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Anionic Polymerization pp 1–90Cite as

Anionic polymerizations of non-polar monomers involving lithium

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 56))

Abstract

This article deals with developments in the field of anionic polymerization of nonpolar monomers by the use of the lithium counter-ion. The topics discussed include structure and bonding of organolithium compounds, the initiation and propagation reactions in hydrocarbon solvents, the influence of polar co-solvents on chain propagation, the stereochemistry of polydienes and chain end functionalization. Furthermore, the bonding energies of organolithium aggregates are discussed with regard to the identity of the active species in the initiation and propagation events.

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Author information

Author notes

  1. Roderic P. Quirk

    Present address: The Institute of Polymer Science, The University of Akron, 44325, Akron, Ohio, U.S.A.

  2. L. J. Fetters

    Present address: Corporate Research-Science Laboratories, Exxon Research and Engineering Co., 08801, Clinton Township, Annandale, N.J., U.S.A.

Authors and Affiliations

  1. The Department of Chemistry, The University of Sheffield, S3 7HF, Sheffield, GB

    Ronald N. Young

  2. Michigan Molecular Institute, 1910 St. Andrews Drive, 48640, Midland, Michigan, U.S.A.

    Roderic P. Quirk

  3. The Institute of Polymer Science, The University of Akron, 44325, Akron, Ohio, U.S.A.

    L. J. Fetters

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  1. Ronald N. Young
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  2. Roderic P. Quirk
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  3. L. J. Fetters
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© 1984 Springer-Verlag

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Young, R.N., Quirk, R.P., Fetters, L.J. (1984). Anionic polymerizations of non-polar monomers involving lithium. In: Anionic Polymerization. Advances in Polymer Science, vol 56. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0024120

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  • DOI: https://doi.org/10.1007/BFb0024120

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-12792-5

  • Online ISBN: 978-3-540-38736-7

  • eBook Packages: Springer Book Archive

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