Abstract
The anomalies in the thermal expansion of fcc FeNi-alloys are known as “Invareffect” since a long time. Inspite of numerous experimental and theoretical efforts, the microscopic origin of the Invar-effect is todate not understood. We will show in the present paper that the Invar-effect incorporates a broad spectrum of magnetic and magnetoelastic anomalies in a wide variety of ferro- as well as antiferromagnetic alloys, which may have fcc, bcc, and hexagonal lattice structures or even be amorphous. We will also demonstrate to what extent mixed magnetic behavior or the occurrence of reentrant spin glass states contribute to the observed anomalies in Invar alloys. We will then focus on the question, how, according to new, systematic studies, the contributions from band (itinerant) magnetism and local moments can be separated. Finally, we will present results of our recent experimental investigations of the spin polarized photoemission on Fe3Pt-Invar. Comparison of these data to band-structure calculations on fcc Fe and Fe3Pt as a function of volume of the Wigner-Seitz cell will show that within the broad spectrum of available Invar models the “old” heuristic 2γ-states model, of Weiss describes the Invar-effect in principle correct.
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© 1987 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH
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Wassermann, E.F. (1987). Invar: A new approach to an old problem of magnetism. In: Grosse, P. (eds) Festkörperprobleme 27. Advances in Solid State Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107917
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DOI: https://doi.org/10.1007/BFb0107917
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