Abstract
We have applied evanescent dynamic light scattering (DLS) to study the film formation of polymer latex dispersions. A dynamical glass transition is observed. When the particles fuse, the scattering rate decreases. After fusion, a new fast process (τ r 1 ms) is observed, which is not present in bulk DLS data. We attribute the process to discontinuous relaxation of surface induced stresses (transient micro-cracks).
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© 1997 Steinkopff Verlag
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Schmidt, M., Krieger, S., Johannsmann, D. (1997). Film formation of latex dispersions observed with evanescent dynamic light scattering. In: Palberg, T., Ballauff, M. (eds) Optical Methods and Physics of Colloidal Dispersions. Progress in Colloid & Polymer Science, vol 104. Steinkopff. https://doi.org/10.1007/BFb0110777
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DOI: https://doi.org/10.1007/BFb0110777
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