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Optically active synthetic polymers containing pendant carbazolyl groups

  • Emo Chiellini
  • Roberto Solaro
  • Giancarlo Galli
  • Anthony Ledwith
Conference paper
  • 140 Downloads
Part of the Advances in Polymer Science book series (POLYMER, volume 62)

Abstract

Optically active polymers containing carbazole groups may be synthesised by polymerisation of intrinsically optically active carbazole-containing monomers or by copolymerisation of a variety of optically active co-monomers with nonchiral carbazole-containing monomers. Full details are given and it is concluded that the second method is most useful, not least because it permits a wider variation in polymer backbone structures. U.V. absorption fluorescence emission, NMR, and circular dichroism spectra are reported in detail and help to establish a correlation between photophysical behaviour with both primary and secondary structural features of the polymers.

Keywords

Circular Dichroism Active Polymer Excimer Emission Induce Circular Dichroism Carbazole Derivative 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1984

Authors and Affiliations

  • Emo Chiellini
    • 1
    • 2
  • Roberto Solaro
    • 2
    • 3
  • Giancarlo Galli
    • 2
    • 3
  • Anthony Ledwith
    • 4
  1. 1.Instituto di Chimica Generale, Facoltà di IngegneriaUniversità di PisaItaly
  2. 2.Centro CNR Macromolecole Stereordinate Otticamente AttiveItaly
  3. 3.Istituto di Chimica Organica IndustrialeUniversità di PisaItaly
  4. 4.Department of Inorganic, Physical and Industrial ChemistryUniversity of LiverpoolLiverpoolUK

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