Abstract
In the past few years significant advances have been made in observing and understanding the microscopic properties of metal/semiconductor interfaces. Progress in this direction has been particularly striking for the case of transition-metal/Si and corresponding silicide/Si interfaces because: (i) the interface chemistry is somewhat simplified by the existence of well-defined compounds as reaction products; (ii) previous thin film studies have provided a considerable body of background information on some aspects of these reactions; and (iii) new experiments using a broad variety of techniques have addressed and correlated the electronic structure, the atomic structure, and the electrical properties of the interface on a microscopic level. The investigations have demonstrated the dominance of the microscopic chemical interactions in determining the interface properties. This paper reviews the essential scientific issues of metal/semiconductor interfaces and summarizes the evidence acquired and conclusions reached concerning the microscopic interface chemistry and Schottky barrier characteristics of transition-metal/Si and silicide/Si interfaces.
Supported in part by the U.S. Office of Naval Research.
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References
G. W. Rubloff, Surface Science (in press).
P. S. Ho, J. Vac. Sci. Technol. A 1, 745 (1983).
P. S. Ho and G. W. Rubloff, Thin Solid Films 89, 433 (1982).
G. W. Rubloff and P. S. Ho, Thin Solid Films 93, 21 (1982).
S. P. Murarka, J. Vac. Sci. Technol. 17, 775 (1980).
S. M. Sze, Physics of Semiconductor Devices, 2nd edition (Wiley, N. Y., 1981).
K. N. Tu and J. W. Mayer, Thin Films—Interdiffusion and Reactions, edited by J. M. Poate, K. N. Tu, and J. W. Mayer, (Wiley, New York, 1978), p. 359.
K. N. Tu, R. D. Thompson, and B. Y. Tsaur, Appl. Phys. Letters 38, 626 (1981).
J. L. Freeouf, G. W. Rubloff, P. S. Ho, and T. S. Kuan, Phys. Rev. Letters 43, 1836 (1979).
G. W. Rubloff, Proceedings of the 8th International Vacuum Congress, Cannes, France, Sept. 22–26, 1980, Vol. I, Thin Films, p. 562.
P. S. Ho, G. W. Rubloff, J. E. Lewis, V. L. Moruzzi, and A. R. Williams, Phys. Rev. B 22, 4784 (1980).
G. W. Rubloff, P. S. Ho, J. L. Freeouf, and J. E. Lewis, Phys. Rev. B23, 4183 (1981).
G. W. Rubloff, Phys. Rev. B25, 4307 (1982).
H. Föll, P. S. Ho, and K. N. Tu, Phil. Mag. A45, 31 (1982).
R. J. Purtell, P. S. Ho, G. W. Rubloff, and P. E. Schmid, Proceedings of the 16th International Conference on the Physics of Semiconductors, Montpellier, France, Sept. 6 10, 1982 (in press).
J. N. Miller, S. A. Schwarz, I. Lindau, and W. E. Spicer, J. Vac. Sci. Technol. 17 (5), 920 (1980).
L. Braicovich and I. Abbati, J. Vac. Sci. Technol. 17, 1005 (1980).
I. Abbati, L. Braicovich, U. Del Pennino and B. De Michelis, Proceedings of the 4th International Conference on Surface Science, Cannes, France, Sept. 22–26, 1980, Vol. II, p. 959 (1980).
