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Polymer-like lecithin reverse micelles: a multicomponent self-diffusion study

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Trends in Colloid and Interface Science XI

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 105))

Abstract

We report NMR-PFGSE self-diffusion coefficient measurements of long cylindrical reverse micelles in ternary system lecithin/cyclohexane/water. 1H-NMR linewidth values of the trimethylammonium signal, as a function of W 0, at different temperatures and lecithin concentrations, were also determined. The measured water self-diffusion coefficients, \(D_{H_2 O}\), show a strong dependence on W 0. Both \(D_{H_2 O}\) and D lec (lecithin self-diffusion) exhibit a characteristic dependence on the experimental time scale. An attempt to rationalize the data obtained in terms of different motional regimes is reported.

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Authors and Affiliations

  1. Dipartimento di Chimica, Università di Bari, Via Orabona 4, 70126, Bari, Italy

    R. Angelico, G. Colafemmina, M. Della Monica & G. Palazzo

  2. CNR, Centro Studi Chimico-Fisici sull'Interazione Luce-Materia c/o Dipartimento di Chimica, Università di Bari, 70126, Bari, Italy

    M. Giustini

  3. Facoltà di Agraria, Università del Molise, 86100, Campobasso, Italy

    A. Ceglie

Authors
  1. R. Angelico
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  2. G. Colafemmina
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  3. M. Della Monica
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  4. G. Palazzo
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  5. M. Giustini
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  6. A. Ceglie
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Editor information

J. B. Rosenholm B. Lindman P. Stenius

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© 1997 Steinkopff Verlag

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Angelico, R., Colafemmina, G., Monica, M.D., Palazzo, G., Giustini, M., Ceglie, A. (1997). Polymer-like lecithin reverse micelles: a multicomponent self-diffusion study. In: Rosenholm, J.B., Lindman, B., Stenius, P. (eds) Trends in Colloid and Interface Science XI. Progress in Colloid & Polymer Science, vol 105. Steinkopff. https://doi.org/10.1007/BFb0110985

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  • DOI: https://doi.org/10.1007/BFb0110985

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1086-9

  • Online ISBN: 978-3-7985-1660-1

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