Abstract
The complex permittivity of AOT/H2O/CCl4 and AOT/H2O/n-heptane microemulsions has been measured by a frequency domain coaxial techniques in the range 0.02/20 GHz as a function of the molar ratio [H2O]/[AOT] (W). A relaxation phenomenon was observed whose behavior vs. W has been interpreted, in the dilute limit, in terms of two coexisting mechanisms: the reorientation of the whole micellar aggregate and the “free” rotational diffusion of the completely hydrated AOT ion pairs.
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© 1996 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Camardo, M., D’Angelo, M., Fioretto, D., Onori, G., Palmieri, L., Santucci, A. (1996). Dielectric relaxation of microemulsions. In: Solans, C., Infante, M.R., García-Celma, M.J. (eds) Trends in Colloid and Interface Science X. Progress in Colloid & Polymer Science, vol 100. Steinkopff. https://doi.org/10.1007/BFb0115775
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DOI: https://doi.org/10.1007/BFb0115775
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