Skip to main content
SpringerLink
Log in

The catalytic activity of organic and metallo-organic compounds in heterogeneous systems

  • Conference paper
  • First Online:
Catalysis

Part of the book series: Fortschritte der Chemischen Forschung ((TOPCURRCHEM,volume 25/1))

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Hanke, W.: Heterogene Katalyse an halbleitenden organischen Verbindungen. Z. Chem. 9, 1 (1969).

    Article  CAS  Google Scholar 

  2. Roginski, S. Z., Sakharov, M. M.: Catalytic Properties of Organic Semiconductors. Russ. J. Phys. Chem. (English Transl.) 42, 696 (1968).

    Google Scholar 

  3. Krause, H. W.: Organische Halbleiterkatalysatoren. Fortschr. Chem. Forsch. 6, 327 (1966).

    Google Scholar 

  4. Charentenay, F. X. de, Castel, P., Theyssié, Ph.: Polymères Semi-Conducteurs. Rev. Inst. Franc. Pétrole Ann. Combust. 18, 1126 (1963).

    Google Scholar 

  5. Leftin, H. P., Hermana, E.: Optical Spectra of Adsorbed Molecules. Mechanism of Stereo Selective Olefin Isomerisation on Silica-Alumina. Proc. Third Intern. Congr. Catalysis. Vol. II, p. 1064. Amsterdam: North Holland Publ. Comp. 1965.

    Google Scholar 

  6. Manassen, J., Klein, F. S.: Reactions of n-Butene and Butan-2-ol in Dilute Acid. The Elucidation of the Mechanism and the Intermediate in Elimination from Secondary Alcohols and in the Hydration of Olefins. J. Chem. Soc. 1960, 4203.

    Google Scholar 

  7. Szwarc, M.: Carban Ions, Living Polymers and Electron Transfer Processes. New York: Interscience Publ. 1968.

    Google Scholar 

  8. Woodward, R. G., Hoffmann, R.: The Conservation of Orbital Symmetry. New York: Acad. Press 1969; Fukui, K.: Orientation and Stereoselection. Fortschr. Chem. Forsch. 15, 1 (1970).

    Google Scholar 

  9. Cassar, L., Eaton, Ph. E., Halpern, J.: Catalysis of Symmetry Restricted Reactions by Transition Metal Compounds. J. Am. Chem. Soc. 92, 3515 (1970).

    Article  CAS  Google Scholar 

  10. Lugt, W. Th. A. M. van der: Symmetry Control and Transition Metal Catalyzed Reactions Tetrahedron Letters 1970, 2281.

    Google Scholar 

  11. Trapnell, B. M. W.: The Parahydrogen and Orthodeuterium Conversions and the Hydrogen-Deuterium Exchange. Catalysis, Vol. III (ed. Paul H. Emmett), p. 1. New York: Reinhold 1955.

    Google Scholar 

  12. Cremer, E.: Heterogene Ortho-und Parawasserstoffkatalyse. Handb. Katalyse, Vol. VI (ed. G.-M. Schwab). Heterogene Katalyse III, p. 1. Wien: Springer Verlag 1943.

    Google Scholar 

  13. Wigner, E.: über die paramagnetische Umwandlung von Para-Orthowasserstoff III. Z. Phys. Chem. B 23, 28 (1933).

    Google Scholar 

  14. Farkas, L., Sachsse, H.: über die homogene Katalyse der Para-Orthowasserstoffumwandlung unter Einwirkung paramagnetischer Moleküle I, II. Z. Phys. Chem. B 23, 1, 19 (1933).

    Google Scholar 

  15. Schwab, G.-M., Agallidis, E.: über die Einwirkung von Organischen Radikalen auf Para-Wasserstoff. Z. Phys. Chem. B 41, 59 (1938).

    Google Scholar 

  16. Bonhoeffer, K. F., Harteck, D.: über Para-und Ortho-Wasserstoff. Z. Phys. Chem. B 4, 113 (1929).

    Google Scholar 

  17. Rummel, K. W.: über die Parawasserstoff-Umwandlung an Kohle-OberflÄchen bei tiefen Temperaturen. Z. Phys. Chem. A 167, 221 (1933).

    Google Scholar 

  18. Bonhoeffer, K. F., Farkas, A., Rummel, K. W.: über die heterogene Katalyse der Parawasserstoffumwandlung. Z. Phys. Chem. B 21, 225 (1933).

