Abstract
The effect of adsorption of macromolecular surfactants on the stability and rheological properties of latex dispersions has been investigated using adsorption isotherms and rheological measurements. Two latex particles with diameters of 427 and 867 nm were used and two macromolecular surfactants with poly(methyl methacrylate) backbone and poly(ethylene oxide) side chains were studied. It was found that the amount of adsorbed surfactant per unit area was approximately constant for both latex particles. The adsorbed amount increased with increase of temperature as a result of reduction of solvency of the medium for the chains. The steric interaction of the particles at saturation adsorption of macromolecular surfactants was investigated using rheological measurements, namely steady-state shear stress-shear rate and oscillation measurements. The adsorbed layer thickness of surfactants on the latex particle was determined as a function of volume fraction of the dispersions.
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References
Napper DH (1983) In: Polymeric Stabilization of Colloidal Dispersions. Academic Press, London, pp 28
Tadros ThF (1993) Adv Colloid Interface Sci 46:1–47
Goodwin JW, Hearn J, Ho CC, Ottewill RH (1974) Colloid Polym Sci 252:464–471
Baleux B (1972) C R Acad Sci Ser C 274:1617
Tadros ThF, Vincent B (1980) J Phys Chem 84:1575–1580
Liang W, Tadros ThF, Luckham PF (1992) J Colloid Interface Sci 153:131–139
Liang W, Tadros ThF, Luckham PF (1993) J Colloid Interface Sci 155:156–164
Tadros ThF, Liang W, Costello B, Luckham PF (1993) Colloids Surfaces A: 79:105–114
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© 1995 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Liang, W., Tadros, T.F., Bognolo, G. (1995). Adsorption of macromolecular surfactants on polystyrene latex particles and the rheology of the resulting dispersions. In: Appell, J., Porte, G. (eds) Trends in Colloid and Interface Science IX. Progress in Colloid & Polymer Science, vol 98. Steinkopff. https://doi.org/10.1007/BFb0115222
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DOI: https://doi.org/10.1007/BFb0115222
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