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Film formation of latex dispersions observed with evanescent dynamic light scattering

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Optical Methods and Physics of Colloidal Dispersions

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 104))

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Abstract

We have applied evanescent dynamic light scattering (DLS) to study the film formation of polymer latex dispersions. A dynamical glass transition is observed. When the particles fuse, the scattering rate decreases. After fusion, a new fast process (τ r 1 ms) is observed, which is not present in bulk DLS data. We attribute the process to discontinuous relaxation of surface induced stresses (transient micro-cracks).

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T. Palberg M. Ballauff

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© 1997 Steinkopff Verlag

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Schmidt, M., Krieger, S., Johannsmann, D. (1997). Film formation of latex dispersions observed with evanescent dynamic light scattering. In: Palberg, T., Ballauff, M. (eds) Optical Methods and Physics of Colloidal Dispersions. Progress in Colloid & Polymer Science, vol 104. Steinkopff. https://doi.org/10.1007/BFb0110777

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  • DOI: https://doi.org/10.1007/BFb0110777

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1085-2

  • Online ISBN: 978-3-7985-1661-8

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