Skip to main content

A diffusion-limited reaction

  • Activation And Brownian Motors
  • Conference paper
  • First Online:

Part of the book series: Lecture Notes in Physics ((LNP,volume 484))

Abstract

Fluctuations in diffusion-controlled reactions lack the necessary features for a mesoscopic description. We show how the correlations dominate the dynamics by juxtaposing the macroscopic dynamics of a cellular automaton model for the diffusion-controlled limit to the deterministic diffusion-reaction rate equation for the same reaction. A more detailed N-body master equation is then presented in which explicit diffusion-controlled limits are explained.

This is a preview of subscription content, log in via an institution.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. von Smoluchowski M., Phys. Z. 17, 585 (1916), Z. Phys. Chem. 92 129 (1917)

    Google Scholar 

  2. Weiss G. H. and Rubin, R. J., Advan. Chem. Phys. 52 363 (1982)

    Article  Google Scholar 

  3. van Kampen N. G., Int. J. Quant. Chem. Symp. 16, 101 (1982)

    Google Scholar 

  4. Calef D. and Deutch J. M., Ann. Rev. Phys. Chem. 34 493 (1983)

    Article  ADS  Google Scholar 

  5. Gardiner C. W., Handbook of Stochastic Methods (Springer, Berlin) (1983)

    MATH  Google Scholar 

  6. Rice S. A., Comprehensive chemical kinetics, vol. 25. Diffusion-limited reactions (Elsevier, Amsterdam) (1985)

    Google Scholar 

  7. Keizer J., Chem. Rev. 87, 167 (1987)

    Article  Google Scholar 

  8. Ovchinnikov A. A., Timashev S. F. and Belyy A. A., Kinetics of Diffusion-Controlled Processes (Nova, New York) (1989)

    Google Scholar 

  9. Felderhof B. U., Theory of Diffusion-Controlled Reactions (preprint) (1996)

    Google Scholar 

  10. Field R. J., Noyes R. M., Nature 237 390 (1972), J. Chem. Phys. 60(5) 1877 (1974)

    Article  ADS  Google Scholar 

  11. Noyes R. M., Field R. J., Körös E., J. Amer. Chem. Soc. 94, 1394 (1972)

    Article  Google Scholar 

  12. Burschka M. A., Europhys. Lett. 16, 537 (1991)

    Article  ADS  MathSciNet  Google Scholar 

  13. van Kampen N. G., Stochastic Processes in Physics and Chemistry, (North-Holland 1981)

    Google Scholar 

  14. Burschka M. A., J. Stat. Phys. 45(3/4) 115 (1986)

    MathSciNet  Google Scholar 

  15. van Kampen N. G., Phys. Reports 124 69 (1985)

    Article  ADS  Google Scholar 

  16. Burschka M. A., Doering C. R., Horsthemke W. H. (to be published)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Lutz Schimansky-Geier Thorsten Pöschel

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Springer-Verlag

About this paper

Cite this paper

Burschka, M.A. (1997). A diffusion-limited reaction. In: Schimansky-Geier, L., Pöschel, T. (eds) Stochastic Dynamics. Lecture Notes in Physics, vol 484. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0105602

Download citation

  • DOI: https://doi.org/10.1007/BFb0105602

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-62893-4

  • Online ISBN: 978-3-540-69040-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics