Skip to main content

The kinetics and mechanism of N-carboxy-α-amino-acid anhydride (NCA) polymerisation to poly-amino acids

  • Conference paper
  • First Online:
Fortschritte der Hochpolymeren-Forschung

Part of the book series: Advances in Polymer Science ((POLYMER,volume 4/1))

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Leuchs, H.: Ber. 39, 857 (1906).

    CAS  Google Scholar 

  2. Leuchs, H., and W. Manasse: Ber. 40, 3235 (1907).

    CAS  Google Scholar 

  3. —, and W. Geiger: Ber. 41, 1721 (1908).

    CAS  Google Scholar 

  4. Katchalski, E., and M. Sela: Advances in Protein Chem. 13, 249 (1958).

    Google Scholar 

  5. Bartlett, P. D., and R. H. Jones: J. Am. Chem. Soc. 79, 2153 (1957).

    Article  CAS  Google Scholar 

  6. Miller, E., I. Fankuchen, and H. Mark: J. Appl. Phys. 20, 531 (1949).

    Article  CAS  Google Scholar 

  7. See, e.g. M. Sela, and E. Katchalski: J. Am. Chem. Soc. 76, 129 (1956).

    Article  Google Scholar 

  8. Dieckmann, W., and F. Breest: Ber. 39, 3052 (1906).

    CAS  Google Scholar 

  9. Kopple, K. D.: J. Am. Chem. Soc. 79, 6442 (1957).

    Article  CAS  Google Scholar 

  10. Heyns, K., and R. Brockmann: Z. Naturforsch. 9b, 21 (1954).

    CAS  Google Scholar 

  11. Fuchs, F.: Ber. 55, 2943 (1922).

    Google Scholar 

  12. Wessely, F.: Z. physiol. Chem. 146, 72 (1925).

    Google Scholar 

  13. —, and F. Sigmund: Z. physiol. Chem. 157, 91 (1926).

    Google Scholar 

  14. Hanby, W. E., S. G. Waley, and J. Watson: J. Chem. Soc. 1950, 3009.

    Google Scholar 

  15. Waley, S. G., and J. Watson: Proc. Roy. Soc. A 199, 499 (1949).

    Google Scholar 

  16. Fessler, J. H., and A. G. Ogston: Trans. Faraday Soc. 47, 667 (1951).

    Article  CAS  Google Scholar 

  17. Pope, M. T., T. J. Weakley, and R. J. P. Williams: J. Chem. Soc. 1959, 3442.

    Google Scholar 

  18. Lundberg, R. D., and P. Doty: J. Am. Chem. Soc. 79, 3961 (1957).

    Article  CAS  Google Scholar 

  19. Bamford, C. H., and H. Block: In: Polyamino Acids, Polypeptides and Proteins, p. 65. Wisconsin University Press 1962.

    Google Scholar 

  20. Bailey, J. L.: J. Chem. Soc. 1950, 3461.

    Google Scholar 

  21. Ballard, D. G. H., and C. H. Bamford: Proc. Roy. Soc. A223, 495 (1954).

    CAS  Google Scholar 

  22. Heyns, K., H. Schultze, and R. Brockmann: Ann. 611, 33 (1958).

    CAS  Google Scholar 

  23. —, and H. Schultze: Ann. 611, 40 (1958).

    CAS  Google Scholar 

  24. Sela, M., and A. Berger: J. Am. Chem. Soc. 77, 1893 (1955).

    Article  CAS  Google Scholar 

  25. Kopple, K. D.: J. Am. Chem. Soc. 79, 662 (1957).

    Article  CAS  Google Scholar 

  26. Hanby, W. E., S. G. Waley, and J. Watson: J. Chem. Soc. 1950, 3239.

    Google Scholar 

  27. Mitchell, J. C., A. E. Woodward, and P. Doty: J. Am. Chem. Soc. 79, 3955 (1957).

    Article  CAS  Google Scholar 

  28. Wessely, F., and M. John: Z. physiol. Chem. 170, 38 (1927).

    CAS  Google Scholar 

  29. Woodward, R. B., and C. H. Schramm: J. Am. Chem. Soc. 69, 1551 (1947).

    Article  CAS  Google Scholar 

  30. Sluyterman, L. A., and A. Labruyere: Rec. trav. chim. 73, 347 (1954).

    CAS  Google Scholar 

  31. Coleman, D., and A. C. Farthing: J. Chem. Soc. 1950, 3218.

    Google Scholar 

  32. Breitenbach, J. W., and K. Allinger: Monatsh. Chem. 84, 1103 (1953).

    Article  CAS  Google Scholar 

  33. Frankel, M., and E. Katchalski: J. Am. Chem. Soc. 65, 1670 (1943).

    Article  CAS  Google Scholar 

  34. Faurholt, C.: J. chim. phys. 22, 1 (1925).

    CAS  Google Scholar 

  35. Weingarten, H.: J. Am. Chem. Soc. 80, 352 (1958).

    Article  CAS  Google Scholar 

  36. Shalitin, Y.: Ph. D. Thesis, Hebrew University (1958).

    Google Scholar 

  37. Blout, E. R., and A. Asadourian: J. Am. Chem. Soc. 78, 955 (1956).

    Article  CAS  Google Scholar 

  38. Doty, P., and R. D. Lundberg: J. Am. Chem. Soc. 78, 4810 (1956).

    Article  CAS  Google Scholar 

  39. Katchalski, E., Y. Shalitin, and M. Gehatia: J. Am. Chem. Soc. 77, 1925 (1955).

    Article  CAS  Google Scholar 

  40. Ballard, D. G. H., and C. H. Bamford: J. Am. Chem. Soc. 79, 2336 (1957).

    Article  CAS  Google Scholar 

  41. Doty, P., and R. D. Lundberg: J. Am. Chem. Soc. 79, 2338 (1957).

    Article  CAS  Google Scholar 

  42. Ballard, D. G. H., C. H. Bamford, and A. Elliott: Makromol. Chem. 35, 222 (1960).

    Article  CAS  Google Scholar 

  43. Bilek, L., J. Derkosch, H. Michl, and F. Wessely: Monatschr. Chem. 84, 717 (1953).

    Article  CAS  Google Scholar 

  44. Coleman, D.: J. Chem. Soc. 1950, 3222.

    Google Scholar 

  45. Ballard, D. G. H., and C. H. Bamford: J. Chem. Soc. 1956, 381.

    Google Scholar 

  46. — —, and F. J. Weymouth: Proc. Roy. Soc. 227 A, 155 (1955).

    Google Scholar 

  47. Kurtz, J., G. D. Fasman, A. Berger, and E. Katchalski: J. Am. Chem. Soc. 80, 393 (1958).

    Article  CAS  Google Scholar 

  48. Bamford, C. H., H. Block, and A. C. P. Pugh: J. Chem. Soc. 1961, 2057.

    Google Scholar 

  49. Blout, E. R., R. H. Karlson, P. Doty, and B. Hargitay: J. Am. Chem. Soc. 76, 4492 (1954).

    Article  CAS  Google Scholar 

  50. Doty, P., A. M. Holtzer, J. H. Bradbury, and E. R. Blout: J. Am. Chem. Soc. 76, 4493 (1954).

    Article  CAS  Google Scholar 

  51. Blout, E. R., and R. H. Karlson: J. Am. Chem. Soc. 78, 941 (1956).

    Article  CAS  Google Scholar 

  52. Idelson, M., and E. R. Blout: J. Am. Chem. Soc. 80, 2387 (1958).

    Article  CAS  Google Scholar 

  53. Bamford, C. H., and H. Block: J. Chem. Soc. 1961, 4989.

    Google Scholar 

  54. — — J. Chem. Soc. 1961, 4992.

