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Photochromic phenomena in the solid phase

  • G. Smets
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 50)

Abstract

Photochromic phenomena occurring in the solid phase are discussed first from the point of view of the influence of a polymer medium on the photochromic behavior and reaction reversibility. Inversely, in the second part, the influence of conformational changes of chain segments induced by chromophore isomerization is discussed with respect to the physical behavior of the polymer matrix, and especially concerning photomechanical effects.

Keywords

Methyl Methacrylate Bulk Polymer Ethyl Acrylate Photochromic Behavior Isophthaloyl Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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4 References

  1. 1.
    Irie, M., Hayashi, K.: Photochromic phenomena in liquid phase. Adv. Polym. Sci. Berlin, Heidelberg, New York: Springer Verlag, in pressGoogle Scholar
  2. 2.
    Kuhn W., Künzle, O., Katchalsky, A.: Bull. Soc. Chim. Belge 57, 421 (1948)Google Scholar
  3. 3.
    Katchalsky, A., Künzle, O., Kuhn, W.: J. Polym. Sci. 5, 283 (1950)CrossRefGoogle Scholar
  4. 4.
    Künzle, O.: Rec. Trav. Chim. Pays-Bas 67, 699 (1949)Google Scholar
  5. 5.
    Kuhn, W., Katchalsky, A., Eisenberg, H.: Nature 165, 514 (1950)Google Scholar
  6. 6.
    Katchalsky, A., Eisenberg, H.: Nature 166, 267 (1-50Google Scholar
  7. 7.
    Osada, Y., Y. Saito: Makromol. Chem. 176, 2761 (1975)CrossRefGoogle Scholar
  8. 8.
    Kun, W.: Angew. Chem. 70, 58 (1958)Google Scholar
  9. 9.
    Kuhn, W., Ramel, A., Walters, D. H.: Angew. Chem. 70, 314 (1958)Google Scholar
  10. 10.
    Kuhn, W., Ramel, A., Walters, D. H.: Size and shape changes of contractile polymers. Conversion of chemical into mechanical energy. Wasserman, A. (ed.), p. 41. New York: Pergamon Press 1960Google Scholar
  11. 11.
    Katchalsky, A., Zwick, M.: J. Polym. Sci. 16, 221 (1955)CrossRefGoogle Scholar
  12. 12.
    Kuhn, W., Toth, I., Kuhn, H. J.: Makromol. Chem. 60, 77 (1963)CrossRefGoogle Scholar
  13. 13.
    Osada, Y., Sato, M.: Polymer 21, 1061 (1980)CrossRefGoogle Scholar
  14. 14.
    Osada, Y.: J. Polym. Sci. Polym. Chem. Ed. 15, 255 (1977)CrossRefGoogle Scholar
  15. 15.
    Osada, Y.: J. Polym. Sci. Polym. Lett. Ed. 18, 281 (1980)CrossRefGoogle Scholar
  16. 16.
    Lovrien, R.: Proc. Nat. Acad. Sci. U.S. 57, 236 (1967)Google Scholar
  17. 17.
    Blair, H. S., Pogue, H. I., Riordan, E.: Polymer 21, 1195 (1980)CrossRefGoogle Scholar
  18. 18.
    Irie, M. et al.: Macromolecules 14, 262 (1981)Google Scholar
  19. 19.
    Irie, M., Schnabel, W.: Macromolecules 14, 1246 (1981)CrossRefGoogle Scholar
  20. 20.
    Matějka, L., Dušek, K.: Makromol. Chem. 182, 3223 (1981)CrossRefGoogle Scholar
  21. 21.
    Osada, Y., Katsumura, E.: Makromol. Chem. Rapid Commun. 2, 241 (1981); 2, 411 (1981)CrossRefGoogle Scholar
  22. 22.
    Irie, M. et al.: J. Polym. Sci. Polym. Lett. 17, 29 (1979)CrossRefGoogle Scholar
  23. 23.
    Irie, M. Menju, A., Hayashi, K.: Macromolecules 12, 1176 (1979)CrossRefGoogle Scholar
  24. 24.
    Menju, A., Hayashi, K., Irie, M.: Macromolecules 14, 755 (1981)CrossRefGoogle Scholar
  25. 25.
    Kamogawa, H., Kato, M., Sugiyama, H.: J. Polym. Sci. A-1 6, 2967 (1968)Google Scholar
  26. 26.
    Gardlund, Z. G.: J. Polym. Sci., 6, 57 (1968)CrossRefGoogle Scholar
  27. 27.
    Gardlund, Z. G., Laverty, J. J.: J. Polym. Sci., Polym. Lett. 7, 719 (1969)Google Scholar
  28. 28.
    Smets, G.: Pure Appl. Chem. 30, 1 (1972)Google Scholar
  29. 29.
    Verborgt, J., Smets, G.: J. Polym. Sci., Polym. Chem. Ed. 12, 2511 (1974)Google Scholar
  30. 30.
    Chaudé, O.: Cah. Phys. 52, 39 (1954)Google Scholar
  31. 31.
    Arnaud, J., Wippler, C., Beau d'Angères, F.: J. Chim. Phys. 64, 1165 (1967)Google Scholar
