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Isotope equilibrium of hydrogen with hydrite phases (thermodynamic isotope effect)

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Interaction of Hydrogen Isotopes with Transition Metals and Intermetallic Compounds

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References

Chapter 3

  1. P. W. Albers, G. H. Sicking, D. K. Ross: J. Phys. Condens. Matter 1, 6025 (1989)

    Article  ADS  Google Scholar 

  2. J. J. Rush, J. M. Rowe, D. Richter: Z. Phys. B-Condens. Matter 55, 283 (1984)

    Article  ADS  Google Scholar 

  3. D. Basmadjian: Can. J. Chem. 38, 149 (1960)

    Article  Google Scholar 

  4. W. E. Kochurikhin, Ya. D. Zelvenskii: Zh. Fiz. Khim. 38, 2594 (1964) (in Russian)

    Google Scholar 

  5. B. M. Andreev, M. M. Domanov, G. I. Medvedeva: Isotopenpraxis 6, 236 (1971)

    Google Scholar 

  6. B. Andreev, V. Shitikov, E. Magomedbekov, A. Shafiev: J. Less-Common Met. 90, 161 (1983)

    Article  Google Scholar 

  7. B. M. Andreev, O. V. Dobryanin, E. P. Magomedbekov, Yu. S. Pak, V. V. Shitikov: Zh. Fiz. Khim. 56, 463 (1982) (in Russian)

    Google Scholar 

  8. B. M. Andreev, E. P. Magomedbekov, A. S. Polevoi: Tr. Mosk. Khim.-Tekhnol. Inst. im. D.I. Mendeleeva 130, 45 (1984) (in Russian)

    Google Scholar 

  9. R. H. Wiswall, J. J. Reily: Inorg. Chem. 11, 1691 (1972)

    Article  Google Scholar 

  10. S. Imoto, T. Tanaba, K. Utsunomiya: Int. J. Hydr. Energy 7, 597 (1982)

    Article  Google Scholar 

  11. M. Karas, E. P. Magomedbekov, G. H. Sicking: J. Less-Common Met. 159, 307 (1990)

    Article  Google Scholar 

  12. B. M. Andreev, A. S. Polevoi, A. N. Perevezentsev: At. Energy 45, 53 (1978) (in Russian)

    Article  Google Scholar 

  13. G. Sicking, E. Magomedbekov, R. Hempelmann: Ber. Bunsenges. Phys. Chem. 85, 686 (1981)

    Article  Google Scholar 

  14. A. I. Brodskii: Chemistry of Isotopes (Akad. Nauk SSSR, Moscow 1957) pp. 1–594 (in Russian)

    Google Scholar 

  15. B. M. Andreev, Ya. D. Zelvenskii, S. G. Katalnikov: Heavy Hydrogen Isotopes in Nuclear Technology (Energoatomisdat. Moscow 1987) pp. 1–456 (in Russian)

    Google Scholar 

  16. J. Bron, C. F. Chang, M. Wolfsberg: Z. Naturforschung 28a, 129 (1972)

    ADS  Google Scholar 

  17. G. Sicking: Z. Phys. Chem. NF 93, 53 (1974)

    Article  Google Scholar 

  18. G. Sicking, E. Magomedbekov: Met.-Hydrogen Syste., Proc. Miami Int. Symp., Miami Beach, Florida, USA, April 13–15, 1981, ed. by T. N. Veziroglu (Pergamon, Oxford 1982) pp. 71–88

    Google Scholar 

  19. B. M. Andreev, E. P. Magomedbekov, V. V. Shitikov: At. Energy 55, 102 (1983) (English transl: Sov. At. Energy 55, 535 (1983))

    Article  Google Scholar 

  20. G. Sicking: J. Less-Common Met. 101, 169 (1984)

    Article  Google Scholar 

  21. B. M. Andreev, G. H. Sicking: Ber. Bunsenges. Phys. Chem. 91, 177 (1987)

    Article  Google Scholar 

  22. B. M. Andreev, A. N. Perevezentsev, I. L. Selivanenko: Isotope Separation and Chemical Exchange Uranium Enrichment Proc. Int. Symp., Tokio, Japan, October 29–November 1, 1990, ed. by Y. Fujii, T. Ishida, K. Takeuchi, Bull. Research Lab. Nucl. Reactors 1, 1 (1992)

    Google Scholar 

  23. Ya. M. Warshawskii, S. E. Waysberg: Zh. Fiz. Khim. 29, 523 (1955) (in Russian)

    Google Scholar 

  24. V. S. Parbuzin, N. I. Malyavskii: Zh. Fiz. Khim. 50, 2944 (1976) (in Russian)

    Google Scholar 

  25. N. I. Malyavskii, V. S. Parbuzin: Vestn. Mosk. Univ., Ser. Khim. 18, 111 (1977) (in Russian)

    Google Scholar 

  26. B. M. Andreev, Ya. D. Zelvenskii, S. G. Katalnikov, W. W. Uborskii: Isotopenpraxis 12, 440 (1977) (in Russian)

    Google Scholar 

  27. F. Botter: J. Phys. Chem. 69, 2485 (1965)

    Article  Google Scholar 

  28. F. Botter: J. Less-Common Met. 49, 111 (1976)

    Article  Google Scholar 

  29. E. Wicke, G. Nernst: Ber. Bunsenges. Phys. Chem. 68, 224 (1964)

    Article  Google Scholar 

  30. M. N. Domanov, B. M. Andreev, S. E. Gilburd: Tr. Mosk. Khim.-Tekhnol. Inst. im. D.I. Mendeleeva 67, 104 (1970) (in Russian)

    Google Scholar 

  31. F. Botter; Isotope Effects in Physical and Chemical Processes Int. Meeting, Cluj. Roumania, June 25–28, 1973

    Google Scholar 

  32. G. Sicking: Ber. Bunsenges. Phys. Chem. 76, 790 (1972)

    Google Scholar 

  33. B. M. Andreev, M. M. Domanov: Zh. Fiz. Khim. 49, 1258 (1975) (in Russian)

    Google Scholar 

  34. B. M. Andreev, A. N. Perevezentsev, I. A. Mandrykin, N. F. Myasoedov: Radiokhimia 28, 212 (1986) (English transl.: Sov. Radiochem. 28, 188 (1986))

