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Stochastic modelling of ion diffusion in complex systems

  • W. Dieterich
  • O. Dürr
  • P. Pendzig
  • A. Nitzan
Conference paper
Part of the Lecture Notes in Physics book series (LNP, volume 519)

Abstract

Fast ion conduction is known to occur in many solid materials, allowing us to perform fundamental studies of diffusion processes in a variety of structures. After briefly discussing classes of solid ionic conductors with increasing complexity in their structural and transport behaviour, we shall focus on polymer electrolytes. A lattice model is described which emphasizes the asymmetry in the cation-polymer and anion-polymer interactions. Monte-Carlo simulations of the equation of state are supplemented by calculations based on the quasi-chemical approximation. Simulated diffusion constants and their dependence on temperature and ion concentration are compared with recent experiments on PEO (polyethylene oxid)-type conductors.

Keywords

Polymer Electrolyte Solid State Ionic Point Particle Anion Diffusion Polyethylene Oxid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1999

Authors and Affiliations

  • W. Dieterich
    • 1
  • O. Dürr
    • 1
  • P. Pendzig
    • 1
  • A. Nitzan
    • 2
  1. 1.Fakultät für Physik Universität KonstanzKonstanzGermany
  2. 2.School of Chemistry, The Sackler Faculty of ScienceTel Aviv UniversityTel AvivIsrael

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