Skip to main content

Polymer-like giant micelles. An invesetigation by light scattering

  • Micelles
  • Conference paper
  • First Online:

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 84))

Abstract

We report here on a system (cetylpyridinium chlorate in brine (1 M sodium chlorate)) where giant elongated micelles from. We compare its properties to that of solutions of polymers in a good solvent. The semi-dilute regime is reached at very low concentration with a large correlation length. This situation allows to investigate, using static and dynamic light scattering, the mass distribution and the dynamics on length scales larger and smaller than the correlation length. The results obtained allow to confirm our initial hypothesis: analogy between the solutions of giant micelles and the solutions of polymers.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Tanford C (1973) The Hydrophobic Effect. Wiley, New York

    Google Scholar 

  2. Reiss-Husson F, Luzatti V (1964) J Phys Chem 68:3504

    Article  CAS  Google Scholar 

  3. Mazer N, Benedek G, Carey MC (1976) J Phys Chem 80:1075

    Article  CAS  Google Scholar 

  4. Missel P, Mazer N, Benedek G, Carey M (1983) J Phys Chem 87:1264

    Article  CAS  Google Scholar 

  5. Porte G, Appell J, Poggi Y (1980) J Phys Chem 84:3105

    Article  CAS  Google Scholar 

  6. Porte G, Appell J (1981) J Phys Chem 85:2511

    Article  CAS  Google Scholar 

  7. Appell J, Porte G, Poggi Y (1982) J Colloid Interface Sci 87:492

    Article  CAS  Google Scholar 

  8. Porte G, Appell J (1984) In: Mittal KL, Lindman B (eds) Surfactants in Solution (Plenum Press, New York) 2:1

    Google Scholar 

  9. Gomati R, Appell J, Bassereau P, Marignan J, Porte G (1987) J Phys Chem 91:6203

    Article  CAS  Google Scholar 

  10. Hoffmann H, Platz G, Ulbricht W (1981) J Phys Chem 85:3160

    Article  Google Scholar 

  11. Hoffmann H, Platz G, Rehage H, Schorr W (1982) Adv Colloid Interface Sci 17:275

    Article  CAS  Google Scholar 

  12. Candaus SJ, Hirsch E, Zana R (1984) J Phys 45:1263

    Article  Google Scholar 

  13. Candaus SJ, Hirsche E, Zana R (1985) J Colloid Interface Sci 105:521

    Article  Google Scholar 

  14. Imae T (1989) Colloid Polym Sci 267:707 and references therein

    Article  CAS  Google Scholar 

  15. Appell J, Porte G (1983) J Phys Lett 44:L-689

    Article  Google Scholar 

  16. Candaus SJ, Hirsch E, Zana R (1987) In: Safran SA, Clark NA (eds) Physics of complex and supermolecular fluids, Wiley, New York, 569

    Google Scholar 

  17. Candau SJ, Hirsch E, Zana R, Adam M (1989) J Colloid Interface Sci 122:430

    Article  Google Scholar 

  18. Marignan J, Appell J, Bassereau P, Porte G, May RP (1989) J Phys 50:3553

    Article  CAS  Google Scholar 

  19. Appell J, Bassereau P, Marignan J, Porte G (1990) In: Progr Colloid Polym Sci 81:13

    Article  CAS  Google Scholar 

  20. Appell J, Porte G (1990) Europhys Lett 12:185

    Article  CAS  Google Scholar 

  21. De Gennes PG (1979) Scaling Concepts in Polymer Physics, Cornell Univ Press

    Google Scholar 

  22. des Coizeaux J, Janninck G (1987) Les Polymères en solution (Ed. Physique, France)

    Google Scholar 

  23. Doi M, Edwards SF (1989) The theory of polymer dynamics (Clarendon Press, Oxford)

    Google Scholar 

  24. Israelachvili J, Mitchell D, Ninham B (1976) J Chem Soc Faraday Trans 2 72:525

    Google Scholar 

  25. Koppel DE (1972) J Chem Phys 57:4814

    Article  CAS  Google Scholar 

  26. Weil G, des Cloizeaux J (1979) J Phys 40:99

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

M. Corti F. Mallamace

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

About this paper

Cite this paper

Appell, J., Porte, G. (1991). Polymer-like giant micelles. An invesetigation by light scattering. In: Corti, M., Mallamace, F. (eds) Trends in Colloid and Interface Science V. Progress in Colloid & Polymer Science, vol 84. Steinkopff, Heidelberg. https://doi.org/10.1007/BFb0115931

Download citation

  • DOI: https://doi.org/10.1007/BFb0115931

  • Published:

  • Publisher Name: Steinkopff, Heidelberg

  • Print ISBN: 978-3-662-16029-9

  • Online ISBN: 978-3-7985-1685-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics