Skip to main content
SpringerLink
Log in

Complex fluids under shear: Block copolymers

  • Conference paper
  • First Online:
Transport and Structure

Part of the book series: Lecture Notes in Physics ((LNP,volume 532-532))

Abstract

A survey is given on the effects of large amplitude oscillatory shear (LAOS) flow on the orientation behavior of lamellar poly (styrene-b- isoprene) (PS-b-PI) diblock copolymers with emphasis on the elucidation of common behavior with other layered complex fluids like lyotropic lamellar phases. It is described that for LAOS at temperatures close to the order-disorder-transition temperature, T ODT, three orientation regimes related to the dynamic shear viscosity of the block copolymers are observed: parallel orientation at high, perpendicular orientation at intermediate, and parallel orientation again at very low shear frequencies. It is demonstrated that one of the key issues to understand these non- equilibrium type experiments is the behavior of instabilities leading to flips of orientation from parallel to perpendicular alignment and vice versa. An orientation diagram showing the position of these instabilities in the amplitude-frequency space is derived experimentally suggesting a consistent phenomenological picture of orientation phenomena of layered systems under shear.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. The Physics of Block Copolymers, I. W. Hamley, Oxford University Press, Oxford 1998

    Google Scholar 

  2. M. Templin, A. Franck, A. Du Chesne, H. Leist, Y. Zhang, R. Ulrich, V. Schädler, U. Wiesner, Science 278 (1997), 1795

    Article  ADS  Google Scholar 

  3. R. Ulrich, A. Du Chesne, M. Templin, U. Wiesner, Adv. Mater. 11 (1999), 141

    Article  Google Scholar 

  4. A. Bagshaw, E. Prouzet, T. J. Pinnavaia, Science 269 (1995), 1242

    Article  ADS  Google Scholar 

  5. D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka, G. D. Stucky, Science 279, (1997), 548

    Article  ADS  Google Scholar 

  6. M. C. Weissenberger, C. G. Göltner, M. Antonietti, Ber. Bunsenges. Phys., Chem. 101 (1997), 1679.

    Google Scholar 

  7. R. Stadler, C. Auschra, J. Beckmann, U. Krappe, I. Voigt-Martin, L. Leibler, Macromolecules 28, 3080 (1995)

    Article  ADS  Google Scholar 

  8. U. Breiner, U. Krappe, V. Abetz, R. Stadler, Macromol. Chem. Phys. 198 (1997), 1051

    Article  Google Scholar 

  9. T. Goldacker, B. Abetz, R. Stadler, I. Erukhimovich, L. Leibler, Nature 398 (1999), 137

    Article  ADS  Google Scholar 

  10. M. Cross; P. Hohenberg, Rev. Mod. Phys. 65 (1993), 851

    Article  ADS  Google Scholar 

  11. The Structure and Rheology of Complex Fluids, R. G. Larson, Oxford University Press, New York, Oxford 1999

    Google Scholar 

  12. C. R. Safinya, E. B. Sirota, R. J. Plano, Phys. Rev. Lett. 66, 1986 (1991)

    Article  ADS  Google Scholar 

  13. C. R. Safinya, E. B. Sirota, R. F. Bruinsma, C. Jeppesen, R. J. Plano, L. J. Wenzel, Science 261 (1993), 588

    Article  ADS  Google Scholar 

  14. M. E. Cates, S. T. Milner, Phys. Rev. Lett. 62, 1856 (1989)

    Article  ADS  Google Scholar 

  15. K. A. Koppi, M. Tirrell, F. S. Bates, Phys. Rev. Lett. 70 (1993), 1449

    Article  ADS  Google Scholar 

  16. G. H. Fredrickson, J. Rheol. 38, 1045 (1994)

    Article  ADS  Google Scholar 

  17. M. Goulian, S. T. Milner, Phys. Rev. Lett. 74 (1995), 1775

    Article  ADS  Google Scholar 

  18. U. Wiesner, Macromol. Chem. Phys. 198 (1997), 3319

    Article  Google Scholar 

  19. G. Hadziioannou, C. Picot, A. Skoulios, M.-L. Ionescu, S. Mathis, R. Duplessix, Y. Gallot, J.-P. Lingelser, Macromolecules 15 (1982), 263