    Google Scholar 

  19. Calvin, M., Cockbain, E. G., Polanyi, M.: Activation of Hydrogen by Phthalocyanine and Copper-Phthalocyanine. Part. I. Trans. Faraday Soc. 32, 1436 (1936).

    Article  CAS  Google Scholar 

  20. -, Eley, D. D., Polanyi, M.: Activation of Hydrogen by Phthalocyanine and Copper-Phthalocyanine. Part. II. Trans. Faraday Soc. 32, 1443 (1936).

    Article  CAS  Google Scholar 

  21. Eley, D. D.: The Conversion of Parahydrogen by Porphyrin Compounds, Including Hemoglobin. Trans. Faraday Soc. 36, 500 (1940).

    Article  CAS  Google Scholar 

  22. Turkevich, J., Selwood, P. W.: Solid Free Radical as Catalyst for Ortho-Para-Hydrogen Conversion. J. Am. Chem. Soc. 63, 1077 (1941).

    Article  CAS  Google Scholar 

  23. Harrison, L. G., McDowell, E. A.: The Catalysis of the Para-Hydrogen Conversion by the Solid Free Radical α, α′-diphenyl-Β-picryl Hydrazyl. Proc. Roy. Soc. London Ser. A, 220, 77 (1953).

    Article  CAS  Google Scholar 

  24. Eley, D. D., Inokuchi, H.: Organic Solids and Heterogeneous Catalysis. Electron Transfer in α,α′-diphenyl-Β-Pycryl-Hydrazyl. Z. Elektrochem. 63, 29 (1959).

    CAS  Google Scholar 

  25. Turkevich, J., Laroche, J.: Catalytic Activity of a Graded Set of Charcoals for the Hydrogen-Deuterium Equilibration and the Ortho-Para Hydrogen Conversion and Electron Spin Resonance. Z. Phys. Chem. N.F. 15, 399 (1958).

    CAS  Google Scholar 

  26. Acres, G. J. K., Eley, D. D.: Activation of Hydrogen by Polycopperphthalocyanine. Trans. Faraday Soc. 60, 1157 (1964).

    Article  CAS  Google Scholar 

  27. Davydova, I. R., Kiperman, S. L., Slinkin, A. A., Dulov, A. A.: On the Catalytic Activity of Certain Synthetic Organic Polymers Bull. Acad. Sci. USSR (English Transl.) 1964. 1502.

    Google Scholar 

  28. Tamaru, Kenzi: Catalysis by Electron Donor-Acceptor Complexes. Advan. Catalysis 20, 327 (1969).

    Article  CAS  Google Scholar 

  29. Kondow, T., Inokuchi, H., Wakayama, N.: Ortho-Para Hydrogen Conversion and Hydrogen-Deuterium Exchange in the Presence of Tetracyanopyrene-Cesium Complex. J. Chem. Phys. 43, 3766 (1965).

    Article  Google Scholar 

  30. Inokuchi, H., Wakayama, N., Kondow, T., Mori, Y.: Activated Adsorption of Hydrogens on Aromatic-Alkalimetal Charge-Transfer Complexes. J. Chem. Phys. 46, 837 (1967).

    Article  CAS  Google Scholar 

  31. -, Mori, Y., Wakayama, N.: Hydrogen Exchange between Deuterium and Charge-Transfer Complexes. J. Catalysis 8, 288 (1967).

    Article  CAS  Google Scholar 

  32. -, Wakayama, N., Hirooka, T.: Effect of Chemisorption of Hydrogen on Electrical Conductivity of Perylene-Cesium Charge-Transfer Complexes. J. Catalysis 8, 383 (1967); 8, 383(1967).

    Article  Google Scholar 

  33. Ichikawa, M., Soma, M., Onishi, T., Tamaru, K.: Reactivity of Electron Donor-Acceptor Complexes. Part. 8. Exchange Reaction of Hydrogen between Various Phthalocyanine EDA Complexes and Acetylene or Molecular Hydrogen. Trans. Faraday Soc. 63, 1215 (1967).

    Article  CAS  Google Scholar 

  34. -, Reactivity of Electron Donor-Acceptor Complexes. Part. 6. Hydrogen Exchange of Aromatic Cyano-Substituted Compounds. Trans. Faraday Soc. 63, 997 (1967).

    Article  CAS  Google Scholar 

  35. Wakayama, N., Inokuchi, H.: Catalytic Behavior of Organic Semiconductors. Hydrogen Exchange on Aromatic-Alkali-Metal Charge-Transfer Complexes. J. Catalysis 11, 143 (1968).

