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Relaxation properties of polymer gels and concept of physical networks

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Gels

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 102))

Abstract

Relaxation properties of linear and network polymers are analyzed on the basis of physical networks.

Two approaches are proposed: a) taking into account the equilibrium concentration of physical crosslinks; b) taking into account the concentration of nonequilibrium physical crosslinks reflecting the nonequilibrium chain conformation and kinetics of their transformation to equilibrium ones. The modulus changing with time and/or temperature is shown to connect with integral function of molar mass distribution of polymer chains.

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Author information

Authors and Affiliations

  1. Department of Polymer and Composite Materials Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Moscow distr., 142432, Chernogolovka, Russia

    V. I. Irzhak, S. E. Varyukhin & T. F. Irzhak

Authors
  1. V. I. Irzhak
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  2. S. E. Varyukhin
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  3. T. F. Irzhak
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Editor information

M. Zrínyi

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© 1996 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Irzhak, V.I., Varyukhin, S.E., Irzhak, T.F. (1996). Relaxation properties of polymer gels and concept of physical networks. In: Zrínyi, M. (eds) Gels. Progress in Colloid & Polymer Science, vol 102. Steinkopff. https://doi.org/10.1007/BFb0114379

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  • DOI: https://doi.org/10.1007/BFb0114379

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1065-4

  • Online ISBN: 978-3-7985-1663-2

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