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TSD-α-peak and non-equilibrium processes

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Relaxation in Polymers

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 80))

Abstract

The influence of physical aging on the electrical properties of poly(vinylacetate) in the glass transition region were investigated using the thermally stimulated depolarization (TSD) technique. The position, intensity, and shape of TSD-α-peaks were studied in dependence on cooling and heating rates. Furthermore, a model for TSD measurements in the glass transition region is presented based on the phenomenological approach, as proposed by Narayanaswamy. The theoretical predictions are in qualitative agreement with experimental findings.

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References

  1. Belana J, Colomer P, Pujal M, Montserrat S (1984–1985) J Macromol Sci Phys B 23:467

    Google Scholar 

  2. Struik LCE (1978) Physical aging in amorphous polymers and other materials. Elsevier, Amsterdam

    Google Scholar 

  3. van Turnhout J (1975) Thermally Stimulated Sicharge of Polymer Electrets. Elsevier, Amsterdam, pp 33–34

    Google Scholar 

  4. van Turnhout J (1980) in: Sessler GM (ed) Electrets. Springer, Berlin, Heidelberg, New York, p 160

    Google Scholar 

  5. Schrader S, Schönhals A, Schlosser E (1987) Poster IV/124. 31. IUPAC Macromolecular Symposium, Microsymposium IV, June 30–July 4, Merseburg, GDR

    Google Scholar 

  6. Kubon U, Schilling R, Wendorff JH (1988) Colloid Polym Sci 266:123

    Article  CAS  Google Scholar 

  7. Schneider K (1984) Dissertation A, Technische Hochschule “Carl Schorlemmer” Leuna-Merseburg

    Google Scholar 

  8. Struik LCE (1980) Polymer 21:962

    Article  Google Scholar 

  9. Narayanaswamy OS (1971) J Amer Ceram Soc 54:491

    Article  CAS  Google Scholar 

  10. Sasabe H, Moynihan CT (1978) J Polym Sci. Polym Phys Ed 16:1447

    Article  CAS  Google Scholar 

  11. Tool AQ (1946) J Res Nat Bur Standards 37:73

    CAS  Google Scholar 

  12. Havriliak S, Negami S (1966) J Polym Sci C Polym Symp 14:59

    Google Scholar 

  13. Hodge IM, Berens AR (1982) Macromolecules 15:762

    Article  CAS  Google Scholar 

  14. Schlosser E, Kästner S, Friedland KJ (1981) Plaste u. Kautschuk 28:77

    CAS  Google Scholar 

  15. Schlosser E, Schönhals A (1987) Acta Polymerica 38:357

    Article  CAS  Google Scholar 

  16. Kovacs AJ, Aklonis JJ, Hutchinson JM, Ramos AR (1979) J Polym Sci Polym Phys Ed 17:1097

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Akademie der Wissenschaften der DDR Zentralinstitut für Organische Chemie, Bereich Makromolekulare Verbindungen, Rudower Chaussee 5, 1199, Berlin, DDR

    S. Schrader & A. Schönhals

Authors
  1. S. Schrader
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  2. A. Schönhals
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Editor information

M. Pietralla W. Pechhold

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© 1989 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Schrader, S., Schönhals, A. (1989). TSD-α-peak and non-equilibrium processes. In: Pietralla, M., Pechhold, W. (eds) Relaxation in Polymers. Progress in Colloid & Polymer Science, vol 80. Steinkopff. https://doi.org/10.1007/BFb0115420

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  • DOI: https://doi.org/10.1007/BFb0115420

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0832-3

  • Online ISBN: 978-3-7985-1689-2

  • eBook Packages: Springer Book Archive

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