    Article  CAS  Google Scholar 

  36. -, Mori, Y., Inokuchi, H.: Catalytic Behavior of Organic Semiconductros. Relation Between Reactivity and Valency of Aromatic in Aromatic-Alkali Metal Complexes. J. Catalysis 12, 15 (1968).

    Article  CAS  Google Scholar 

  37. -, Inokuchi, H.: Catalytic Behavior of Organic Semiconductors. Hydrogen Exchange on Barium-Naphthacene Ion Salts. J. Catalysis 15, 417 (1969).

    Article  CAS  Google Scholar 

  38. Ichikawa, M., Soma, M., Onishi, T., Tamaru, K.: Exchange Reactions of Hydrogen over the Electron Donor-Acceptor Complexes of Various Phthalocyanines with Sodium. J. Catalysis 6, 336 (1966).

    Article  CAS  Google Scholar 

  39. -: Hydrogen Exchange Reaction between Molecular Hydrogen and the Electron Donor-Acceptor Complexes of Various Aromatic Compounds. Bull. Chem. Soc. Japan 40, 1015 (1967).

    CAS  Google Scholar 

  40. Tanaka, S., Ichikawa, M., Naito, S., Soma, M., Onishi, T., Tamaru, K.: The Behavior of Hydrogen Chemisorbed over the Electron Donor-Acceptor Complexes of Aromatic Hydrocarbons with Sodium in the Hydrogen Exchange and Hydrogenation Reaction. Bull. Chem. Soc. Japan 41, 1278 (1968).

    CAS  Google Scholar 

  41. Ichikawa, M., Soma, M., Onishi, T., Tamaru, K.: Reactivity of Electron Donor-Acceptor Complexes of Aromatic Compounds. Bull. Chem. Soc. Japan 40, 1294 (1967).

    CAS  Google Scholar 

  42. -: Reactivity of Electron Donor-Acceptor Complexes. Part 9. Isomerisation of Butene. Trans. Faraday Soc. 63, 2012 (1967).

    Article  CAS  Google Scholar 

  43. -: Reaction between Molecular Hydrogen and Various Electron Donor-Acceptor Complexes of Aromatic Hydrocarbons with Sodium. Their Electronic Properties. J. Am. Chem. Soc. 91, 6505 (1969).

    Article  CAS  Google Scholar 

  44. Haber, F., Weiss, J.: The Catalytic Decomposition of Hydrogen Peroxide by Iron Salts. Proc. Roy. Soc. (London), Ser. A, 147, 332 (1934).

    CAS  Google Scholar 

  45. Gallard-Nechtstein, J., Salle, R., Traynard, Ph.: Catalyse sur Polychélates. C. R. Acad. Sci. Paris, Ser. C, 262, 949 (1966).

    Google Scholar 

  46. Cook, A. H.: Catalytic Properties of the Phthalocyanines. Part. I. Catalase Properties. J. Chem. Soc. 1938, 1761.

    Google Scholar 

  47. Roginskii, S. Z., Berlin, A. A., Golovina, O. A., Dokukina, E. S., Sakharov, M. M., Cherkashina, L. G.: Catalytic Activity of Polyphthalocyanines with Respect to the Decomposition of Hydrogen Peroxide. Kinetica Katal. 4, 431 (1963); C. A. 59, 5833d (1963).

    CAS  Google Scholar 

  48. Levina, S. D., Andrianova, T. I., Sakharov, M. M., Golovina, O. A., Lobanova, K. P., Rotenberg, Z. A.: Catalytic Properties of Systems Consisting of Powered Metals and Phthalocyanines. Russ. J. Phys. Chem. (English Transl.) 40, 660 (1960).

    Google Scholar 

  49. Keier, N. P., Troitskaya, M. G., Rukhadze, E. G.: Catalytic Activity of Chelate Polymers in the Reaction of Hydrogen Peroxide Decomposition. Kinetika Katal. 3, 691 (1962); C. A. 58, 7413a (1963).

    CAS  Google Scholar 

  50. Hercules, David M.: Electron Spectroscopy. Anal. Chem. 42, 20 A (1970).

    CAS  Google Scholar 

  51. Topchiev, A. V., Geiderikh, M. A., Davydov, B. E., Kargin, V. A., Krentsel, B. A., Kustanovich, I. M., Polak, L. S.: Preparation of Polymeric Materials with Semiconductor Properties Based on Acrylonitrile. Dokl. Akad. Nauk SSSR 128, 312 (1959); C. A. 54, 6223h (1960).