I. Abbati, L. Braicovich, B. De Michelis, O. Bisi, and R. Rovetta, Solid State Commun. 37, 119–122 (1980).
I. Abbati, G. Rossi, I. Lindau, and W. E. Spicer, J. Vac. Sci. Technol. 19, 636–640 (1981).
G. Rossi, I. Abbati, L. Braicovich, I. Lindau, and W. E. Spicer, Phys. Rev. B25, 3627 (1982).
P. J. Grunthaner, F. J. Grunthaner, and J. W. Mayer, J. Vac. Sci. Technol. 17, 924 (1980).
N. W. Cheung, P. J. Grunthaner, F. J. Grunthaner, J. W. Mayer, and B. M. Ulrich, J. Vac. Sci. Technol. 18, 917 (1981).
P. J. Grunthaner, F. J. Grunthaner, D. M. Scott, and M-A. Nicolet, J. Vac. Sci. Technol. 19, 641 (1981).
P. J. Grunthaner, F. J. Grunthaner, A. Madhukar, and J. W. Mayer, J. Vac. Sci. Technol. 19, 649 (1981).
P. J. Grunthaner, F. J. Grunthaner, and A. Madhukar, J. Vac. Sci. Technol. 21, 637 (1982).
P. J. Grunthaner, F. J. Grunthaner, and A. Madhukar, J. Vac. Sci. Technol. 20, 680 (1982).
J. H. Weaver, V. L. Moruzzi and F. A. Schmidt, Phys. Rev. B23, 2916 (1981).
A. Franciosi, D. J. Peterman, J. H. Weaver, and V. L. Moruzzi, Phys. Rev. B25, 4981 (1982).
Y. J. Chabal, A. Franciosi, J. H. Weaver, J. E. Rowe, and J. M. Poate, J. Vac. Sci. Technol. (in press).
A. Franciosi, J. H. Weaver, D. G. O'Neill, Y. Chabal, J. E. Rowe, J. M. Poate, O. Bisi, and C. Calandra, J. Vac. Sci. Technol. 21, 624 (1982).
A. Franciosi, J. H. Weaver, and F. A. Schmidt, J. Vac. Sci. Technol. (in press).
A. Franciosi, D. J. Peterman, and J. H. Weaver, J. Vac. Sci. Technol. 19, 657 (1981).
G. V. Hansson, R. Z. Bachrach, R. S. Bauer, P. Chiaradia, J. Vac. Sci. Technol. 18, 550 (1981).
Y. J. Chabal, R. J. Culbertson, L. C. Feldman and J. E. Rowe, J. Vac. Sci. Technol 18, 880 (1981).
P. S. Ho, P. E. Schmid, and H. Föll, Phys. Rev. Letters 46, 782 (1981).
J. A. Roth and C. R. Crowell, J. Vac. Sci. Technol. 15, 1317 (1978).
N. Cheung, M.-A. Nicolet, and J. W. Mayer, Thin Film Interfaces and Interactions, ed. by J. E. E. Baglin and J. M. Poate (Vol. 80–2, The Electrochemical Society, 1980), p. 176.
N. W. Cheung, R. J. Culbertson, L. C. Feldman, P. J. Silverman, K. W. West, and J. W. Mayer, Phys. Rev. Letters 45, 120 (1980).
N. W. Cheung and J. W. Mayer, Phys. Rev. Letters 46, 671 (1981).
R. Tromp, E. J. van Loenen, M. Iwami, R. Smeenk, and F. W. Saris, Thin Solid Films 93, 151 (1982).
K. C. R. Chiu, J. M. Poate, L. C. Feldman and C. J. Doherty, Appl. Phys. Letters 36 (1980).
K. C. R. Chiu, J. M. Poate, L. C. Feldman, and C. J. Doherty, Thin Film Interfaces and Interactions, ed. by J. E. E. Baglin and J. M. Poate (Vol. 80-2, The Electrochemical Society, 1980), p. 171.
P. S. Ho, T. Y. Tan, J. E. Lewis, and G. W. Rubloff, J. Vac. Sci. Technol. 16, 1120 (1979).
H. Föll, P. S. Ho, and K. N. Tu, J. Appl. Phys. 52, 250 (1981).
P. E. Schmid, P. S. Ho, H. Föll, and G. W. Rubloff, J. Vac. Sci. Technol. 18, 937 (1981).
H. Föll and P. S. Ho, J. Appl. Phys. 52, 5510 (1981).
J. Stöhr and R. Jaeger, J. Vac. Sci. Technol. 21, 619 (1982).
J. G. Clabes, G. W. Rubloff, B. Reihl, R. J. Purtell, P. S. Ho, A. Zartner, F. J. Himpsel, and D. E. Eastman, J. Vac. Sci. Technol. 20, 684 (1982).
R. Purtell, J. G. Clabes, G. W. Rubloff, P. S. Ho, B. Reihl, and F. J. Himpsel, J. Vac. Sci. Technol. 21, 615 (1982).
R. J. Purtell, P. S. Ho, G. W. Rubloff, and P. E. Schmid, Proc. of the 16th Int. Conf. on the Physics of semiconductors, Montpellier, France, 1982, Physica 11, 834 (1983).
