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Anionic polymerizations of non-polar monomers involving lithium

  • Ronald N. Young
  • Roderic P. Quirk
  • L. J. Fetters
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 56)

Abstract

This article deals with developments in the field of anionic polymerization of nonpolar monomers by the use of the lithium counter-ion. The topics discussed include structure and bonding of organolithium compounds, the initiation and propagation reactions in hydrocarbon solvents, the influence of polar co-solvents on chain propagation, the stereochemistry of polydienes and chain end functionalization. Furthermore, the bonding energies of organolithium aggregates are discussed with regard to the identity of the active species in the initiation and propagation events.

Keywords

Active Center Lewis Base Lithium Atom Anionic Polymerization Hydrocarbon Solvent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1984

Authors and Affiliations

  • Ronald N. Young
    • 1
  • Roderic P. Quirk
    • 2
  • L. J. Fetters
    • 3
  1. 1.The Department of ChemistryThe University of SheffieldSheffield
  2. 2.Michigan Molecular InstituteMidlandU.S.A.
  3. 3.The Institute of Polymer ScienceThe University of AkronAkronU.S.A.

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