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Luminescence study of fluidity in the L a mesophase and liquid phase of lead(II) decanoate

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Trends in Colloid and Interface Science V

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 84))

Abstract

Fluorescence spectra indicate that pyrene is solubilized in a non-polar region in lead(II) decanoate. The local fluidity of the probe in the L a and liquid phases, monitored by excimer formation, is comparable to that of aliphatic hydrocarbons at the same temperature, and the microviscosity is an order of magnitude lower than the bulk viscosity of the soap.

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References

  1. Pownall HJ, Smith LC (1973) J Am Chem Soc 95:3136–3140

    Article  CAS  Google Scholar 

  2. Kalyanasundaraman K, Gratzel M, Thomas JK (1975) J Am Chem Soc 97:3915–3922

    Article  Google Scholar 

  3. Vauhkoren M, Sanaroli M, Somerharju P, Eisinger J (1990) Biophys J 57:291–300, and references therein

    Article  Google Scholar 

  4. See, however, Blackwell MF, Gounaris K, Barber J (1986) Biochim Biophys Acta 858:221–234

    Article  CAS  Google Scholar 

  5. Winnik MA (1987) In: Feast WJ, Munro HS (eds) Polymer Surfaces and Interfaces, Wiley, New York, 1–31

    Google Scholar 

  6. Viriot ML, Bouchy M, Donner M, André JC (1983) Photobiochem Photobiophys 5:293–306

    CAS  Google Scholar 

  7. Melnick RL, Haspel HC, Goldenberg M, Greenbaum LM, Weinstein S (1981) Biophys J 34:499–515

    Article  CAS  Google Scholar 

  8. Parthasarathy R, Labes MM (1990) LAngmuir 6:542–547

    Article  CAS  Google Scholar 

  9. Borrows HD (1990) In: Bloor DM, Wyn-Jones E (eds) Structure, Dynamics and Equilibrium Properties of Colloidal Systems, Kluwer, Dordrecht, Holland, 415–426

    Chapter  Google Scholar 

  10. Amorim da Costa AM, Burrows HD, Geraldes CFGC, Teixeira Dias JJC, Bazuin CG, Guillon D, Skoulios A, Blackmore E, Tiddy GJT, Turner DL (1986) Liquid Crystals 1:215–226

    Article  CAS  Google Scholar 

  11. Bazuin CG, Guillon D, Skoulios A, Amorim da Costa AM, Burrows HD, Geraldes CFGC, Teixeira Dias JJC, Blackmore E, Tiddy GJT (1988) Liquid Crystals 3:1655–1670

    Article  CAS  Google Scholar 

  12. Burrows HD, Geraldes CFGC, Pinheiro TJT, Harris RK, sebald A (1988) Liquid Crystals 3:853–860

    Article  CAS  Google Scholar 

  13. Feio G, Burrows HD, Geraldes CFGC, Pinheiro TJT (1991) Liquid Crystals 9:417–432

    Article  CAS  Google Scholar 

  14. Ekwunife ME Nwachukwu MU, Rinehart FP, Sime SJ (1975) J Chem Soc, Faraday Trans 1 71:1432–1446

    Article  CAS  Google Scholar 

  15. Murrell JN, Boucher EA (1982) Properties of Liquids, John Wiley, Chichester, p 117

    Google Scholar 

  16. Adeosun SO, Sime SJ (1976) Thermochim Acta 17:351–359

    Article  CAS  Google Scholar 

  17. Ellis HA (1986) Mol Cryst Liq Cryst 139:281–290

    Article  CAS  Google Scholar 

  18. Dinis CJS (1989) Licenciatura Report, Universidade de Coimbra

    Google Scholar 

  19. Dong DC, Winnik MA (1984) Can J Chem 62:2560–2565

    Article  CAS  Google Scholar 

  20. Street KW Jr, Acree WE Jr (1986) Analyst 111:1197–1201

    Article  CAS  Google Scholar 

  21. Parker CA (1968) Photoluminescence of Solutions, Elsevier, Amsterdam, pp 351–356

    Google Scholar 

  22. Weast RC (ed) (1974) Handbook of Chemistry and Physics, CRC Press, Cleveland

    Google Scholar 

  23. To facilitate comparison with literature data, densities are given in g cm−3 and viscosities in cP. 1 g cm−3=10−3 kg m−3, 1 cP=10−3 N s m−2

    Google Scholar 

  24. Kauzman W, Eyring H (1940) J Am Chem Soc 62:3113–3125

    Article  Google Scholar 

  25. Ekpe UJ, Sime SJ (1976) J Chem Soc, Faraday Trans 1 72:1144–1149

    Article  CAS  Google Scholar 

  26. Turro NJ, Aikawa M, Yekta A (1979) J Am Chem Soc 101:772–774

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Departmento de Química, Universidade de Coimbra, 3049, Coimbra, Portugal

    M. da Graça M. Miguel & H. D. Burrows

Authors
  1. M. da Graça M. Miguel
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  2. H. D. Burrows
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Editor information

M. Corti F. Mallamace

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© 1991 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Miguel, M.d.G.M., Burrows, H.D. (1991). Luminescence study of fluidity in the L a mesophase and liquid phase of lead(II) decanoate. In: Corti, M., Mallamace, F. (eds) Trends in Colloid and Interface Science V. Progress in Colloid & Polymer Science, vol 84. Steinkopff, Heidelberg. https://doi.org/10.1007/BFb0115969

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  • DOI: https://doi.org/10.1007/BFb0115969

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  • Publisher Name: Steinkopff, Heidelberg

  • Print ISBN: 978-3-662-16029-9

  • Online ISBN: 978-3-7985-1685-4

  • eBook Packages: Springer Book Archive

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