Skip to main content

Phase transitions in nonadditive hard disc systems: a Gibbs ensemble Monte Carlo Study

  • Conference paper
  • First Online:
Optical Methods and Physics of Colloidal Dispersions

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 104))

  • 73 Accesses

Abstract

we study the properties of a model fluid in two dimensions with Gibbs ensemble Monte Carlo (GEMC) techniques, in particular we analyze the entropy-driven phase separation in case of a nonadditive symmetric hard disc fluid. By a combination of GEMC with finite size scaling techniques we locate the critical line of nonadditivities as a function of the system density, which separates the mixing/demixing regions and compare with a simple analytical approximation.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  1. Biben T, Hansen JP (1991) Phys Rev Lett 66:2215; (1991) J Phys, Condens Matter 3:F65

    Article  CAS  Google Scholar 

  2. Lebowitz JL, Mazel A, Nielaba P, Samaj L (1995) Phys Rev E 52:5985

    Article  CAS  Google Scholar 

  3. Jung J, Jhon MS, Ree FH (1995) J Chem Phys 102:1349

    Article  CAS  Google Scholar 

  4. Amar JG (1989) Mol Phys 67:739

    Article  CAS  Google Scholar 

  5. Gazzillo D, Pastore G (1989) Chem Phys Lett 159:388

    Article  CAS  Google Scholar 

  6. Gazzillo D (1991) J Chem Phys 95:4565

    Article  CAS  Google Scholar 

  7. Mountain RD, Harvey AH (1991) J Chem Phys 94:2238

    Article  CAS  Google Scholar 

  8. Frenkel D, Louis AA (1992) Phys Rev Lett 68:3363

    Article  CAS  Google Scholar 

  9. Panagiotopoulos AZ (1987) Mol Phys 61:813

    Article  CAS  Google Scholar 

  10. Smit B, De Smedt Ph, Frenkel D (1989) Mol Phys 86:931; Smit B, Frenkel D (1989) Mol Phys 68:951

    Article  Google Scholar 

  11. Schneider F, Nielaba P (1995) Phys Rev E 51:5162

    Article  CAS  Google Scholar 

  12. Panagiotopoulos AZ (1992) Molec Simul 9:1; Smit B (1993) In: Allen MP, Tildesley DJ (eds) Computer Simulation in Chemical Physics. Kluwer, Dordrecht, p 173

    Article  Google Scholar 

  13. Mon KK, Binder K (1992) J Chem Phys 96:6999

    Article  Google Scholar 

  14. Binder K (1981) Z Phys B 43:119

    Article  Google Scholar 

  15. Rovere M, Heermann DW, Binder K (1988) Europhys Lett 6:585; Rovere M, Nielaba P, Binder K (1993) Z Phys B 90:215

    Article  Google Scholar 

  16. Ihm MO (1993) Diplomarbeit, Mainz

    Google Scholar 

  17. Schneider F, Ihm MO, Nielaba P (1994) In: Landau DP, Mon KK, Schattier HB (eds) Computer Simulation Studies in Condensed Matter Physics VII. Springer, Berlin, p 188

    Google Scholar 

  18. Melnyk TW, Sawford BL (1975) Mol Phys 29:891

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

T. Palberg M. Ballauff

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Steinkopff Verlag

About this paper

Cite this paper

Ihm, M.O., Schneider, F., Nielaba, P. (1997). Phase transitions in nonadditive hard disc systems: a Gibbs ensemble Monte Carlo Study. In: Palberg, T., Ballauff, M. (eds) Optical Methods and Physics of Colloidal Dispersions. Progress in Colloid & Polymer Science, vol 104. Steinkopff. https://doi.org/10.1007/BFb0110770

Download citation

  • DOI: https://doi.org/10.1007/BFb0110770

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1085-2

  • Online ISBN: 978-3-7985-1661-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics