I, Ch. 7. Elsevier, New York
McLin MG, Angell CA (1991) J Phys Chem 95:9464
Börjesson L, Torell LM, Stevens JR (1987) Polymer 28:1803; (1987) Physica Scripta 35:692
Stevens JR, Schantz S (1988) Polymer Comm. 29:330; Wixwat W, Fu Y, Stevens JR (1991) Polymer 32:1181
Torell LM, Jacobsson P, Sidebottom D, Petersen G, Solid State Ionics, in press
Ratner M, Nitzan A (1989) Faraday Discuss Chem Soc 88:19
Olender R, Nitzan A (1992) Electrochimica Acta 37:1505
Sandahl J, Schantz S, Börjesson L, Torell LM, Stevens JR (1989) J Chem Phys 81:2
Sidebottom D, Bergman R, Börjesson L, Torell LM (1992) Phys Rev Lett 68:3587
Börjesson L (1987) Phys Rev B 36:4600
Fuchs M, Götze W, Hofacker I, Latz A (1991) J Phys: Condensed Matter 3:5047
Wang CH, Fytas G, Lilge D, DorfmÜller Th (1981) Macromolecules 14:1363
Schantz S, Sandahl J, Börjesson L, Torell LM, Stevens JR (1988) Solid State Ionics 28–30:1047
Torell LM, Angeil CA (1988) British Polymer J 20:173
Kakihana M, Schantz S, Torell LM (1990) J Chem Phys 92:6271
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© 1993 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Torell, L.M., Jacobsson, P., Sidebottom, D., Börjesson, L. (1993). Structural relaxation characteristics of glass-forming polymeric liquids subject to transisent cross-links. In: Ewen, B., Fischer, E.W., Fytas, G. (eds) Application of Scattering Methods to the Dynamics of Polymer Systems. Progress in Colloid & Polymer Science, vol 91. Steinkopff. https://doi.org/10.1007/BFb0116454
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DOI: https://doi.org/10.1007/BFb0116454
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