    Google Scholar 

  55. Patchornik, A., and Y. Shalitin: Anal. Chemistry 33, 1887 (1961).

    Article  CAS  Google Scholar 

  56. Idelson, M., and E. R. Blout: J. Am. Chem. Soc. 79, 3948 (1957).

    Article  CAS  Google Scholar 

  57. Ballard, D. G. H., and C. H. Bamford: Special Publication of Chem. Soc. No. 2, p. 25 (1955).

    Google Scholar 

  58. Goodman, M., and U. Arnon: Biopolymers. 1, 500 (1963).

    Article  CAS  Google Scholar 

  59. Wieland, T.: Angew. Chem. 63, 7 (1951).

    CAS  Google Scholar 

  60. Angew. Chem. 66, 507 (1954).

    CAS  Google Scholar 

  61. Gold, V., and E. G. Jefferson: J. Chem. Soc. 1953, 1409 and 1416.

    Google Scholar 

  62. Walker, E. E.: Proceeding International Colloquium on Macromolecules. Amsterdam (1949), p. 381.

    Google Scholar 

  63. Peggion, E., A. Cosani, A. M. Mattucci, and E. Scoffone: Biopolymers. 2, 69 (1964).

    Article  Google Scholar 

  64. Champetier, G., and H. Sekiguchi: J. Polymer Sci. 48, 309 (1960) contains the previous references. See also for a review: M. Szwarc: Progress in Chemical Kinetics, vol. 4, p. 226. Oxford: Pergamon Press 1964.

    Article  CAS  Google Scholar 

  65. Blout, E. R., and M. Idelson: Polyamino Acids, Polypeptides and Proteins, p. 79. The University of Wisconsin Press 1962.

    Google Scholar 

  66. Katchalski, E., and M. Sela: ref. 3, p. 62.

    Google Scholar 

  67. Kopple, K. D., and J. J. Katz: J. Am. Chem. Soc. 78, 6199 (1956); J. Org. Chem. 27, 1062 (1962).

    Article  CAS  Google Scholar 

  68. Pauling, L., R. B. Corey, and H. L. Branson: Proc. Nat. Acad. Sci. 37, 205 and 235 (1951).

    Google Scholar 

  69. Luzzati, V., M. Cesari, G. Spach, F. Marson, and J. M. Vincent: Polyamino Acids etc. p. 121. The Wisconsin University Press 1962.

    Google Scholar 

  70. Astbury, W. T., and A. Idveet: Phil. Trans. Roy. Soc. A 230, 75 (1931).

    Google Scholar 

  71. , and H. J. Woods: Phil. Trans. Roy. Soc. A 232, 333 (1933).

    Google Scholar 

  72. Ambrose, E. J., and A. Elliott: Proc. Roy. Soc. 205A, 47 (1951).

    Google Scholar 

  73. Bamford, C. H., W. E. Hanby, and F. Happey: Proc. Roy. Soc. 206 A, 407 (1951).

    Google Scholar 

  74. Elliott, A.: Proc. Roy. Soc. 221 A, 104 (1953).

    Google Scholar 

  75. Doty, P., A. M. Holtzer, J. H. Bradbury, and E. R. Blout: J. Am. Chem. Soc. 76, 4493 (1954).

    Article  CAS  Google Scholar 

  76. Schellman, C. G., and J. A. Schellman: Compt. rend. trav. lab., Carlsberg, Ser. chim. 30, 465 (1958).

    CAS  Google Scholar 

  77. Zimm, B. H., and J. K. Bragg: J. Chem. Phys. 28, 1246 (1958); 31, 526 (1959).

    Article  CAS  Google Scholar 

  78. Goodman, M., and K. C. Stueben: J. Am. Chem. Soc. 81, 3980 (1959).

    Article  CAS  Google Scholar 

  79. —, E. E. Schmitt, and D. A. Yphantis: J. Am. Chem. Soc. 84, 1283 (1962).

    Article  CAS  Google Scholar 

  80. Doty, P., and J. T. Yang: J. Am. Chem. Soc. 78, 498 (1956); 79, 761 (1957).

    Article  CAS  Google Scholar 

  81. See also W. Moffitt, and J. T. Yang: Proc. Nat. Acad. Sci. 42, 596 (1956).

    CAS  Google Scholar 

  82. Goodman, M., and E. E. Schmitt: J. Am. Chem. Soc. 81, 5507 (1959).

    Article  CAS  Google Scholar 

  83. Doty, P., A. M. Holtzer, J. H. Bradbury, and E. R. Blout: J. Am. Chem. Soc. 76, 4493 (1954).

    Article  CAS  Google Scholar 

  84. Yphantis, D. A.: Ann. N. Y. Acad. Sci. 88, 586 (1960).

    CAS  Google Scholar 

  85. Goodman, M., E. E. Schmitt, and D. A. Yphantis: J. Am. Chem. Soc. 82, 3483 (1960).

    Article  CAS  Google Scholar 

  86. — — —J. Am. Chem. Soc. 84, 1288 (1962).