    CAS  Google Scholar 

  52. Berlin, A. A., Blyumenfeld, L. A., Semenov, N. N.: Catalytic Properties of some Macromolecular Structures. Izv. Akad. Nauk SSSR, Ser. Khim. 1959, 1689. C. A. 54, 8252h (1960).

    Google Scholar 

  53. Inoue, H., Kida, Y., Imoto, E.: Vulcanized Anilinblack. Its Electrical Conductivity and Catalysis upon the Decomposition of Hydrogen Peroxide. Bull. Chem. Soc. Japan 39, 551 (1966).

    CAS  Google Scholar 

  54. Parini, V. P., Kazokova, Z. S., Berlin, A. A.: Polymers with Conjugated Bonds and Heteroatoms in the Conjugated Bond Chain. XIX. Some Properties of Aniline Black. Vysokomolekul Soedin. 3, 1870 (1961). C. A. 56, 14460g (1962).

    CAS  Google Scholar 

  55. Dokukina, E. S., Golovina, O. A., Sakharov, M. M., Aseeva, R. M.: Catalytic Activity of Organic Semiconductors Obtained by Thermal Dehydrochlorination of Poly(vinylchloride). Kinetika Katal. 7, 660 (1966). C. A. 65, 17755f (1966).

    CAS  Google Scholar 

  56. Manassen, J., Wallach, J.: Organic Polymers. Correlation between their Structure and Catalytic Activity in Heterogeneous Systems. I. Pyrolyzed Polyacrylonitrile and Polycyanoacetylene. J. Am. Chem. Soc. 87, 2671 (1965).

    Article  CAS  Google Scholar 

  57. Higginson, W. C. E.: The Oxidation of Hydrazine in Aqueous Solution. The Chemical Society, London. Special Publication No. 10, p. 95 (1957). (Recent Aspects of the Inorganic Chemistry of Nitrogen.)

    Google Scholar 

  58. Willhoft, E. M. A., Robertson, A. J. B.: Mass-Spectrometric Investigation of Di-imide by the Catalytic Decomposition of Hydrazine at Low Pressures on Platinum. Chem, Commun. 1967, 385.

    Google Scholar 

  59. Boreskov, G. K., Keier, N. P., Rubtsova, L. P., Rukhadze, E. G.: The Catalytic Properties of Chelate (Intramolecular) Polymers. Dokl. SSSR. Phys. Chem. Section 144, 453 (1962). (English Transl.)

    Google Scholar 

  60. Keier, N. P., Boreskov, G. K., Rubtsova, L. F., Rukhadze, E. G.: Catalytic Activity of Organic Polymers. III. Regularities of Catalysis on the Chelate Polymers of Different Chemical Composition and Structure. Kinetika Katal. 3, 680 (1962). C. A. 58, 7412g (1963).

    CAS  Google Scholar 

  61. -Regularities of Catalysis on Chelate Polymers. Proc. Third Intern. Congr. Catalysis, p. 1021. Amsterdam: North Holland Publishing Co.

    Google Scholar 

  62. -, Astafiev, I. V.: Catalytic Activity of Organic Polymers. II. Catalytic Proporties of a Polymer Obtained by Dechlorination of Poly(vinylidene Chloride). Kinetika Katal. 3, 364 (1962).

    CAS  Google Scholar 

  63. Hine, J.: Physical Organic Chemistry (Second Edition), p. 311. New York: McGraw-Hill Book Company Inc. 1962.

    Google Scholar 

  64. Sachtler, W. M. H., Fahrenfort, J.: The Catalytic Decomposition of Formic Acid Vapor on Metals. Proc. Second. Intern. Congr. Catalysis. Technip. Paris 1961, p. 831.

    Google Scholar 

  65. Walling, Ch.: Free Radicals in Solution, p. 273 and 288. New York: John Wiley and Sons Inc. 1957.

    Google Scholar 

  66. Beckwith, A. L. S., Norman, R. O. C.: Electron Spin Resonance Studies. Part XX. The Generation of Organic Radicals by the One Electron Reduction of Aliphatic Halogeno-Compounds in Aqueous Solution. J. Chem. Soc. A 1969, 400.

    Google Scholar 

  67. Hanke, W.: Katalyse an Phthalocyaninen. I. AmeisensÄuredampfzerfall an Metall-Phthalocyaninen. Z. Anorg. Allgem. Chem. 343, 121 (1966).