    Google Scholar 

  35. T. Tanabe, S. Miura, S. Imoto: J. Nucl. Sci. Technol. 16, 690 (1979)

    Article  Google Scholar 

  36. B. M. Andreev, E. P. Magomedbekov, V. V. Shititkov: Zh. Fiz. Khim. 58, 2418 (1984) (in Russian)

    Google Scholar 

  37. A. S. Horen, M. W. Lee: Fus. Technol. 21, 282 (1992)

    Google Scholar 

  38. T. R. P. Gibb: Adv. Chem. Ser. 39, 99 (1992)

    Article  Google Scholar 

  39. G. G. Libowitz: The Solid State Chemistry of Binary Metal Hydrides (Benjamin, New York 1965)

    Google Scholar 

  40. N. F. Mott, H. Jones: The Theory of the Properties of Metals and Alloys (Clarendon, Oxford 1936)

    Google Scholar 

  41. D. Zamir: Phys. Rev. 140, A271 (1965)

    Article  ADS  Google Scholar 

  42. K. F. Herzfeld, M. Goeppert-Mayer: Z. Phys. Chem. 26, 203 (1934)

    Google Scholar 

  43. Y. Ebisuzaki, M. O'Keeffe: Prog. Solid State Chem. 4, 187 (1967)

    Article  Google Scholar 

  44. C. Kittel: Introduction to Solid State Physics 2nd ed. (Wiley, New York 1956)

    MATH  Google Scholar 

  45. J. M. Ziman: Adv. Phys. 13, 89 (1964)

    Article  ADS  Google Scholar 

  46. A. I. Gubanov, V. K. Nikulin: Sov. Phys. Solid State 7, 2184 (1965)

    Google Scholar 

  47. J. J. Rush, R. C. Livingston, L. A. de Graaf, H. E. Flotow, J. M. Rowe: J. Chem. Phys. 59, 6570 (1973)

    Article  ADS  Google Scholar 

  48. A. Magerl, N. Stump, W. D. Teuchert, V. Wagner, G. Alefeld: J. Phys. C., Solid State Phys. 10, 2783 (1977)

    Article  ADS  Google Scholar 

  49. R. Yamada, N. Watanabe, K. Sato, H. Asano, M. Hirabayashi: J. Phys. Soc. Japan 41, 85 (1976)

    Article  ADS  Google Scholar 

  50. G. Verdan, R. Rubin, W. Kley: Neutron Inelastic Scattering Proc IAEA, Vienna (1968) p. 223

    Google Scholar 

  51. N. Stump, G. Alefeld, D. Tochetti: Solid State Commun. 19, 805 (1976)

    Article  ADS  Google Scholar 

  52. T. Springer: “Investigations of Vibrations in Metal Hydrides” in Topics Appl. Phys. Vol. 28 (Springer, Berlin, Heidelberg 1978) p. 75

    Google Scholar 

  53. N. A. Chernoplekov, M. G. Zemlyanov, V. A. Somenkov, A. A. Chertkov: Sov. Phys. Solid State 10, 2783 (1977)

    Article  Google Scholar 

  54. D. K. Ross, P. F. Martin, W. A. Oates, R. Khoda-Bakhsh: Z. Phys. Chem. 114, 221 (1979)

    Article  Google Scholar 

  55. R. Khoda-Bakhsh, D. K. Ross: J. Phys. F: Met Phys. 12, 15 (1982)

    Article  ADS  Google Scholar 

  56. J. J. Rush, N. F. Berk, A. Magerl, J. M. Rowe: Phys. Rev. B 37, 7901 (1988)

    Article  ADS  Google Scholar 

  57. J. J. Rush, H. E. Flotow: J. Chem. Phys. 48, 3795 (1968)

    Article  ADS  Google Scholar 

  58. R. Hempelmann, D. Richter, B. Stritzker: J. Phys. F: Met. Phys. 12, 79 (1982)

    Article  ADS  Google Scholar 

  59. W. Drexel, A. Murani, D. Tochetti, W. Kley, I. Sosnowska, D. K. Ross: J. Phys. Chem. Solids 37, 1135 (1976)

    Article  ADS  Google Scholar 

  60. D. G. Hunt, D. K. Ross: J. Less-Common Met. 49, 169 (1976)

    Article  Google Scholar 

  61. A. J. Maeland: J.Chem. Phys. 52, 3952 (1970)

    Article  ADS  Google Scholar 

  62. W. Wagener, P. Vorderwisch, S. Hautecler: Phys. Status Solidi B 98K, 171 (1980)

    Article  ADS  Google Scholar 

  63. P. Vorderwisch, S. Hautecler, H. Deckers: Phys. Status Solidi B 65, 171 (1974)

    Article  ADS  Google Scholar 

  64. J. J. Rush, H. E. Flotow, D. W. Connor, C. L. Thaper: J. Chem. Phys. 45, 3817 (1966)

    Article  ADS  Google Scholar 

  65. M. Saad: Atomkernenergie 17, 281 (1971)

    Google Scholar 

  66. O. de Pous, H. M. Lutz: Second Int. Cong. Hydr. in Met., June 6–11, Paris 1977, P. 1E8

    Google Scholar 

  67. O. de Pous, H. M. Lutz: Proc. 2nd World Hydrogen Energy Conf., Zürich 1977 (Pergamon, Oxford 1978) p. 1597

    Google Scholar 

  68. H. Sugimoto, Y. Fukai: J. Phys. Soc. Japan 51, 2554 (1982)

    Article  ADS  Google Scholar 

  69. Y. Fukai: J. Less-Common Met. 101, 1 (1984)

    Article  Google Scholar 

  70. Y. Fukai: J. Less-Common Met. 172–174, 8 (1991)

    Article  Google Scholar 

  71. B. Baranowski, S. Majchrzak, T. Flanagan: J. Phys. F 1, 288 (1971)

    Article  ADS  Google Scholar 

  72. Y. Wong, F. B. Hill: AlChE 25, 592 (1979)

    Article  Google Scholar 

  73. T. Schober: In it Electronic Structure and Properties of Hydrogen in Metals, ed. by P. Jena, C. B. Satterthwaite (Plenum, New York 1983) p. 1

