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Recent developments in the chemistry of adamantane and related polycyclic hydrocarbons

Part of the Fortschritte der Chemischen Forschung book series (TOPCURRCHEM,volume 18/1)

Abstract

The chemistry of adamantane and related “cage-like” hydrocarbons has developed rapidly in recent years. These developments, encompassing a broad spectrum of the chemical world, have not been stimulated by any unique properties associated with the cage strutures of these molecules; the chemistry of such systems is typically hydrocarbon in nature. The particular utility of “cage-like” substrates in a variety of chemical investigations arises, for the most part, from their conformational rigidity; variables (e.g. those associated with structure) appropriate to more mobile compounds are often eliminated by the use of “cage-like” systems. The availability, ease of functionalization, and the near ideal structure of adamantane make it extremely useful for this purpose.

Keywords

  • Polycyclic Hydrocarbon
  • Tetrahedron Letter
  • Adamantane Derivative
  • Ring Closure Reaction
  • Methylene Position

These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

National Institutes of Health Predoctoral Fellow, 1968–1970.

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Bingham, R.C., Schleyer, P.v.R. (1971). Recent developments in the chemistry of adamantane and related polycyclic hydrocarbons. In: Chemistry of Adamantanes. Fortschritte der Chemischen Forschung, vol 18/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051406

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