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Radiative recombination in amorphous semiconductors

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Festkörperprobleme 17

Part of the book series: Advances in Solid State Physics ((ASSP,volume 17))

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Abstract

Radiative recombination is observed in amorphous silicon and in the chalcogenide glasses as efficient luminescence. According to current models, radiative recombination in the chalcogenides occurs at network defects including relatively large Stokes shifts. In contrast, amorphous silicon exhibits no or only small Stokes shifts, and the luminescence spectra are explained by transitions between band tails, or between band tails and defect states. In both groups of materials Coulomb attraction between electrons and holes plays an important role.

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References

  1. F. Stern, J. Non-Cryst. Sol. 8–10, 954 (1972).

    Article  Google Scholar 

  2. K. Weiser, J. Non-Cryst. Sol. 8–10, 922 (1972).

    Article  ADS  Google Scholar 

  3. D. Engemann and R. Fischer, Amorphous and Liquid Semicond., edited by J. Stuke and W. Brenig, (Taylor and Francis, London), p. 947 (1974).

    Google Scholar 

  4. D. Engemann, R. Fischer and H. Mell, to be published (1977).

    Google Scholar 

  5. D. Engemann and R. Fischer, Proc. 12th Intern. Conf. on the Physics of Semicond., edited by M. H. Pilkuhn (Teubner, Stuttgart) p. 1042 (1974).

    Google Scholar 

  6. R. J. Loveland, W. E. Spear and A. Al-Sharbaty, J. Non-Cryst. Sol. 13, 55 (1973).

    Article  ADS  Google Scholar 

  7. J. R. Haynes, M. Lax and W. F. Flood, J. Phys. Chem. Solids 8, 392 (1959).

    Article  ADS  Google Scholar 

  8. W. C. Dash and R. Newman, Phys. Rev. 99, 1151 (1955).

    Article  ADS  Google Scholar 

  9. D. Engemann and R. Fischer, Structure and Excitations of Amorphous Solids (AIP Conf. Proc. No. 31, American Institute of Physics, New York) p. 37 (1976).

    Google Scholar 

  10. D. Engemann and R. Fischer, phys. stat. sol. (b) 79, 195 (1977).

    Article  ADS  Google Scholar 

  11. B. T. Kolomiets, T. N. Mamontova and A. A. Babaev, J. Non-Cryst. Sol. 4, 289 (1970).

    Article  ADS  Google Scholar 

  12. S. G. Bishop and D. L. Mitchell Phys. Rev. B8, 5696 (1973).

    Article  ADS  Google Scholar 

  13. J. Cernegora, F. Mollot and C. Benoit à la Guillaume phys. stat. sol. (a) 15, 401 (1973).

    Article  ADS  Google Scholar 

  14. R. A. Street, T. M. Searle and I. G. Austin, Phil. Mag. 30, 1181 (1974).

    Article  ADS  Google Scholar 

  15. J. T. Edmond, Brit. J. Appl. Phys. 17, 979 (1966).

    Article  ADS  Google Scholar 

  16. R. A. Street, I. G. Austin, T. M. Searle and B. A. Smith, J. Phys. C 7, 4185 (1974).

    Article  ADS  Google Scholar 

  17. R. Zallen, R. E. Drews, R. L. Emerald and M. L. Slade, Phys. Rev. Lett. 26, 1564 (1971).

    Article  ADS  Google Scholar 

  18. J. Cernegora, F. Mollot and C. Benoit à la Guillaume, Proc. 12th Intern. Conf. on the Physics of Semicond., edited by M. H. Pilkuhn (Teubner, Stuttgart), p. 1027 (1974).

