Abstract
The application of electron spectroscopy for chemical analysis (ESCA) to liquid phase samples is described. The surface sensitivity of this technique allows structures within the first few molecular layers to be investigated. In particular, the study of electron spectra in angular resolved mode provides a means to perform depth profiling of the surface region. Applications are presented for solutions of fatty acid salts and phase transfer catalysts. In these solutions details of the electric double layer at the surface have been investigated.
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Siegbahn HOG (1985) J Phys Chem 89:897
Holmberg S, Moberg R, Yuan ZC, Siegbahn H (1986) J Electron Spectrosc 41:337
Holmberg S, Yuan ZC, Moberg R, Siegbahn H (1988) ibid 47:27
Moberg R, Bökman F, Bohman O, Siegbahn HOG (1991) J Am Chem Soc 113:3663
Moberg R, Bökman F, Bohman O, Siegbahn HOG (1991) J Chem Phys 94:5226
Moberg R, Bökman F, Hagfeldt A, Lindquist S-E, Bohman O, Siegbahn HOG (1990) UUIP (Uppsala University Institute of Physics Report) 1218
Croxton T, McQuarrie DA, Patey GN, Torrie GM, Valleau JP (1981) Can J Chem 59:1998
Patey GN, Torrie GM (1989) Chem Scr 29A:39
Braslau A, Persham PS, Swislow G, Ocko BM, Als-Nielsen J (1988) Phys Rev A38:2457
Yun WB, Bloch JM, Rev Sci Instr 60:214 (1989)
Penfold J, Thomas RK (1989) RAL-89-057 Rutherford Appleton Lab Rep
Bökman F, Bohman O, Siegbahn HOG Surf Sci (in press)
Makosza M, Serafinowa B (1965) Rocsz Chem 39:1223
Makosza M, Wawrzyniewicz W (1969) Tetrahedron Lett 4659
Starks CM (1971) J Am Chem Soc 93:195
Brändström A (1974) Preparative Ion Pair Extraction, an Introduction to Theory and Practice. Apotekarsocieteten, Hässle Läkemedel
Gustavii K (1967) Acta Pharm Suec 4:233
Gustavii K, Schill G (1966) ibid. 3:259
Bökman F, Bohman O, Siegbahn HOG (1992) J Phys Chem 96:2278
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© 1992 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Siegbahn, H.O.G. (1992). ESCA studies of solution/vacuum interfaces. In: Sjöblom, J., Lindman, B., Stenius, P. (eds) Advances in Colloid Structures. Progress in Colloid & Polymer Science, vol 88. Steinkopff. https://doi.org/10.1007/BFb0114429
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DOI: https://doi.org/10.1007/BFb0114429
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