Abstract
Fast ion conduction is known to occur in many solid materials, allowing us to perform fundamental studies of diffusion processes in a variety of structures. After briefly discussing classes of solid ionic conductors with increasing complexity in their structural and transport behaviour, we shall focus on polymer electrolytes. A lattice model is described which emphasizes the asymmetry in the cation-polymer and anion-polymer interactions. Monte-Carlo simulations of the equation of state are supplemented by calculations based on the quasi-chemical approximation. Simulated diffusion constants and their dependence on temperature and ion concentration are compared with recent experiments on PEO (polyethylene oxid)-type conductors.
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Dieterich, W., Dürr, O., Pendzig, P., Nitzan, A. (1999). Stochastic modelling of ion diffusion in complex systems. In: Pękalski, A., Sznajd-Weron, K. (eds) Anomalous Diffusion From Basics to Applications. Lecture Notes in Physics, vol 519. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0106841
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DOI: https://doi.org/10.1007/BFb0106841
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