    Google Scholar 

  19. S. G. Bishop, U. Strom and P. C. Taylor, Phys. Rev. Lett. 34, 1346 (1975).

    Article  ADS  Google Scholar 

  20. R. A. Street and N. F. Mott, Phys. Rev. Lett. 35, 1293 (1975).

    Article  ADS  Google Scholar 

  21. D. Emin, to be published (1977).

    Google Scholar 

  22. H. Zetsche and R. Fischer, J. Phys. Chem. Sol. 30, 1425 (1969).

    Article  ADS  Google Scholar 

  23. R. Fischer, Phys. Rev. B5, 3087 (1972).

    Article  ADS  Google Scholar 

  24. S. Tutihasi and I. Chen, Phys. Rev. 158, 623 (1967).

    Article  ADS  Google Scholar 

  25. J. C. Knights and E. A. Davis, J. Phys. Chem. Sol. 35, 543 (1974).

    Article  ADS  Google Scholar 

  26. D. Engemann, R. Fischer, F. W. Richter and H. Wagner, Proc. 6th Intern. Conf. Amorphous and Liquid Semicond., Leningrad, p. 217 (1975).

    Google Scholar 

  27. J. I. Pankove and D. E. Carlson, Appl. Phys. Lett. 29, 620 (1976).

    Article  ADS  Google Scholar 

  28. T. S. Nashashibi, I. G. Austin and T. M. Searle, Phil. Mag. (to be published 1977).

    Google Scholar 

  29. P. G. LeComber and W. E. Spear, Phys. Rev. Lett. 25, 509 (1970).

    Article  ADS  Google Scholar 

  30. W. E. Spear, R. J. Loveland and A. Al-Sharbaty, J. Non-Cryst Sol. 15, 410 (1974).

    Article  ADS  Google Scholar 

  31. D. Engemann, R. Fischer and W. Rehm, to be published (1977).

    Google Scholar 

  32. D. M. Pai and R. C. Enck, Phys. Rev. B11, 5163 (1975).

    Article  ADS  Google Scholar 

  33. D. G. Thomas, M. Gershenzon and F. A. Trumbore, Phys. Rev. 133, A269 (1964).

    Article  ADS  Google Scholar 

  34. D. Engemann and R. Fischer, unpublished.

    Google Scholar 

  35. R. S. Knox, Theory of Excitons, Solid State Physics Supplement, 5 (Academic Press, New York 1963).

    MATH  Google Scholar 

  36. J. O. Dimmock, Semiconductors and Semimetals, edited by R. K. Willardson and A. C. Beer (Academic Press, New York), Vol. 3, p. 259 (1967).

    Google Scholar 

  37. K. L. Shaklee and R. E. Nahory, Phys. Rev. Lett. 24, 942 (1970).

    Article  ADS  Google Scholar 

  38. V. S. Bagaev and L. I. Paduchikh, Soviet Physics-Solid State 13, 389 (1971).

    Google Scholar 

  39. J. E. Smith, M. H. Brodsky, B. L. Crowder and M. I. Nathan, J. Non-Cryst. Sol. 8–10, 179 (1972).

    Article  Google Scholar 

  40. J. Frenkel, Phys. Rev. 54, 647 (1938).

    Article  ADS  Google Scholar 

  41. J. L. Hartke, J. Appl. Phys. 39, 4871 (1968).

    Article  ADS  Google Scholar 

  42. L. Onsager, J. Chem. Phys. 2, 599 (1934).

    Article  ADS  Google Scholar 

  43. L. Onsager, Phys. Rev. 54, 554 (1938).

    Article  ADS  Google Scholar 

  44. D. L. Smith, D. S. Pan, T. C. McGill, Phys. Rev. B12, 4360 (1975).

    Article  ADS  Google Scholar 

  45. W. Rehm, D. Engemann, R. Fischer and J. Stuke, Proc. 13th Intern. Conf. Physics of Semicond., Rome, edited by F. G. Fumi, p. 525 (1976).