    Article  CAS  Google Scholar 

  87. e. g. K. Rosenheck, and P. Doty: Proc. Nat. Acad. Sci. 47, 1775 (1961).

    CAS  Google Scholar 

  88. Goodman, M., and I. Listowsky: J. Am. Chem. Soc. 84, 3770 (1962).

    Article  CAS  Google Scholar 

  89. —, and F. Boardman: J. Am. Chem. Soc. 85, 2483 (1963).

    Article  CAS  Google Scholar 

  90. — —, and I. Listowsky: J. Am. Chem. Soc. 85, 2491 (1963).

    Article  CAS  Google Scholar 

  91. Karlson, R. H., K. S. Norland, G. D. Fasman, and E. R. Blout: J. Am. Chem. Soc. 82, 2268 (1960).

    Article  CAS  Google Scholar 

  92. Elliott, A., E. M. Bradbury, A. R. Downie, and W. E. Hanby: Proc. Roy. Soc. A 259, 110 (1960).

    Google Scholar 

  93. See e. g., E. R. Blout: In: Optical Rotatory Dispersion; chapter 17. McGraw-Hill 1961.

    Google Scholar 

  94. Liquori, A. M., et al.: In the course of publication.

    Google Scholar 

  95. Santis, P. de, E. Giglio, A. M. Liquori, and A. Ripamonti: J. Polymer Sci. 1 A, 1383 (1963).

    Google Scholar 

  96. Coombes, J. D., and E. Katchalski: J. Am. Chem. Soc. 82, 5280 (1960).

    Article  CAS  Google Scholar 

  97. Huggins, M. L.: J. Am. Chem. Soc. 74, 3963 (1952).

    Google Scholar 

  98. Szwarc, M.: Chem. and Ind. p. 1589 (1958).

    Google Scholar 

  99. Williams, J. L. R., T. M. Laakso, and W. J. Dulmage: J. Org. Chem. 23, 638 (1958).

    Article  CAS  Google Scholar 

  100. Ham, G. E.: J. Polymer Sci. 40, 569 (1959).

    Article  CAS  Google Scholar 

  101. Glusker, D. L., I. Lysloff, and E. Stiles: J. Polymer Sci. 49, 315 (1961).

    Article  CAS  Google Scholar 

  102. Szwarc, M.: In: The Progress in Chemical Kinetics, Vol. II, p. 228. Oxford: Pergamon Press 1964.

    Google Scholar 

  103. Norrish, R. G. W., and R. R. Smith: Nature 150, 336 (1942).

    CAS  Google Scholar 

  104. Tromsdorff, E., H. Köhle, and P. Lagally: Makromolek. Chem. 1, 169 (1947).

    Article  Google Scholar 

  105. Benson, S. W., and A. M. North: J. Am. Chem. Soc. 81, 1339 (1959).

    Article  CAS  Google Scholar 

  106. North, A. M., and G. A. Reed: Trans. Faraday Soc. 57, 859 (1961).

    Article  CAS  Google Scholar 

  107. Ballard, D. G. H., and C. H. Bamford: J. Chem. Soc. 1959, 1039.

    Google Scholar 

  108. — —Proc. Roy. Soc. A 236, 384 (1956).

    Google Scholar 

  109. Goodman, M., and U. Arnon: J. Amer. Chem. Soc. 86, 3384 (1964).

    Article  CAS  Google Scholar 

  110. Fasmen, G. D., and E. R. Blout: Biopolymers 1, 3 (1963).

    Article  Google Scholar 

  111. — —Biopolymers 1, 99 (1963).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1965 Springer-Verlag

About this paper

Cite this paper

Szwarc, M. (1965). The kinetics and mechanism of N-carboxy-α-amino-acid anhydride (NCA) polymerisation to poly-amino acids. In: Fortschritte der Hochpolymeren-Forschung. Advances in Polymer Science, vol 4/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0050964

Download citation

  • DOI: https://doi.org/10.1007/BFb0050964

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-03245-8

  • Online ISBN: 978-3-540-37126-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics