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J.R.Cooper, J.Lukatela, M.Miljak, J.M.Fabre, L.Giral and E.Aharon-Shalom, Solid State Comms.25,949 (1978)
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Of course this is a critical assumption.In our poster paper at the conference we assumed that similar hysteresis occurred in the internal energy U(T) rather than in G(T). This only leads to a step in CV(T) and not a peak. However the Gibbs free energy is the appropriate thermodynamic quantity so this change seems justified.
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Cooper, J.R., Lukatela, J. (1979). Conductivity measurements on TTF-TCNQ in the phase transition region. In: Bariŝić, S., Bjeliŝ, A., Cooper, J.R., Leontić, B.A. (eds) Quasi One-Dimensional Conductors I. Lecture Notes in Physics, vol 95/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0052787
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DOI: https://doi.org/10.1007/BFb0052787
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