Dielectric and thermal relaxations in amorphous and semicrystalline poly(ethylene terephthalate)

  • C. Schick
  • J. Nedbal
Conference paper
Part of the Progress in Colloid & Polymer Science book series (PROGCOLLOID, volume 78)


Undrawn PET was crystallized using several temperature programs to get samples of different crystalline structure, as indicated by a varying thickness of the amorphous layer between neighboring lamellae. The fluctuation model proposed by Donth was used to estimate the size (1–3 nm) of the cooperative, rearranging regions connected with the glass transition in these samples. There occurs a hindrance of the cooperative motions due to the crystalline structure, as shown by the correlation between the size of the cooperative, rearranging regions and the thickness of the layer of mobile amorphous material.

The WLF-curves are shown for the amorphous and the semicrystalline PET in the frequency range from 10−15 to 108 Hz. A deviation from these curves, expected for the hindrance, is not observed.

Key words

Semicrystalline PET amorphous fraction glass transition cooperative motion characteristic length 


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  1. 1.
    Donth E (1981) Glasübergang, Akademie Verlag, BerlinGoogle Scholar
  2. 2.
    Donth E (1982) J Non-Crystalline Solids 53:325CrossRefGoogle Scholar
  3. 3.
    Schneider K, Schönhals A, Donth E (1981) Acta Polym 32:471CrossRefGoogle Scholar
  4. 4.
    Donth E (1984) Acta Polym 35:120CrossRefGoogle Scholar
  5. 5.
    Vonk CG, Pijpers AP (1985) J Polym Sci Polym Phys Ed 23:2517CrossRefGoogle Scholar
  6. 6.
    Schick C, Fabry F, Acta Polym in preparationGoogle Scholar
  7. 7.
    Varnell WD, Harrison IR, Kozminski SJ (1981) J Polym Sci Polym Phys Ed 19:1237CrossRefGoogle Scholar
  8. 8.
    Groeninckx G, Reynaers H, Bergmans H, Smets G (1980) J Polym Sci Polym Phys Ed 18:1325CrossRefGoogle Scholar
  9. 9.
    Wigger J (1986) Dissertation PH GüstrowGoogle Scholar
  10. 10.
    Schick C, Tanneberger H, Donth E (1980) Makromol Chem Rapid Commun 1:407CrossRefGoogle Scholar

Copyright information

© Dr. Dietrich Steinkopff Verlag GmbH & Co. KG 1998

Authors and Affiliations

  • C. Schick
    • 2
  • J. Nedbal
    • 1
  1. 1.Department of Polymer PhysicsCharles University, Faculty of Mathematics and PhysicsPragueCzechoslovakia
  2. 2.Sektion Mathematik/PhysikPädagogische Hochschule „Liselotte Herrmann“GüstrowG.D.R.

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