Abstract
In order to understand crystal growth on a microscopic level it is necessary to know the sequence of structures a cluster assumes as it evolves from a molecule into a crystal. Small clusters reconstruct every time a molecule is added. After reaching a critical size, clusters take on the structure of a bulk material and therefore might appropriately be called microcrystals. This paper reviews some of the recent work on the structure of clusters and microcrystals with various types of bonding; ionic, metallic, van der Waals, covalent and hydrogen.
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M. R. Hoare and P. Pal, Adv. Phys. 20, 161 (1971); see articles in Proc. Int. Meeting on Small Particles and Inorganic Clusters, J. Physique, Suppl. C2 (1977), and Surface Sci. 106 (1981).
P. A. Aannestad and E. M. Purcell, Ann. Rev. Astr. and Astrophys. 11, 309 (1973); D. R. Hoffmann, Adv. in Phys. 26, 129 (1977); Solid State Astrophysics, N. C. Wickramasinghe and D. S. Morgan, editors (D. Reidel, Publishing Company, Dordrecht-Holland, 1976).
Growth and Properties of Metal Clusters, Applications to Catalysis and the Photographic Process. Jean Bourdon, Editor (Elsevier Scientific Publishing Company, Amsterdam, 1980).
T. H. James, ed., The Theory of the Photographic Process, 3rd ed. (The Macmillan Company, New York, 1966).
Conference on Cloud Physics and Atmospheric Electricity (American Meteorological Society, Boston, 1979).
T. P. Martin, Physics Reports 95, 167 (1983).
K. Sattler, in: Festkörperprobleme (Advances in Solid State Physics), Vol. XXIII, 13, P. Grosse (ed.), Vieweg, Braunschweig 1983.
K. Sattler, J. Mühlbach, O. Echt, P. Pfau, and E. Recknagel, Phys. Rev. Lett. 47, 160 (1981).
F. Honda, G. M. Lancaster, Y. Fukuda, and S. W. Rabelais, J. Chem. Phys. 69, 4931 (1978).
J. Campana, G. M. Barlak, R. J. Colton, J. J. De Corpo, J. R. Wyatt, and B. I. Dunlap, Phys. Rev. Lett. 47, 1046 (1981).
T. M. Barlak, J. E. Campana, R. J. Colton, J. J. De Corpo and J. R. Wyatt J. Chem. Phys. 85, 3840 (1981).
T. M. Barlak, J. R. Wyatt, R. J. Colton, J. J. De Corpo, and J. E. Campana, J. Am. Chem. Soc. 104, 1212 (1982).
T. M. Barlak, J. E. Campana, J. R. Wyatt, and R. J. Colton, J. Chem. Phys. 87 3441 (1983).
W. Ens, R. Beavis, and K. G. Standing, Phys. Rev. Lett. 50, 27 (1983).
T. P. Martin, to be published in Ber. Bunsenges. Phys. Chem.
T. P. Martin, J. Chem. Phys. 67, 5207 (1977); 69, 2036 (1978); 72, 3506 (1980).
D. O. Welch, O. W. Lazareth, G. J. Dienes, and R. D. Hatcher, J. Chem. Phys. 64, 835 (1976); 68, 2159 (1978).
T. P. Martin and A. Kakizaki, to be published in J. chem. Phys.
T. P. Martin and J. Diefenbach, J. Am. Chem. Soc. 106, 623 (1984).
J. D. Bernal, Nature 185, 68 (1960); Proc. Roy. Soc. A280, 299 (1964).
M. R. Hoare, Adv. Chem. Phys. 40, 49 (1979).
R.-P. Pan and R. D. Etters, J. Chem. Phys. 72, 1741 (1980); E. E. Polymeropoulos and J. Brickmann, Chem. Phys. Lett. 96, 273 (1983).
J. G. Allpress and J. V. Sanders, Aust. J. Phys. 23, 23 (1970).
J. J. Burton, J. Chem. Phys. 52, 345 (1970).
A. L. Mackay, Acta Cryst. 15, 916 (1962).
E. W. Becker, K. Bier, and W. Henkes, Z. Physik 146, 333 (1956).
O. F. Hagena and W. Obert, J. chem. Phys. 56, 1793 (1972).
O. Echt, K. Sattler, and E. Recknagel, Phys. Rev. Lett. 47, 1121 (1981).
J. Gspann, Surf. Sci. 106, 219 (1981).
R. G. Orth, H. T. Jonkman, D. H. Powell, and J. Michl, J. Am. Chem. Soc. 103, 6026 (1981).
L. Friedman and R. J. Beuhler, J. Chem. Phys. 78, 4669 (1983).
P. W. Stephens and J. G. King, Phys. Rev. Lett. 51, 1538 (1983).
A. Ding and J. Hesslich, Chem. Phys. Lett. 94, 54 (1983).
J. Farges, B. Raoult, and G. Torchet, J. Chem. Phys. 59, 3454 (1973).
J. Farges, M. F. De Feraudy, B. Raoult, and G. Torchet, Surf. Sci. 106, 95 (1981).
S.-S. Lin, Rev. Sci. Instrum. 44, 576 (1973).