  32. 32.
    Eisenbach, C.: Makromol. Chem. 179, 2489 (1978)CrossRefGoogle Scholar
  33. 33.
    Eisenbach, C.: Polymer Bulletin 1, 517 (1979)CrossRefGoogle Scholar
  34. 34.
    Paik, C. S., Morawetz, H.: Macromolecules 5, 171 (1972)CrossRefGoogle Scholar
  35. 35.
    Vandewyer, P., Smets, G.: J. Polym. Sci. C22, 231 (1968)Google Scholar
  36. 36.
    Semts, G.: IUPAC Internat. Symp. Macromolecules, Budapest 1969, pp. 65–87Google Scholar
  37. 37.
    Miura, M. et al.: Polymer 19, 348 (1978)CrossRefGoogle Scholar
  38. 38.
    Heiligman-Rim, R., Hirshberg, Y., Fischer, E.: J. Phys. Chem. 66, 2465 (1962)Google Scholar
  39. 39.
    Kryszewski, M., Nadolski, B.: J. Polym. Sci., Polym. Chem. Ed. 13, 345 (1975)Google Scholar
  40. 40.
    Kryszewski, M., Nadolski, B.: Pure Appl. Chem. 49, 511 (1977)Google Scholar
  41. 41.
    Lawrie, N. C., North, A. M.: European Polym. J. 9, 348 (1973)Google Scholar
  42. 42.
    Kryszewski, M., Grachowska-Kapienis, D., Nadolski, B.: J. Polym. Sci., Polymer Chem. Ed. 11, 2423 (1973)Google Scholar
  43. 43.
    Smets, G., Thoen, J., Aerts, A.: J. Polym. Sci., Polym. Symp. 51, 119 (1975)Google Scholar
  44. 44.
    Smets, G., Braeken, J., Irie, M.: Pure Appl. Chem. 50, 845 (1978)Google Scholar
  45. 45.
    Flannery, J. B. Jr.: J. Amer. Chem. Soc. 90, 5660 (1968)CrossRefGoogle Scholar
  46. 46.
    Smets, G., Evens, G.: Pure Appl. Chem. Suppl. Macromol. Chem. 8, 357 (1973)Google Scholar
  47. 47.
    Eirich, F. R.: Rheology, theory and applications, Vol. I, p. 441–52. New York: Academic Press 1956Google Scholar
  48. 48.
    Williams, M. L., Landel, R. L., Ferry, J. D.: J. Amer. Chem. Soc. 37, 3701 (1955)CrossRefGoogle Scholar
  49. 49.
    Sevens, G.: Ph. D. thesis K. Universiteit Leuven, pp. 52–60, 1972Google Scholar
  50. 50.
    Eisenbach, C.: Ber. Bunsenges. Phys. Chem. 84, 680–90 (1980)Google Scholar
  51. 51.
    Eisenbach, C.: Photogr. Sci. Eng. 23, 183 (1979)Google Scholar
  52. 52.
    Eisenbach, C.: Polym. Bull. 2, 169 (1980)CrossRefGoogle Scholar
  53. 53.
    Sung, C. S. P., Lamarre, L., Chung, K. H.: Macromolecules 14, 1839 (1981)CrossRefGoogle Scholar
  54. 54.
    Van der Veen, G., Prins, W.: Nat. Phys. Sci. 230, 70 (1971)Google Scholar
  55. 55.
    Chuang, J. C., De Sorgo, M., Prins, W.: J. Mechanochem. Cell Mobility 2, 105 (1973)Google Scholar
  56. 56.
    Van der Veen, G., Hoguet, R., Prins, W.: Photochem. Photobiol. 19, 197 (1974)PubMedGoogle Scholar
  57. 57.
    Aviram, A.: Macromolecules 11, 1275 (1978)CrossRefGoogle Scholar
  58. 58.
    Smets, G.: Pure Appl. Chem. 30, 1 (1972)Google Scholar
  59. 59.
    Smets, G., De Blauwe, F.: Pure Appl. Chem. 39, 225 (1974)Google Scholar
  60. 60.
    Eisenbach, C. D.: Polymer 21, 1175 (1980)CrossRefGoogle Scholar
  61. 61.
    Matějika, L., Dušek, K., Ilavský, M.: Polym. Bulletin, 1, 659 (1979)Google Scholar
  62. 62.
    Matěika, L. et al.: Polymer 22, 1911 (1981)Google Scholar
  63. 63.
    Husy, H., Merian, E., Schetty, G.: Textile Res. J. 39, 94 (1969)Google Scholar
  64. 64.
    Blair, H. S., Kau Law, T.: Polymer 21, 1475 (1980)CrossRefGoogle Scholar
  65. 65.
    Blair, H. S., Pogue, H. I.: Polymer 23, 779 (1982)CrossRefGoogle Scholar
  66. 66.
    Agolini, F., Gay, F. P.: Macromolecules 3, 349 (1970)CrossRefGoogle Scholar
  67. 67.
    Blair, H. S., Pogue, H. I.: Polymer 20, 99 (1979)CrossRefGoogle Scholar
  68. 68.
    Gruler, H., Vilanove, R., Rondelez, F.: Phys. Rev. Lett. 44, 590 (1980)CrossRefGoogle Scholar
  69. 69.
    Vilanove, R. et al.: Macromolecules, in press (1982)Google Scholar

Copyright information

© Springer-Verlag 1983

Authors and Affiliations

  • G. Smets
    • 1
  1. 1.Laboratory of Macromolecular ChemistryK. Universiteit LeuvenBelgium

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