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Surface grafting of polyethyleneoxide optimized by means of ESCA

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Surface Forces and Surfactant Systems

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 74))

Abstract

A hydrophilic, non-ionic surface was prepared by grafting polyethyleneoxide (PEO) onto polyethylene (PE) and mica substrates. Monofunctional PEO-aldehyde was coupled by means of reductive amination to primary and secondary amino groups of polyethyleneimine (PEI) adsorbed on oxidized polyethylene (PE) and on mica. Optimum values of the reaction parameters influencing the reductive amination in this heterogeneous system were sought in order to achieve complete coverage of the surface by covalently linked PEO chains. Carrying out the coupling reaction at 60 °C, pH 6 and ck 2 so 4 over 40 h resulted in a PEO surface characterized by a maximal ESCA — C-O-/-CH2-ratio and, simultaneously, complete wetting by water. A PEO surface with a high degree of coverage was also obtained by means of adsorption from solution of a PEO-amine compound on mica.

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Author information

Authors and Affiliations

  1. Department of Colloid Science, L. Eötvös University, Budapest, Hungary

    E. Kiss

  2. Institute for Surface Chemistry, Stockholm, Sweden

    C. -G. Gölander

  3. Department of Physical Chemistry, The Royal Institute of Technology, Stockholm, Sweden

    J. C. Eriksson

Authors
  1. E. Kiss
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  2. C. -G. Gölander
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  3. J. C. Eriksson
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© 1987 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Kiss, E., Gölander, C.G., Eriksson, J.C. (1987). Surface grafting of polyethyleneoxide optimized by means of ESCA. In: Surface Forces and Surfactant Systems. Progress in Colloid & Polymer Science, vol 74. Steinkopff. https://doi.org/10.1007/BFb0109382

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  • DOI: https://doi.org/10.1007/BFb0109382

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0745-6

  • Online ISBN: 978-3-7985-1694-6

  • eBook Packages: Springer Book Archive

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