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Rheokinetics of curing

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Polymer Compositions Stabilizers/Curing

Part of the book series: Advances in Polymer Science ((POLYMER,volume 101))

Abstract

The mechanisms and variations of rheological properties of network-forming polymers are considered. The variation in the relaxation state during curing determines which rheological method is to be employed at different stages of the process. In the flow region before the gelpoint, the viscosity at shear flow is the most informative and easily determined parameter, while after the gelpoint in the region of rubbery or glassy state, the components of dynamic modulus are more informative. Viscometric investigations show that sometimes microgels are formed in the reactive system before the gelpoint. Microgels represent branched and partly crosslinked molecules of the size of colloid particles.

The rheokinetic phenomenology of curing is associated with the structure and covers a wide range of polymers which form cured materials. The universality of the mathematical description of rheokinetics of curing of different products indicates that the physico-chemical phenomena associated with the formation of crosslinked structures are general.

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  1. Research Institute of Plastics, Perovskii pr. 35, 111112, Moscow E-112, USSR

    A. Ya. Malkin & S. G. Kulichikhin

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Malkin, A.Y., Kulichikhin, S.G. (1991). Rheokinetics of curing. In: Polymer Compositions Stabilizers/Curing. Advances in Polymer Science, vol 101. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0018003

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  • DOI: https://doi.org/10.1007/BFb0018003

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