    Google Scholar 

  46. D. Redfield, Phys. Rev. 130, 914 (1963).

    Article  ADS  Google Scholar 

  47. A. Madan, P. G. Le Comber and W. E. Spear, J. Non-Cryst. Sol. 20, 239 (1976).

    Article  ADS  Google Scholar 

  48. W. E. Spear Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor and Francis, London) p. 1 (1974).

    Google Scholar 

  49. W. Beyer and J. Stuke, phys. stat. sol. (a) 30, 511 (1975).

    Article  ADS  Google Scholar 

  50. G. D. Watkins and J. W. Corbett, Phys. Rev. 138, A543 (1965).

    Article  ADS  Google Scholar 

  51. W. E. Spear and P. G. LeComber, Phil. Mag. 33, 935 (1976).

    Article  ADS  Google Scholar 

  52. W. E. Spear and P. G. LeComber, Solid State Comm. 17, 1193 (1975).

    Article  ADS  Google Scholar 

  53. M. H. Brodsky, M. Cardona and J. J. Cuomo, to be published (1977).

    Google Scholar 

  54. H. J. Hrostowski and R. H. Kaiser, Phys. Rev. 107, 966 (1957).

    Article  ADS  Google Scholar 

  55. R. A. Street, Advances in Physics 25, 397 (1976).

    Article  ADS  Google Scholar 

  56. T. D. Moustakas and K. Weiser, Phys. Rev. B12, 2448 (1975).

    Article  ADS  Google Scholar 

  57. R. Fischer and K. Weiser, to be published (1977).

    Google Scholar 

  58. M. Kastner, Phys. Rev. Lett. 28, 355 (1972).

    Article  ADS  Google Scholar 

  59. J. Tauc, A. Menth and D. L. Wood, Phys. Rev. Lett 25, 749 (1970).

    Article  ADS  Google Scholar 

  60. D. L. Wood and J. Tauc, Phys. Rev. B5, 3144 (1972).

    Article  ADS  Google Scholar 

  61. N. F. Mott, E. A. Davis and R. A. Street, Phil. Mag. 32, 961 (1975).

    Article  ADS  Google Scholar 

  62. A. L. Renninger and B. L. Averbach, Acta Crystallogr. B29 1583 (1973).

    Article  Google Scholar 

  63. P. W. Anderson, Phys. Rev. Lett. 34, 953 (1975).

    Article  ADS  Google Scholar 

  64. R. A. Street, T. M. Searle and I. G. Austin, J. Phys. C 6, 1830 (1973).

    Article  ADS  Google Scholar 

  65. J. M. Marshall and A. E. Owen, Phil. Mag. 24, 1281 (1971).

    Article  ADS  Google Scholar 

  66. C. Main, Thesis, Edinburgh (1974), cited from ref. [61] N. F. Mott, E. A. Davis and R. A. Street Phil. Mag. 32, 961 (1975).

    Google Scholar 

  67. R. A. Street, T. M. Searle and I. G. Austin, Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor and Francis, London), p. 953 (1974).

    Google Scholar 

  68. W. E. Spear, P. G. LeComber, S. Kimmond and M. H. Brodsky, Appl. Phys. Lett. 28, 105 (1976).

    Article  ADS  Google Scholar 

  69. D. E. Carlson and C. R. Wronski, Appl. Phys. Lett. 28, 671 (1976).

    Article  ADS  Google Scholar 

  70. C. R. Wronski, D. E. Carlson, and R. E. Daniel, Appl. Phys. Lett. 29, 602 (1976).

    Article  ADS  Google Scholar 

  71. D. A. Anderson and W. E. Spear, Phil. Mag. 35, 1 (1977).

    Article  ADS  Google Scholar 

  72. D. Engemann and R. Fischer, to be published (1977).

    Google Scholar 

  73. M. Gorman and S. A. Solin, Solid State Comm. 15, 761 (1974).

    Article  ADS  Google Scholar 

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J. Treusch

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© 1977 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH

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Fischer, R. (1977). Radiative recombination in amorphous semiconductors. In: Treusch, J. (eds) Festkörperprobleme 17. Advances in Solid State Physics, vol 17. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107759

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  • DOI: https://doi.org/10.1007/BFb0107759

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