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Bases of the axiomatic theory of addition polymerization

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Theories and Mechanism of Phase Transitions, Heterophase Polymerizations, Homopolymerization, Addition Polymerization

Part of the book series: Advances in Polymer Science ((POLYMER,volume 112))

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Abstract

A new qualitative quantum-chemical concept of the elementary act of addition polymerization has been proposed as the development of the polymerization theory. An extensive set of various data on the kinetics and the mechanism of polymer structure controlling has been found to have a new explanation from an uniform viewpoint. This concept is developed in the framework of the axiomatic approach to the general polymerization theory and is based on five postulates, namely: the principle of the intermediate, the principle of intermediate cyclicity, the principle of correspondence, the principle of local symmetry and the spin exclusion principle.

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Authors and Affiliations

  1. The Institute of Macromolecular Compounds of the Russian Academy of Sciences, St. Petersburg, Russia

    V. V. Shamanin

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© 1994 Springer-Verlag

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Shamanin, V.V. (1994). Bases of the axiomatic theory of addition polymerization. In: Theories and Mechanism of Phase Transitions, Heterophase Polymerizations, Homopolymerization, Addition Polymerization. Advances in Polymer Science, vol 112. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0017983

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  • DOI: https://doi.org/10.1007/BFb0017983

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  • Print ISBN: 978-3-540-57236-7

  • Online ISBN: 978-3-540-47989-5

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