    Article  ADS  Google Scholar 

  20. K. A. Koppi, M. Tirrell, F. S. Bates, K. Almdal, R. H. Colby, J. Phys. II France 2 (1992), 1941

    Article  Google Scholar 

  21. K. I. Winey, S. S. Patel, R. G. Larson, H. Watanabe, Macromolecules 26 (1993), 2542

    Article  ADS  Google Scholar 

  22. K. I. Winey, S. S. Patel, R. G. Larson, H. Watanabe, Macromolecules 26 (1993), 4313

    Google Scholar 

  23. R. M. Kannan, J. A. Kornfield, Macromolecules 27 (1994), 1177

    Article  ADS  Google Scholar 

  24. S. Okamoto, K. Saijo, T. Hashimoto, Macromolecules 27 (1994), 5547

    Article  ADS  Google Scholar 

  25. Y. Zhang, U. Wiesner, H. W. Spiess, Macromolecules 28 (1995), 778

    Article  ADS  Google Scholar 

  26. S. S. Patel, R. G. Larson, K. I. Winey, H. Watanabe, Macromolecules 28 (1995), 4313

    Article  ADS  Google Scholar 

  27. V. K. Gupta, R. Krishnamoorti, J. A. Kornfield, S. D. Smith, Macromolecules 28 (1995), 4464

    Article  ADS  Google Scholar 

  28. Y. Zhang, U. Wiesner, J. Chem. Phys. 103 (1995), 4784

    Article  ADS  Google Scholar 

  29. G.H. Fredrickson, F.S. Bates, Ann. Rev. Mater. Sci. 26 (1996), 501

    Article  ADS  Google Scholar 

  30. R.H. Colby, Curr. Op. Colloid & Interface Sci. 1 (1996), 454

    Article  Google Scholar 

  31. C. C. Honeker, E.L. Thomas, Chem. Mater. 8 (1996), 1702

    Article  Google Scholar 

  32. V. K. Gupta, R. Krishnamoorti, Z.-R. Chen, J. A. Kornfield, S. D. Smith, M. M. Satkowski, J. T. Grothous, Macromolecules 29 (1996), 875

    Article  ADS  Google Scholar 

  33. V. K. Gupta, R. Krishnamoorti, J. A. Kornfield, S. D. Smith, Macromolecules 29 (1996), 1359

    Article  ADS  Google Scholar 

  34. B. S. Pinheiro, D. A. Hajduk, S. M. Gruner, K. I. Winey, Macromolecules 29 (1996), 1482

    Article  ADS  Google Scholar 

  35. Y. Zhang, U. Wiesner, Y. Yang, T. Pakula, H.W. Spiess, Macromolecules 29 (1996), 5427

    Article  ADS  Google Scholar 

  36. Z. R. Chen, J. A. Kornfield, S. S. Smith, J. T. Grothaus, M. M. Satowski, Science 277 (1997), 1248

    Article  Google Scholar 

  37. D. Maring, U. Wiesner, Macromolecules 30 (1997), 660

    Article  ADS  Google Scholar 

  38. Z.-R. Chen, A. M. Issaian, J. A. Kornfield, S. D. Smith, J. T. Grothaus, M. M. Satkowski, Macromolecules 30 (1997), 7096

    Article  ADS  Google Scholar 

  39. Y. Zhang, U. Wiesner, J. Chem. Phys. 106 (1997), 2961

    Article  ADS  Google Scholar 

  40. B. S. Pinheiro, K. I. Winey, Macromolecules 31 (1998), 4456

    Article  ADS  Google Scholar 

  41. H. Leist, D. Maring, T. Thurn-Albrecht, U. Wiesner, J. Chem. Phys. 110 (1999), 8225

    Article  ADS  Google Scholar 

  42. Y. Zhang, U. Wiesner, Macromol. Chem. Phys. 199 (1998), 1771

    Article  Google Scholar 

  43. O. Diat, D. Roux, F. Nallet, J. Phys. II France 3 (1993), 1427

    Article  Google Scholar 

  44. J. T. Mang, S. Kumar, B. Hammouda, Europhys. Lett. 28 (1994), 489

    Article  ADS  Google Scholar 

  45. J. Bergenholtz, N. J. Wagner, Langmuir 12 (1996), 3122

    Article  Google Scholar 

  46. J. Penfold, E. Staples, A. Khan Lodhi, I. Tucker, G. J. T. Tiddy, J. Phys. Chem. B 101 (1997), 66

    Article  Google Scholar 

  47. J. Berghausen, J. Zipfel, P. Lindner, W. Richtering, Europhys. Lett. 48 (1998), 683

    Article  ADS  Google Scholar 

  48. H. Leist, K. Geiger, U. Wiesner, Macromolecules, 32 (1999), 1315

    Article  ADS  Google Scholar 

  49. H. Kodama, M. Doi, Macromolecules 29 (1996), 2652

    Article  ADS  Google Scholar 

  50. H. Zhang, Y. Yang, Science in China 40 (1997), 53

    Article  Google Scholar 

  51. T. Pakula, J. Macromol. Sci.-Phys. B 37 (1998), 181

    Article  Google Scholar 

  52. A. V. Zvelindovsky, G. J. A. Sevink, B. A. C. van Vlimmeren, N. M. Maurits, J. G. E. M. Fraaije, Phys. Rev. E 57 (1998), 4879

    Article  ADS  Google Scholar 

  53. A. V. Zvelindovsky, G. J. A. Sevink, B. A. C. van Vlimmeren, N. M. Maurits, J. G. E. M. Fraaije, Progr. Colloid Polym. Sci 110 (1998), 251

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Cornell University, 14853, Ithaca, NY, USA

    Ulrich Wiesner

Authors
  1. Ulrich Wiesner
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Stefan C. Müller Jürgen Parisi Walter Zimmermann

Rights and permissions

Reprints and permissions

Copyright information

© 1999 Springer-Verlag

About this paper

Cite this paper

Wiesner, U. (1999). Complex fluids under shear: Block copolymers. In: Müller, S.C., Parisi, J., Zimmermann, W. (eds) Transport and Structure. Lecture Notes in Physics, vol 532-532. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0104228

Download citation

  • DOI: https://doi.org/10.1007/BFb0104228

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-66632-5

  • Online ISBN: 978-3-540-48070-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation