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Synthesis, electrochemistry, and structural properties of porphyrins with metal-carbon single bonds and metal-metal bonds

  • R. Guilard
  • C. Lecomte
  • K. M. Kadish
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 64)

Abstract

Porphyrins are known to coordinate with most of the metallic or pseudo-metallic elements. However, in spite of the large number of isolated metalloporphyrin derivatives, metal-carbon σ-bonded complexes are limited only to the following series: Fe, Ru, Co, Rh, Ir, Ti, Al, Ga, In, Tl, Si, Ge, Sn, and Zn.

These complexes are of great interest as model compounds for understanding the functions and relationships of several biological macromolecules, as well as for their chemical reactivity. In the latter case the insertion of small molecules between the metal ion and the carbon atom may result in activation of the inserted molecule or may generate new monomeric or polymeric materials. In addition, metal-carbon σ-bonded porphyrins can act as precursors in the synthesis of metal-metal bonded derivatives.

This review will cover the general strategies for synthesizing organometallic porphyrin complexes. Furthermore, we will also discuss the electrochemical and structural properties of metalloporphyrins from the viewpoint of organometallic chemistry. In doing this we will focus on the following points:
  1. (i)

    We will give a summary of the synthetic procedures and characteristics of metal-alkyl (aryl) σ-bonded porphyrins. Special emphasis will be placed on the magnetic properties of the ironcarbon porphyrin derivatives.

     
  2. (ii)

    The insertion of carbon dioxide and sulfur dioxide into the metal-carbon bond of metalloporphyrins containing main group metals such as Ga, In, and Al will be discussed.

     
  3. (iii)

    The synthesis of metal-metal bonded metalloporphyrins containing a σ-bond or a donor-acceptor bond will be presented; we will also focus on the structural and electrochemical properties of some typical compounds.

     

Keywords

High Spin Axial Ligand Aryl Group Porphyrin Ring Iron Porphyrin 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1987

Authors and Affiliations

  • R. Guilard
    • 1
  • C. Lecomte
    • 2
  • K. M. Kadish
    • 3
  1. 1.Faculté des Sciences “Gabriel”Laboratoire de Synthèse et d'Electrosynthèse Organométallique associé au C.N.R.S. (UA 33)DijonFrance
  2. 2.Faculté des Sciences, Centre de 2eme CycleLaboratoire de Minéralogie et Cristallographie (UA CNRS 809)Vand∄uvre les Nancy CedexFrance
  3. 3.Department of ChemistryUniversity of HoustonHoustonUSA

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