Abstract
We present further evidence in support of our Disordered Open Connected (DOC) model for microemulsion structure: small-angle X-ray scattering (SAXS) data for the systems didodecyl dimethyl ammonium bromide (DDAB)-octane-water and DDAB-dodecane-water. The models is a simple geometrical approximation to a random interface of constant mean curvature. Using only the composition of the sample and the desired curvature of the oil-water interface, we predict the SAXS spectrum, the position in the phase diagram of the conductivity anti-percolation, and the approximate boundary of the single-phase region.
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Zemb TN, Hyde ST, Derian P-J, Barnes IS, Ninham BW (1987) J Phys Chem 91:3814–3820; (1988) J Phys Chem 92:2286–2293
Niham BW, Barnes IS, Hyde ST, Derian P-J, Zmb TN (1987) Europhys Lett 4:561–568
Barnes IS, Hyde ST, Ninham BW, Derian P-J, Drifford M, Zemb TN (1988) J Phys Chem 92
Chen SJ, Evans DF, Ninham BW (1984) J Phys Chem 88:1631–1634
Blum FD, Pickup S, Niham BW, Chen SJ, Evans DF (1985) J Phys Chem 89:711; Fontell K, Ceglie A, Lindman B, Ninham BW (1986) Acta Chem Scand A40:247–256
Derian P-J et al., in preparation
Israelachvili JN, Mitchell DJ, Nihma BW (1976) J Chem Soc Farady Trans II 72:1525–1568
Scriven LE (1977) In: Mittal KL (ed) Micellization, Solubilization and Microemulsions. Vol. 2, Plenum Press, New York, pp 877–893; Hyde ST, Andersson S, Ericsson B, Larsson K (1984) Z Kristallographie 168:213
Anderson DM (1986) Ph D thesis, University of Minnesota
Barnes IS, Zemb TN (1988) J Appl Crystallogr, in press
Hyde ST (1988) submitted
Zemb TN, Charpin P (1985) J Phys 46:249–256
Teubner M, Strey R (1987) J Chem Phys 87:3195–3200
Kaler EW, Vonk CG (1987) presented at the 10th Small Angle Scattering Conference, Prague, July; to be published in J Appl Crystallogr
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© 1988 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Barnes, I.S. et al. (1988). The disordered open connected model of microemulsions. In: Degiorgio, V. (eds) Trends in Colloid and Interface Science II. Progress in Colloid & Polymer Science, vol 76. Steinkopff. https://doi.org/10.1007/BFb0114175
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DOI: https://doi.org/10.1007/BFb0114175
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