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Interaction between ionic surfactants and soil colloids: adsorption, wetting and structural properties

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Surfactants and Colloids in the Environment

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 95))

Abstract

The adsorption of ionic surfactants on different soil components such as silica, clay minerals, and humic acids was studied. The adsorption processes were controlled by flow microcalorimetry to determine the molar adsorption enthalpies of surfactant accumulation on clay and silicate surfaces. The evaluation of adsorption results for cationic surfactants has shown different mechanisms for solids having permanent (kaolinite, illite, montmorillonite) and pH-dependent surface charges (silica gels and powders). The adsorption mechanism for surfactants on silica surfaces with pH-dependent charges has been explained in terms of the development of charges on the surfaces and their interaction with surfactant cations and micelles. The surface hydrophobicity of clay-organocomplexes was characterized by batch microcalorimetry using pure liquids. The fractal dimensions of clays and their organocomplexes were determined by SAXS. The intercalation of organic compounds in the interlamellar space of layered silicates and humates was measured by x-ray diffraction using powder samples and suspensions. The structural properties of the surfactant coated clay suspension were characterized by rheology.

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References

  1. Hough DB, Rendall HM (1983) In: Parfitt GD, Rochester CH (eds) Adsorption from Solution at the Solid/Liquid Interface, Academic Press, London pp 247–319

    Google Scholar 

  2. Rosen MJ (1989) Surfactants and Interfacial Phenomena, John Wiley & Sons, New york

    Google Scholar 

  3. Theng BKG (1974) The Chemistry of Clay-Organic Reactions, Halsted Press, John Wiley & Sons

    Google Scholar 

  4. Szántó F, Dékány I, Patzkó Á, Várkonyi B (1986) Coll Surf 18:359

    Article  Google Scholar 

  5. Dékány I, Szántó F, Weiss A, Lagaly G (1986) Ber Bunsenges Phys Chem 90:422–427

    Google Scholar 

  6. Dékány I, Szántő F, Weiss A, Lagaly G (1986) Ber Bunsenges Phys Chem 90:427–431

    Google Scholar 

  7. Dékány I, Szántó F, Nagy LG (1985) J Coll Interf Sci 103:321

    Article  Google Scholar 

  8. Dékány I, Szántó F, Nagy LG, Schay G (1983) J Coll Interf Sci 93:151

    Article  Google Scholar 

  9. Patzkó Á, Szántó F (1987) Coll Surf 25:173

    Article  Google Scholar 

  10. Patzkó Á, Dákány I (1993) Coll Surf 71:299

    Article  Google Scholar 

  11. Esumi K, Nagahama T, Meguro K (1991) Coll Surf 57:149

    Article  CAS  Google Scholar 

  12. Isfahany TM (1990) Coll Surf 51:339

    Article  Google Scholar 

  13. Gu T, Zhu BY, Rupprecht H (1992) Prog Coll Polym Sci 88:74

    Article  CAS  Google Scholar 

  14. Noll LA, Gall BL (1991) Coll Surf 54:41

    Article  CAS  Google Scholar 

  15. Backlund S, Sjöblom, Matijević E (1993) Coll Surf A 79:263

    Article  CAS  Google Scholar 

  16. Tombácz E, Varga K, Szántó F (1988) Coll Polym Sci 266:734

    Article  Google Scholar 

  17. Tombácz E, Regdon I (20–25 Sept, 1992) Humic substances as various colloidal systems, Proceedings of the 6th International Meeting of the IHSS, Monopoly (Bari) Italy, in press