J. Q. Searcy and J. B. Fenn, J. Chem. Phys. 61, 5292 (1974).
G. M. Lancaster, F. Honda, Y. Fukuda, and J. W. Rabalais, J. Am. Chem. Soc. 101, 1951 (1979).
D. Dreyfuss and H. Y. Wachman, J. chem. Phys. 76, 2031 (1982).
R. J. Beuhler and L. Friedman, J. Chem. Phys. 77, 2549 (1982).
A. J. Stace and C. Moore, Chem. Phys. Lett. 96, 80 (1983).
G. D. Stein and J. A. Armstrong, J. Chem. Phys. 58, 1999 (1973).
B. N. Hale and P. L. M. Plummer, J. Atmos. Sci. 31, 1615 (1974).
J. L. Kassner, Jr. and D. E. Hagen, J. Chem. Phys. 64, 1860 (1976).
F. H. Stillinger and C. W. David, J. Chem. Phys. 73, 3384 (1980).
P. M. Holland and A. W. Castleman, Jr., J. Chem. Phys. 72, 5984 (1980).
H. Haberland, H. Langosch, E.-G. Schindler, and D. R. Worsnop, to be published in Ber. Bunsenges. Phys. Chem.
U. Even and J. Jortner, J. Chem. Phys. 78, 3445 (1983).
A. J. Stace and C. Moore, J. Chem. Phys. 19, 3681 (1983).
J. M. Dartigues, A. Chambellan, and F. G. Gault, J. Am. Chem. Soc. 98, 856 (1976).
R. C. Baetzold and J. F. Hamilton, Proc. Solid St. Chem. 15, 1 (1983).
S. C. Richtsmeier, M. L. Hendewerk, D. A. Dixon, and J. L. Gole, J. Phys. Chem. 86, 3932 (1982).
D. R. Salahub, NATO ASI—Impact of Cluster Physics in Materials Science and Technology, J. Davenas, ed., Nijhoff, The Hague, 1983.
D. R. Salahub and R. P. Messmer, Phys. Rev. B16, 2526 (1977).
R. A. Chiles, C. E. Dykstra, and K. D. Jordan, J. Chem. Phys. 75, 1044 (1981).
C. W. Bauschlicher, Jr. P. S. Bagus, and B. N. Cox, J. Chem. Phys. 77, 4032 (1982).
G. Pacchioni and J. Koutecky, Chem. Phys. 71, 181 (1982).
G. Pacchioni and J. Koutecky, J. Chem. Phys. 77, 5850 (1982).
D. Plavsic, J. Koutecky, G. Pacchioni, and V. Bonacic-Koutecky, J. Phys. Chem. 87, 1096 (1983); P. Fantucci, J. Koutecky, and G. Pacchioni, to be published in J. Phys. Chem.
R. O. Jones, J. Chem. Phys. 71, 1300 (1979); J. Harris and R. O. Jones, J. Chem. Phys. 68, 1190 (1978).
J. Flad, H. Stoll, and H. Preuss, J. Chem. Phys. 71, 3042 (1979); J. Flad, G. Igel, M. Dolg, H. Stoll, and H. Preuss, Chem. Phys. 75, 331 (1983); M. P. Iniguez, C. Baladron, and J. A. Alonso, Surf. Sci. 127, 367 (1983).
R. Car and J. L. Martins, Surf. Sci. 106, 280 (1981).
M. Leleyter and P. Joyes, J. Physique 36, 343 (1975); J. Physique, Suppl. C2, 11 (1977).
A. Hermann, S. Leutwyler, E. Schumacher, and L. Wöste, Helv. Chim. Acta 61, 452 (1978); A. Hoareau, B. Cabaud, and P. Melinon, Surf. Sci. 106, 195 (1981).
T. P. Martin and J. Diefenbach, to be published.
K. Sattler, J. Mühlbach, and E. Recknagel, Phys. Rev. Lett. 45, 821 (1980).
M. M. Kappes, R. W. Kunz, and E. Schumacher, Chem. Phys. Lett. 91, 413 (1982).
S. J. Riley, E. K. Parks, C.-R. Mao, L. G. Pobo, and S. Wexler, J. Phys. Chem. 86, 3911 (1982).
K. Kimoto and I. Nishida, J. Phys. Soc. Japan 42, 2071 (1977).
T. G. Dietz, M. A. Duncan, D. E. Powers, and R. E. Smalley, J. Chem. Phys. 74, 6511 (1981); E. A. Rohlfing, D. M. Cox, and A. Kaldor, Chem. Phys. Lett. 99, 161 (1983).
V. E. Bondybey and J. H. English, J. Chem. Phys. 74, 6978 (1981); 76, 2165 (1982).
J. H. Gole, G. J. Green, S. A. Pace, and D. R. Preuss, J. Chem. Phys. 76, 2247 (1982).
J. B. Hopkins, P. R. R. Langridge-Smith, M. D. Morse, and R. E. Smalley, J. Chem. Phys. 78, 1627 (1983).
For an interesting discussion of phosphorus containing clusters see, H. G. von Schnering, “Catenation of Phosphorus Atoms” in: Homoatomic Rings and Chains, edited by A. L. Rheingold (Elsevier, New York, 1977).
T. P. Martin, Solid State Comm. 47, 111 (1983); J. Chem. Phys. 80, 170 (1984).
A. J. Apling, A. J. Leadbetter, and A. C. Wright, J. Non-Crystalline Solids 23, 369 (1977).
M. F. Daniel, A. J. Leadbetter, A. C. Wright, and R. N. Sinclair, J. Non-Crystalline Solids 32, 271 (1979).
R. J. Nemanich, G. A. N. Connell, T. M. Hayes, and R. A. Street, Phys. Rev. B 18, 6900 (1978).
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© 1984 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH
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Martin, T.P. (1984). The structure of elemental and molecular clusters. In: Grosse, P. (eds) Advances in Solid State Physics. Advances in Solid State Physics, vol 24. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107443
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DOI: https://doi.org/10.1007/BFb0107443
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