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Chemical and stereochemical properties of compounds with silicon or germanium-transition metal bonds

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Inorganic Chemistry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 96))

Abstract

Complexes with silicon (or germanium)-transition metal bonds in which silicon or germanium is optically active are very stable both chemically and optically.

The introduction of a group IVB metal into transition metal complexes modifies the behavior of these complexes and a wide variety of reaction sites may result. Thus, reactions at silicon without cleavage of the transition metal-silicon bond are possible in some cases.

As pointed out in Section 3.1, the particular nature of the Si-H bond in transition metal complexes may explain some features of hydrosilylation.

Anions derived from transition metal-group IVB metal bonds may be interesting as potential asymmetric catalysts in phase transfer reactions. This field is developing now and, in general, the use of these complexes as catalysts is at the beginning.

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Authors and Affiliations

  1. Laboratoire des Organométalliques, Equipe de Recherche Associée au C.N.R.S. No. 554, Université des Sciences et Techniques du Languedoc, Place Eugène Bataillon, 34060, Montpellier-cédex, France

    Ernesto Colomer & Robert J. P. Corriu

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  1. Ernesto Colomer
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  2. Robert J. P. Corriu
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© 1981 Springer-Verlag

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Colomer, E., Corriu, R.J.P. (1981). Chemical and stereochemical properties of compounds with silicon or germanium-transition metal bonds. In: Inorganic Chemistry. Topics in Current Chemistry, vol 96. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051618

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  • DOI: https://doi.org/10.1007/BFb0051618

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  • Print ISBN: 978-3-540-10425-4

  • Online ISBN: 978-3-540-38470-0

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