    Chapter  Google Scholar 

  74. R. Lässer, K.-H. Klatt, P. Mecking, H. Wenzl: Ber. KFA Jülich 1800 (1982)

    Google Scholar 

  75. R. Lässer, T. Schober: J. Less-Common Met. 130, 453 (1987)

    Article  Google Scholar 

  76. I. R. Entin, V. A. Somenkov, S. Sh. Shilshtein: Sov. Phys. Solid State 16, 1569 (1975)

    Google Scholar 

  77. R. Hempelmann, D. Richter, D. L. Price: Phys. Rev. Lett. 58, 1016 (1987)

    Article  ADS  Google Scholar 

  78. R. Hempelmann, D. Richter, D. L. Price: J. Less-Common Met. 130, 203 (1987)

    Article  Google Scholar 

  79. D. Klauder, V. Lottner, H. Scheuer: Solid State Comm. 32, 617 (1979)

    Article  ADS  Google Scholar 

  80. J. H. Wernick: In Intermetallic Compounds, ed. by H. Westbrook (Wiley, New York 1967) p. 197

    Google Scholar 

  81. W. B. Pearson: Lattice Spacing and Structures of Metals and Alloys (Pergamon, Oxford 1958)

    Google Scholar 

  82. L. Pauling: The Nature of the Chemical Bond, 3rd edn. (Cornell. Univ. Press, Ithaca 1960)

    MATH  Google Scholar 

  83. J. Tanaka, R. H. Wiswall, J. J. Reilly: Inorg. Chem. 17, 498 (1978)

    Article  Google Scholar 

  84. E. P. Magomedbekov, B. M. Andreev, A. V. Korolev: Zh. Fiz. Khim. 64, 434 (1990) (in Russian)

    Google Scholar 

  85. B. Baranowski: “Metal-hydrogen Systems at High Hydrogen Pressures” in Hydrogen in Metals, ed. by G. Alefeld, J. Volkl, Topics Appl. Phys. Vol. 29 (Springer, Berlin, Heidelberg 1978) p. 157

    Chapter  Google Scholar 

  86. J. F. Lynch, J. J. Reilly, J. Tanaka: “The Titanium-Molybdenum-Hydrogen System: Isotope Effects, Thermodynamics, and Phase Changes” in Trans. Met. Hydr., ed. by R. Bau (Am. Chem. Soc., Washington 1978) p. 342

    Chapter  Google Scholar 

  87. M. Devillers, M. Sirch, R. D. Penzhorn: Z. Phys. Chem. NF 164, 1355 (1989)

    Article  Google Scholar 

  88. I. I. Wedernikova, E. P. Magomedbekov, B. M. Andreev, A. V. Krupentshenko, A. V. Korolev: Zh. Fiz. Khim. 65, 1657 (1991) (in Russian)

    Google Scholar 

  89. B. Jungblut, G. Sicking: Z. Phys. Chem. NF 164, 1177 (1989)

    Article  Google Scholar 

  90. I. Jacob, A. Stern, A. Moran, D. Shaltiel, D. Davidov: J. Less-Common Met. 73, 369 (1980)

    Article  Google Scholar 

  91. F. T. Aldridge: J. Less-Common Met. 108, 131 (1985)

    Article  Google Scholar 

  92. G. D. Sandrock, J. J. Murray, M. L. Post, J. B. Taylor: Mat. Res. Bull. 17, 887 (1982)

    Article  Google Scholar 

  93. D. G. Westlake: J. Less-Common Met. 91, 275 (1983)

    Article  Google Scholar 

  94. R. Hempelmann, D. Richter, G. Eckold, J. J. Rush, J. M. Rowe, M. Montoya: J. Less-Common Met. 104, 1 (1984)

    Article  Google Scholar 

  95. D. G. Westlake: J. Mater. Sci. 19, 316 (1984)

    Article  ADS  Google Scholar 

  96. J. Shinar, D. Shaltiel, D. Davidov, A. Grayewski: J. Less-Common Met. 60, 209 (1978)

    Article  Google Scholar 

  97. R. L. Beck: “Investigation of Hydriding Characteristics of Intermetallic Compounds” (Lar-55-Denver Research Institute, 1961)

