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Reactive surfactants in emulsion polymerization

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Polymer Synthesis

Part of the book series: Advances in Polymer Science ((POLYMER,volume 111))

Abstract

Covalent binding of the surfactants to the polymers obtained from emulsion polymerization is expected to improve some properties of the resulting latexes and also of the films formed from these latexes. This is possible if the surfactants include functional groups capable of interacting with the radical polymerization process. These functional groups may be a polymerizable function so that the surfactant is a comonomer, named in this review SURFMER. Alternatively it may be an initiator (INISURF) or a transfer agent (TRANSURF). The paper is a literature review of the state of the art and illustrates the increasing interest in this field. The main trends and some prospects are discussed in the conclusions.

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Abbreviations

AIBN:

Azobis isobutyronitrile

B:

Butyl acrylate

CMC:

Critical micellar concentration

DLVO:

DerJaguin, Landau, Verwey, Overbeek

e:

Charge parameter for a monomer

HLB:

Hydrophilic-lipophilic balance

H-SAAS:

Hydrogenated sodium alkyl allyl sulfosuccinate

ICI:

Imperial Chemical Industries

KPS:

Potassium persulfate

Na AAS:

Sodium 9 acrylamidostearate

NIAD:

Non-ionic aqueous dispersion

Q:

Reactivity parameter of a polymer radical

S:

Styrene

SAAS:

Sodium alkyl allyl sulfosuccinate

SAU:

Sodium acrylamido undecanoate

SDS:

Sodium dodecyl sulfate

SPM:

Sulfopropyl methacrylate

SSDSE:

Styrene sodium dodecyl sulfate ether

VA:

Vinyl acetate

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Author information

Authors and Affiliations

  1. CNRS — Laboratoire de Chimie et Procédés de Polymérisation, BP 24-69390, VERNAISON, France

    A. Guyot

  2. Max Planck Institute für Kolloid- und Grenzflächenforschung, Kantsraße 55, D-12169, Berlin, FRG

    K. Tauer

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  1. A. Guyot
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  2. K. Tauer
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© 1994 Springer-Verlag

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Guyot, A., Tauer, K. (1994). Reactive surfactants in emulsion polymerization. In: Polymer Synthesis. Advances in Polymer Science, vol 111. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0024126

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  • DOI: https://doi.org/10.1007/BFb0024126

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-57198-8

  • Online ISBN: 978-3-540-47949-9

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