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Relationships of Polymeric Structure and Properties pp 75–78Cite as

ESR on polymer semiconductors of poly(tetrathiafulvalene)

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Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 78))

Abstract

Results of ESR and conductivity measurements on undoped and iodine doped poly(tetrathiafulvalenes) are reported. The ESR properties of phenylene-bridged polymeric tetrathiafulvalenes which are substituted by CH3- or C2H5-groups and poly(tetrahydroanthratetrathiafulvalene) are described. The maximum spin concentration in the doped speciality polymers is about 1020 spins per gram. The conductivity of the variously doped samples lies in the area of 10−10 to 10−4 Scm−1 at room temperature and increases with temperature, as is typical for semiconductors.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Merseburg Technical University “Carl Schorlemmer”, G.D.R.

    E. Fanghänel & Trinh vu Quang

  2. Department of Natural Sciences, Leipzig University of Technology, PSF 66, DDR-7030, Leipzig, G.D.R.

    H.-K. Roth & H. Gruber

Authors
  1. H.-K. Roth
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  2. H. Gruber
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  3. E. Fanghänel
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  4. Trinh vu Quang
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Editor information

I. Chudáček

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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Roth, HK., Gruber, H., Fanghänel, E., Quang, T.v. (1998). ESR on polymer semiconductors of poly(tetrathiafulvalene). In: Chudáček, I. (eds) Relationships of Polymeric Structure and Properties. Progress in Colloid & Polymer Science, vol 78. Steinkopff. https://doi.org/10.1007/BFb0114349

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  • DOI: https://doi.org/10.1007/BFb0114349

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0779-1

  • Online ISBN: 978-3-7985-1691-5

  • eBook Packages: Springer Book Archive

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