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Progress in polymetallic exchange-coupled systems; some examples in inorganic chemistry

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Complexes, Clusters and Crystal Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 79))

Abstract

The aim of this paper is to review some basic concepts needed for describing polymetallic exchange-coupled systems and to treat problems of current interest in inorganic chemistry.

First, a brief survey of a priori conflicting descriptions of the exchange mechanisms is proposed. The overlap between the Heisenberg and Anderson models is demonstrated in the limiting case of highly distorted systems, in which the orbital degeneracy of interacting ions is removed. Then, the correlations between magnetic properties and structural features are discussed for some series of compounds characterized by specific arrangements of the metal ions such as dimers, trimers ... The sign and magnitude of the exchange parameters are shown to depend on different factors such as the ground-state of the interacting ions, the geometry of the species, and the nature of the bridging ligands.

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Authors and Affiliations

  1. Groupe des Matériaux Inorganiques, IPCMS-EHICS, 1 rue B. Pascal, 67008, Strasbourg, France

    Marc Drillon

  2. Laboratoire de Chimie du Solide, CNRS, 351 cours de la Libération, 33405, Talence, France

    Jacques Darriet

Authors
  1. Marc Drillon
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  2. Jacques Darriet
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© 1992 Springer-Verlag

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Drillon, M., Darriet, J. (1992). Progress in polymetallic exchange-coupled systems; some examples in inorganic chemistry. In: Complexes, Clusters and Crystal Chemistry. Structure and Bonding, vol 79. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0036500

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  • DOI: https://doi.org/10.1007/BFb0036500

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-55095-2

  • Online ISBN: 978-3-540-46694-9

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