L. Braicovich, B. De Michelis, O. Bisi, C. Calandra, U. del Pennino, and S. Valeri, J. Phys. Soc. Japan 49, 1071 (1980).
O. Bisi and C. Calandra, J. Phys. C (in press).
Y. Chabal, D. R. Hamann, J. E. Rowe, M. Schlüter, (in press).
F. J. Himpsel and D. E. Eastman, J. Vac. Sci. Technol. 16, 1297 (1979).
R. Butz, G. W. Rubloff, and P. S. Ho, J. Vac. Sci. Technol. (in press).
I. Abbati, L. Braicovich, U. Del Pennino, B. De Michelis, and S. Valeri, Proceedings of the 4th International Conference on Surface Science. Cannes, France, Sept. 22–26, 1980, Vol. II, p. 1023 (1980).
Y. J. Chang and J. L. Erskine, Phys. Rev. B26, 4766 (1982).
G. Rossi, I. Abbati, L. Braicovich, I. Lindau, and W. E. Spicer, J. Vac. Sci. Technol. 21, 617 (1982).
I. Abbati, L. Braicovich, B. De Michelis and U. del Pennino, J. Vac. Sci. Technol. 17, 1303 (1980).
D. E. Eastman, F. J. Himpsel, J. A. Knapp, and K. C. Pandey, Proceedings of the 14th International Semiconductor Conference, Edinburgh, 1978, edited by B. L. H. Wilson (Institute of Physics and Physical Society, London, 1979).
P. S. Ho, G. W. Rubloff, J. E. Lewis, V. L. Moruzzi, and A. R. Williams, Thin Film Interfaces and Interactions, ed. by J. E. E. Baglin and J. M. Poate (Vol. 80–2, The Electrochemical Society, 1980), p. 85.
J. L. Freeouf, G. W. Rubloff, P. S. Ho, and T. S. Kuan, J. Vac. Sci. Technol. 17, 916 (1980).
I. Abbati, G. Rossi, L. Braicovich, I. Lindau, W. E. Spicer, and B. De Michelis, J. Appl. Phys. 52, 6994 (1981).
K. Oura, S. Okada, and T. Hanawa, Appl. Phys. Lett. 35, 705 (1979).
L. J. Chen, J. W. Mayer, K. N. Tu, and T. T. Sheng, Thin Solid Films 93, 91 (1982).
D. Cherns, D. A. Smith, W. Krakow, and P. E. Batson, Phil. Mag. 45, 107 (1982).
W. Krakow, Thin Solid Films 93, 109 (1982).
R. T. Tung, J. M. Gibson, and J. M. Poate, Phys. Rev. Lett. 50, 429 (1983).
G. W. Rubloff, Phys. Rev. B25, 4307 (1982).
J. L. Freeouf, Solid State Commun. 33, 1059 (1979).
J. L. Freeouf, J. Vac. Sci. Technol. 18, 910 (1981).
L. Braicovich, Surface Science (in press).
R. J. Purtell, G. Hollinger, G. W. Rubloff, and P. S. Ho, (to be published).
W. Schottky, Z. Physik 113, 367 (1939).
J. Bardeen, Phys. Rev. 71, 717 (1947).
M. Schlüter, Thin Solid Films 93, 1 (1982).
R. H. Williams, Contemp. Phys. 23, 329 (1982).
J. M. Andrews and J. C. Phillips, Phys. Rev. Lett. 35, 56 (1975).
G. Ottaviani, K. N. Tu, and J. W. Mayer, Phys. Rev. Lett. 44, 284 (1980).
P. E. Schmid, P. S. Ho, and T. Y. Tan, J. Vac. Sci. Technol. 20, 688 (1982).
G. Ottaviani, K. N. Tu, and J. W. Mayer, Phys. Rev. B24, 3354 (1981).
R. J. Purtell, G. Hollinger, G. W. Rubloff, and P. S. Ho, J. Vac. Sci. Technol. A1, 566 (1983).
J. L. Freeouf, M. Aono, F. J. Himpsel, and D. E. Eastman, J. Vac. Sci. Technol. 19, 681 (1981).
J. G. Clabes, G. W. Rubloff and T. Y. Tan, (to be published).
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Rubloff, G.W. (1983). Microscopic properties and behavior of metal/semiconductor interfaces. In: Grosse, P. (eds) Festkörperprobleme 23. Advances in Solid State Physics, vol 23. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107975
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