    Article  CAS  Google Scholar 

  68. -: Katalyse an Phthalocyaninen. II, AmeisensÄuredampfzerfall an polymeren Kupfer-Phthalocyanin und die Bedeutung des elektronischen Faktors. Z. Anorg, Allgem. Chem. 347, 67 (1967).

    Article  Google Scholar 

  69. -: Katalyse an Phthalocyaninen IV. Mangan-Formiat-Phthalocyanin und der AmeisensÄuredampfzerfall an Mangan Phthalocyanin. Z. Anorg. Allgem. Chem. 355, 160 (1967).

    Article  CAS  Google Scholar 

  70. -, Gutschick, D.: Katalyse und Phthalocyaninen V. über ein Zinkphthalocyanin-AmeisensÄure-Addukt und zur Wechselwirkung von Metallphthalocyaninen mit AmeisensÄure. Z. Anorg. Allgem. Chem. 366, 201 (1969).

    Article  CAS  Google Scholar 

  71. Rosswurm, H., Haevecker, R., Doiwa, A.: Katalyse an organischen Halbleitern I. AmeisensÄuredampfzerfall an Phthalocyaninen. Z. Anorg. Allgem. Chem. 350, 1 (1967).

    Article  CAS  Google Scholar 

  72. Tanaka, S., Onishi, T., Tamaru, K.: Decomposition of Formic Acid over Metal Phtahlocyanines. Bull. Chem. Soc. Japan 41, 2557 (1968).

    CAS  Google Scholar 

  73. Roginskii, S. Z., Berlin, A. A., Kutseva, L. N., Aseeva, R. M., Cherkashina, L. G., Sherle, A. I., Matseeva, N. G.: Catalytic Properties of Organic Polymers with a Conjugated Bond System. The Formation of Hydroperoxides by Oxidation of Alkylaromatic Hydrocarbons and Cychlohexane. Dokl. SSSR, Chemistry Section (English Transl.) 148, 35 (1963) (1963).

    Google Scholar 

  74. Nesmeyanov, A. N., Rubinstein, A. M., Dulov, A. A., Slinkin, A. A., Rubinskaya, M. I., Slonimskii, G. L.: Catalytic Properties of Polymers Prepared from Methyl-Chlorovinyl Ketone. Dokl. Akad. Nauk. SSSR 135, 609 (1960). C. A. 55, 15338a (1961).

    CAS  Google Scholar 

  75. Taylor, William F.: Catalysis in Liquid-Phase Autoxidation. I. Effect of Polymeric Surfaces. J. Catalysis 16, 20 (1970).

    Article  CAS  Google Scholar 

  76. Hock, H., Kropf, H.: Autoxidation von Kohlenwasserstoffen XXVII. Phthalocyanine als Katalysatoren für die Autoxydation von Cumol und sonstigen Benzolkohlenwasserstoffen. J. Prakt. Chem. 9, 173 (1959).

    Article  CAS  Google Scholar 

  77. Kropf, H.: Katalyse durch Phthalocyanine. I. Kinetik und Mechanismus der Autoxydation von Cumol in Gegenwart von Phthalocyaninen. Ann. Chem. 637, 73 (1960).

    CAS  Google Scholar 

  78. -: Katalyse durch Phthalocyanine. II. Katalyse von Benzolkohlenwasserstoffen durch Kupfer-Phthalocyanine. Ann. Chem. 637, 93 (1960).

    CAS  Google Scholar 

  79. -Katalyse durch Phthalocyanine. V. Autoxydation von Cumol in Gegenwart von Vanadyl-Phthalocyanin. Tetrahedron Letters 1962, 577.

    Google Scholar 

  80. -Hoffmann, Hd.: Autoxydation von Cumol in Gegenwart von substituierten Kupfer-Phthalocyaninen und verwandten Kupfer-Komplexen. Tetrahedron Letters 1967, 659.

    Google Scholar 

  81. Minkov, A. I., Keier, N. P.: The Mechanism of Cumene Oxidation over Copper Phthalocyanine. Kinetika Katal. 8, 160 (1967). C. A. 67, 21210s (1967).

    CAS  Google Scholar 

  82. --, Anufrienko, V. F.: Oxidation of Isopropylbenzene on Copper Phthalocyanine. Kinetika Katal. 8, 387 (1967). C. A. 67, 107899(1967).