    Google Scholar 

  18. Pfirrmann GL (1968) Thesis, Heidelberg

    Google Scholar 

  19. Somasundaran P, Healy TW, Fuerstenau DW (1964) J Phys Chem 68:3562

    Article  CAS  Google Scholar 

  20. Fuerstenau DW (1956) J Am Chem Soc 60:981

    CAS  Google Scholar 

  21. Kern HE, Piechocki A, Brauer U, Findenegg GH (1978) Prog Coll Polym Sci 65:118

    CAS  Google Scholar 

  22. Kern HE, Findenegg GH (1980) J Coll Interf Sci 75:346

    Article  CAS  Google Scholar 

  23. Dékány I, Zszednai Á, Király Z, László K, Nagy LG (1986) Coll Surf 19:47

    Article  Google Scholar 

  24. Dékány I, Szednai Á, Király Z, László K, Nagy LG (1987) Coll Surf 132:41

    Google Scholar 

  25. Dékány I, Ábrahám I, Nagy LG, László K (1987) Coll Surf 23:57

    Article  Google Scholar 

  26. Dékány I, Szántó F, Nagy LG (1986) J Coll Interf Sci 109:376

    Article  Google Scholar 

  27. Weiss A, Mehler A, Hofmann U (1956) Z Naturforsch 11b:431

    CAS  Google Scholar 

  28. Lagaly G, Weiss A (1971) Kolloid Z Z Polym 243:48

    Article  CAS  Google Scholar 

  29. Lagaly G, Weiss A (1971) Kolloid Z Z Polym 248:979

    Article  CAS  Google Scholar 

  30. Lagaly G, Stange H, Weiss A (1972) Kolloid Z Z Polym 250:675

    Article  CAS  Google Scholar 

  31. Lagaly G (1982) Ullmans Encyklopädie 21:366

    Google Scholar 

  32. Tombácz E, Meleg E (1990) Organic Geochemistry 15:357

    Article  Google Scholar 

  33. Reid VW, Longman GF, Heinrich E (1968) Tenside 5:90

    CAS  Google Scholar 

  34. James RO, Parks GA (1982) In: Matijević E (ed) Surface and Colloid Science, Vol 12, Characterization of Aqueous Colloids by their Electrical Double-Layer and Intrinsic Surface Chemical Properties, Plenum Publishing Corporation

    Google Scholar 

  35. Yates DE, Healy TW (1976) J Coll Interf Sci 55:9

    Article  CAS  Google Scholar 

  36. Hartley GS (1938) J Chem Soc 1968

    Google Scholar 

  37. Tanford C (1973) Formation of Micelles and Biological Membranes, The Hydrophobic Effect, John Wiley & Sons

    Google Scholar 

  38. Raltson AW, Eggenberger DN, Broome FK (1949) J Am Chem Soc 71:2145

    Article  Google Scholar 

  39. Schmidt PW (1989) In: Anvir A (ed) The Fractal Approach to Heterogeneous Chemistry, John Wiley, New York, London

    Google Scholar 

  40. Kriechbaum M, Degovics G, Titthardt I, Laggner P (1989) Prog Colloid Polym Sci 79:101

    CAS  Google Scholar 

  41. Nagy B, Bradley WF (1955) The Amer Mineral 40:885

    CAS  Google Scholar 

  42. Hofmann U, Endell K, Wilm D (1933) Z Kristallog 86:340

    CAS  Google Scholar 

  43. van Olphen H (1965) J Coll Interf Sci 20:822

    CAS  Google Scholar 

  44. Grimm RE (1953) Clay Mineralogy, McGraw-Hill Book Comp, New York

    Google Scholar 

  45. Schnitzer M (1986) In: Huang PM, Schnitzer M (eds) Binding of Humic Substances by Soil Mineral Colloids Ch 4, Interactions of Soil Minerals with Natural Organics and Microbes, SSSA Special Publication Number 17, Soil Science Society of America, Inc Madison Wisconsin USA

    Google Scholar 

  46. Theng BKG (1979) Formation and Properties of Clay-polymer Complexes Ch 12, Elsevier, Amsterdam, pp 283–326

    Google Scholar 

  47. Wershaw RL (1989) In: Everett RC, Leenheer DM, Thorn KA (eds) Humic Substances in the Suwannee River, Georgia: Interactions, Properties and Proposed Structures, US Geological Survay Open File Report 87–557, p 354

    Google Scholar 

  48. Tombácz E, Sipos S, Szántó F (1981) Agrokémia Talajtan 30:365

    Google Scholar 

  49. Shinozuka N, Lee Ch (1991) Marine Chemistry 33:229

    Article  CAS  Google Scholar 

  50. Guetzlhoff TF, Rice JA (1992) Does humic acid form a micelle?, International Conference on Organic Substances in Soils and Sediments, Lanchester, UK

    Google Scholar 

  51. Buffle J (1988) Complexation Reactions in Aquatic Systems: an Analytical Approach, Ellis Horwood Limited Publisher, Chichester

    Google Scholar 

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Authors and Affiliations

  1. Department of Colloid Chemistry, Attila József University, Aradi Vŕtanúk tere 1, 6720, Szeged, Hungary

    I. Dékány, M. Szekeres, T. Marosi, J. Balázs & E. Tombácz

Authors
  1. I. Dékány
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  2. M. Szekeres
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  3. T. Marosi
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  4. J. Balázs
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  5. E. Tombácz
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Editor information

M. J. Schwuger F. H. Haegel

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© 1994 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Dékány, I., Szekeres, M., Marosi, T., Balázs, J., Tombácz, E. (1994). Interaction between ionic surfactants and soil colloids: adsorption, wetting and structural properties. In: Schwuger, M.J., Haegel, F.H. (eds) Surfactants and Colloids in the Environment. Progress in Colloid & Polymer Science, vol 95. Steinkopff. https://doi.org/10.1007/BFb0115706

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  • DOI: https://doi.org/10.1007/BFb0115706

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0994-8

  • Online ISBN: 978-3-7985-1668-7

  • eBook Packages: Springer Book Archive

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