    Google Scholar 

  98. F. Pourarian, H. Fujii, W. E. Wallace, V. K. Sinha, H. K. Smith: J. Phys. Chem. 85, 3105 (1981)

    Article  Google Scholar 

  99. L. Pontonnier, S. Miraglia, D. Fruchart, J. L. Soubeyroux, A. Baudry, P. Boyer: J. Alloys Comp. 186, 241 (1992)

    Article  Google Scholar 

  100. J. H. N.van Vucht, F. A. Kuijpers, H. C. A. M. Bruning: Philips. Res. Rep. 25, 133 (1970)

    Google Scholar 

  101. A. Drasner, Z. Blazina: J. Less-Common Met. 168, 289 (1991)

    Article  Google Scholar 

  102. F. Pourarian, W. E. Wallace: J. Solid State Chem. 55, 181 (1984)

    Article  ADS  Google Scholar 

  103. J. Bergsma, J. Goedkoop: Physica 26, 744 (1960)

    Article  ADS  Google Scholar 

  104. G. Boureau, O. Kleppa, P. Dantzer: J. Chem. Phys. 64, 5247 (1976)

    Article  ADS  Google Scholar 

  105. E. Glueckauf, G. P. Kitt: Isotope Separation Proc. Int. Symp. Amsterdam 1957 (North-Holland, Amsterdam 1958) p. 210

    Google Scholar 

  106. G. Sicking, P. Albers, E. Magomedbekov: J. Less-Common Met. 89, 373 (1983)

    Article  Google Scholar 

  107. P. Albers, Doctoral thesis, Münster, 1985

    Google Scholar 

  108. W. L. Whittemore, A. W. McReynolds: Inelastic Scattering of Neutrons in Solids and Liquids (IAEA, Vienna, 1961) p. 511

    Google Scholar 

  109. J. M. Rowe, J. J. Rush, H. G. M. Smith, H. E. Flotow: Phys. Rev. B14, 3630 (1976)

    ADS  Google Scholar 

  110. S. J. C. Irvine, D. K. Ross, I. R. Harris, J. D. Browne: J. Phys. F: Met. Phys. 14, 2881 (1984)

    Article  ADS  Google Scholar 

  111. E. Wicke, H. Brodowski: “Hydrogen in Palladium and Palladium Alloys”, in Hydrogen in Metals, ed. by G. Alefeld, J. Völkl, Topics Appl. Phys. Vol. 29 (Springer, Berlin, Heidelberg 1978) p. 73

    Chapter  Google Scholar 

  112. J. M. Nicol, J. J. Rush, R. D. Kelley: Phys. Rev. B 36, 9315 (1987)

    Article  ADS  Google Scholar 

  113. A. J. Renouprez, B. Fouillox, J. P. Candy: Surf. Sci. 83, 285 (1979)

    Article  ADS  Google Scholar 

  114. P. W. Albers, G. H. Sicking, D. K. Ross: J. Phys.: Condens. Matter 1, 6025 (1989)

    ADS  Google Scholar 

  115. B. M. Andreev, A. N. Perevezentsev: Zh. Fiz. Khim. 55, 2709 (1981) (English transl.: Russ. J. Phys. Chem. 55, 1545 (1981))

    Google Scholar 

  116. V. Trentin, Ph. Brassard, D. Schweich: Chem. Eng. Sci. 48, 873 (1993)

    Article  Google Scholar 

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Andreev, B., Magomedbekov, E., Sicking, G. (1996). Isotope equilibrium of hydrogen with hydrite phases (thermodynamic isotope effect). In: Andreev, B., Magomedbekov, E., Sicking, G. (eds) Interaction of Hydrogen Isotopes with Transition Metals and Intermetallic Compounds. Springer Tracts in Modern Physics, vol 132. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0045243

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