    CAS  Google Scholar 

  83. Kundo, N. N., Keier, N. P.: Catalytic Activity of Organic Copper Complexes in Cysteine Oxidation. Kinetika Katal. 8, 796 (1967). C. A. 68, 30008e (1968).

    CAS  Google Scholar 

  84. Wolberg, A., Manassen, J.: Electrochemical and Electron Paramagnetic Resonance Studies on Metalloporphyrins and their Electrochemical Oxidation Products. J. Am. Chem. Soc. 92, 2982 (1970).

    Article  CAS  Google Scholar 

  85. Falk, J. E.: Porphyrins and Metalloporphyrins. p. 26. Amsterdam: Elsevier 1964.

    Google Scholar 

  86. Kamiya, Y.: The Autoxidation of α-Methylstyrene, Catalyzed by Copperphthalocyanine. Tetrahedron Letters 1968, 4965

    Google Scholar 

  87. Inoue, H., Kida, Y., Imoto, E.: The Catalytic Action of Binary Metal-Polyphthalocyanine Complexes on the Oxidation of Acetaldehyde Ethylene Acetal. Bull. Chem. Soc. Japan 38, 2214 (1965).

    CAS  Google Scholar 

  88. ---: Organic Catalysts. III. The Catalytic Action of Copper-Iron Polyphthalocyanine on Oxidation of Acetalhyde Ethylene Acetal. Bull. Chem. Soc. Japan 40, 184 (1967).

    CAS  Google Scholar 

  89. ---: Organic Catalysts. The Role of the Iron as an Oxidation Catalysts in Copper-Iron Polyphthalocyanine. Bull. Chem. Soc. Japan 41, 684 (1968).

    CAS  Google Scholar 

  90. ---: Organic Catalysts. V. Specific Catalytic Properties of Copper-Iron Polyphthalocyanine in the Oxidation of Aldehydes. Bull. Chem. Soc. Japan 41, 692 (1968); 41, 692(1968).

    CAS  Google Scholar 

  91. Keier, N. P., Mamaeva, E. K., Alikina, G. M., Tyuleneva, L. I., Afanaseva, S. M.: Catalytic Activity of the Transition Metal Chelate Salts of Quinaldine Dithioamides on Oxidation of Cumene. Kinetika Katal. 6, 849 (1965).

    CAS  Google Scholar 

  92. Minkov, A. I., Alikina, F. M., Fridnev, Yu. M., Keier, N. P.: Catalytic Activity of Polychelates in the Liquid-Phase Oxidation for Hydrocarbons. Kinetika Katal. 7, 632 (1966).

    CAS  Google Scholar 

  93. Universal Oil Products Co.: Oxidative Sweetening of Kerosine with Phthalocyanine Catalysts. U.S. Patent 3, 408, 287 (1968); C.A. 70, 13245d (1969).

    Google Scholar 

  94. Allis Chambers Manufg. Co.: Fuel Electrodes Having a Metal Phthalocyanine Catalyst. U.S. Patent 3, 410, 727 (1968); C.A. 70, 33823u (1969).

    Google Scholar 

  95. Compagnie FranÇaise de Raffinage (1966): Catalyseurs Organiques a Grande Spécifique et leur Procédé de Fabrication. French Patent 1, 431, 848.

    Google Scholar 

  96. Manassen, J., Khalif, Sh.: Organic Polymers. Correlation between their Structure and Catalytic Activity in Heterogeneous Systems. II. Models for Dehydrogenation Catalysts. J. Am. Chem. Soc. 88, 1943 (1966).

    Article  CAS  Google Scholar 

  97. -Catalytic Hydrogen Transfer. Israel Patent Apllication 27693 (1966).

    Google Scholar 

  98. Berlin, A. A., Ragimov, A. V., Liogonkii, B. I., Belova, G. V.: Synthesis and Study of Polyarylene Quinones. Polymer Sci. (USSR) (English Transl.) 8, 589 (1966).

    Google Scholar 

  99. Manassen, J., Khalif, Sh.: Organic Polymers: Correlation between their Structure and Catalytic Activity in Heterogeneous Systems. IV. Oxydative Dehydrogenation. A Comparison between the Catalytic Activity of an Organic Polymer and that of some Molybdate Catalysts. J. Catalysis 13, 290 (1969).

    Article  CAS  Google Scholar 

  100. -, Bar Ilan, A.: Metal Complexes of Phthalocyanine and α, Β, λ, δ-Tetraphenyl Prophyrin as Heterogeneous Catalysts in Oxidative Dehydrogenation. Correlation between Catalytic Activity and Redox Potential. J. Catalysis 17, 86 (1970).

    Article  CAS  Google Scholar 

  101. Bar Ilan, A., Manassen, J.: Unpublished Results.

    Google Scholar 

  102. Jolly, W. L.: The Inorganic Chemistry of Nitrogen, p. 71. New York, Amsterdam: W. A. Benjamin Inc. 1964.

    Google Scholar 

  103. Mme Gallard, J., Laederlich, Th., Salle, R., Traynard, Ph.: Polymeres a Structures Conjuguée. I. Catalyse par les Polymères Conjugées. Bull. Soc. Chim. France 1963, 2204.

    Google Scholar 

  104. -Nechtstein, M., Soutif, M., Traynard, Ph.: Polymères à Structure Conjuguée. II. Conclusion entre Propriétés Cataliques et Centres Paramagnétiques dans les Polymères Conjuguées. Bull. Soc. Chim. France 1963, 2209.

    Google Scholar 

  105. Gallard-Nechtstein, J., Pècher-Reboul, A., Traynard, Ph.: Polymères à Structure Conjuguée. III. Influence de la Structure sur les Propriétés Cataliques des Polymères Conjugués. Bull. Soc. Chim. France 1967, 960.

    Google Scholar 

  106. ---: Heterogeneous Catalysis on Organic Conjugated Polymers. II. Electron Spin Resonance and Structural Factor. J. Catalysis 13, 261 (1969).

    Article  Google Scholar 

  107. Cutlip, M. B., Peters, M. S.: Heterogeneous Catalysis over an Organic Semiconducting Organic and Metallo-Organic Compounds in Heterogeneous Systems Polymer made from Acrylonitrile. Symp. on Recent Advances in Reaction Kinetics and Catalysis, Part. I. Sixtieth Annual Meeting, New York. November 26–30, 1967.

    Google Scholar 

  108. Paushkin, Ya. M., Burova, L. M., Voronina, M. A., Vishnyakova, T. D., Sokolinskaya, T. A., Aliev, L. A.: Dehydration and Dehydrogenation of Alcohols, Catalyzed by Ferrocene Polymers. Dokl. Akad. Nauk. SSSR 186, 108 (1969).

    CAS  Google Scholar 

  109. Fang, F. T.: Heterogeneous Catalysis by Macroreticular Functional Resins. Proc. Third. Internat. Cong. Catalysis, p. 901. Amsterdam: North Holland Publ. Comp. 1965.

    Google Scholar 

  110. Manassen, J., Khalif, Sh.: Organic Polymers. Correlation between their Structure and Catalytic Activity in Heterogeneous Systems. III. Acid Type Catalysis, Sulfonated and Phosphonated Polyphenyl. J. Catalysis 7, 110 (1967).

    Article  CAS  Google Scholar 

  111. Kallo, D., Preszler, I.: n-Butene Isomerization on Acidic Ion-Exchange Resins. J. Catalysis 12, 1 (1968).

    Article  CAS  Google Scholar 

  112. Gates, B. C., Schwab, G.-M.: The Dehydration of Formic Acid Catalyzed by Polystyrene Sulfonic Acid. J. Catalysis 15, 430 (1969).

    Article  CAS  Google Scholar 

  113. -, Johanson, L. N.: The Dehydration of Methanol and Ethanol Catalyzed by Polystyrene Sulfonate Resins. J. Catalysis 14, 69 (1969).

    Article  CAS  Google Scholar 

  114. Frilette, V. J., Mower, E. M., Rubin, M. K.: Kinetics of Dehydration of Ter-butyl Alcohol Catalyzed by Ion Exchange Resins. J. Catalysis 3, 25 (1964).

    Article  CAS  Google Scholar 

  115. Cassidy, H. G., Kun, K. A.: Oxidation-reduction Polymers; Redox Polymers. Interscience, New York (1965).

    Google Scholar 

  116. Chelate Polymers Give New Redox Route. Chem. Eng. News, April 2, 1962, p. 48.

    Google Scholar 

  117. Allan, G. G., Neogi, A. N.: Macromolecular Organometallic Catalysis. J. Phys. Chem. 73, 2093 (1969).

    Article  CAS  Google Scholar 

  118. Mobil Oil: Procédé de Mise en Oeuvre de Reactions Catalysées par und Compléxe Résine-Metal' Belgian Patent 721, 696 (1969).

    Google Scholar 

  119. I. C. I.: Verfahren zur Oligomerisation von Olefinen. German Patent 1,937,232 (1970).

    Google Scholar 

  120. Manassen, J.: Heterogeneous Hydroformylation of Olefins. Israel Patent Application 30505 (1968).

    Google Scholar 

  121. Legzdins, P., Rempel, G. L., Wilkinson, G.: The Protonation of Metal Carboxylates. New Homogeneous Hydrogenation Catalyst. Chem. Commun. 1969, 825.

    Google Scholar 

  122. Tyruenkova, O. A.: Hydrogenation of Unsaturated Compounds on Palladium/Polymer Catalysts. Russian J. Phys. Chem. (English Transl.) 43, 1167 (1969).

    Google Scholar 

  123. Akabori, S., Sakurai, S., Izumi, Y., Fujii, Y.: Asymmetric Catalyst. Nature 178, 323 (1956).

    CAS  Google Scholar 

  124. Harada, K., Yoshida, T.: Asymmetric Hydrogenation Using Modified Cellulose-Palladium Catalysts. Naturwissenschaften 57, 131 (1970).

    Article  CAS  Google Scholar 

  125. --: Asymmetric Hydrogenation Using Modified Ion Exchange Resin-Palladium Catalysts. Naturwissenschaften 57, 306 (1970).

    Article  CAS  Google Scholar 

  126. Izumi, Y., Akabori, S., Fukawa, H., Tatumi, S., Imaida, N., Fukuda, T., Komatu, S.: Asymmetric Hydrogenation with Modified Raney Nickel. Proc. Third Intern. Congr. Catalysis. Volume II, p. 1364. Amsterdam: North Holland Publ. Comp. 1965.

    Google Scholar 

  127. -, Tatsumi, S., Imaida, M., Okubo, K.: Asymmetric Hydrogenation of C=O Double Bonds with Modified Raney Nickel. XIII. Modification with Peptides. Bull. Chem. Soc. Japan 43, 556 (1970).

    Google Scholar 

  128. Cooper, B. J.: Platinum-Carbon Catalysts with Molecular Sieve Properties. Shape Selectivity in Hydrogenation Catalysis. Platinum Metals Rev. 14, 133 (1970).

    CAS  Google Scholar 

  129. Welch, R. C. W., Rase, H. F.: Selectivity Characteristics of a Geometrically Designed Heterogeneous Catalyst. A High Melting Copper-Enzyme Model. Ind. Eng. Chem. Fundamentals 8, 389 (1969).

    Article  CAS  Google Scholar 

  130. Harrison, D. D., Rase, H. F.: Nylon Platinum Catalysts with Unusual Geometric and Selective Characteristics. Ind. Eng. Chem. Fundamentals 6, 161 (1967).

    Article  CAS  Google Scholar 

  131. Mme Nechtstein, J.: L'Oxidation du n-butyl-sulfure Catalysée par un mélange de Charbon Actif et de Phthalocyanine de Cobalt. C. R. Acad. Sci. Paris, Ser. C. 268, 376 (1969).

    Google Scholar 

  132. Ichikawa, M., Sudo, M., Soma, M., Onichi, T., Tamara, K.: Catalytic Formation of Hydrocarbons (C1-C5) from Hydrogen and Carbon Monoxide over the Electron Donor-Acceptor Complex Films of Alkalimetals with Transition Metal Phthalocyanines or Graphite. J. Am. Chem. Soc. 91, 1538 (1969).

    Article  CAS  Google Scholar 

  133. Lindsey, Alan S.: Polymeric Enzymes and Enzyme Analogs. J. Makromol. Chem. C 3, 1 (1969).

    Google Scholar 

  134. Manassen, J.: Catalysis of a Symmetry Restricted Reaction by Transition Metal Complexes. The Importance of the Ligand. J. Catalysis 18, 38 (1970).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Plastics Research Laboratory, The Weizmann Institute of Science, Rehovot, Israel

    Dr. Joost Manassen

Authors
  1. Dr. Joost Manassen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1972 Springer-Verlag

About this paper

Cite this paper

Manassen, J. (1972). The catalytic activity of organic and metallo-organic compounds in heterogeneous systems. In: Catalysis. Fortschritte der Chemischen Forschung, vol 25/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051368

Download citation

  • DOI: https://doi.org/10.1007/BFb0051368

  • Received:

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-05542-6

  • Online ISBN: 978-3-540-36876-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation