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Polybenzoxazine Alloys

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Part of the book series: Engineering Materials ((ENG.MAT.))

Abstract

Polybenzoxazine is a class of high-performance materials possesses many intriguing characteristics. The ability of alloying with other minor components is one of the crucial properties for this novel kind of thermosetting, i.e., the properties of the rendered alloys and blends could be tailor-made to meet the requirements of any application. In this chapter, the reviews of the polybenzoxazine alloys in the aspects of some important characteristics (such as thermal and mechanical properties) were dedicated.

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References

  1. Holly FW, Cope AC (1944) Condensation products of aldehydes and ketones with o-Aminobenzyl alcohol and o-Hydroxybenzylamine. J Am Chem Soc 66:1875–1879

    Article  CAS  Google Scholar 

  2. Liu J, Ishida H (1996) A new class of phenolic resins with ring-opening polymerization. The polymeric materials encyclopedia. In: Salamone JC (ed), CRC Press, Florida, pp 484–494

    Google Scholar 

  3. Nair CPN (2004) Advances in addition-cure phenolic resins. Prog Polym Sci 29:401–498

    Article  CAS  Google Scholar 

  4. Ghosh NN, Kiskan B, Yagci Y (2007) New high performance thermosetting resins: synthesis and properties. Prog Polym Sci 32:1344–1391

    Article  CAS  Google Scholar 

  5. Yagci Y, Kiskan B, Ghosh NN (2009) Recent advancement on polybenzoxazine—a newly developed high performance thermoset. J Polym Sci Part A: Polym Chem 47:5565–5576

    Article  CAS  Google Scholar 

  6. Endo T, Sudo A (2009) Development and application of novel ring-opening polymerizations to functional networked polymers. J Polym Sci: Part A: Polym Chem 47:4847–4858

    Article  CAS  Google Scholar 

  7. Kumar KSS, Nair CPR (2010) Polybenzoxazines: chemistry and properties, iSmithers Rapra Publishing, England

    Google Scholar 

  8. Ishida H (1996) Process for preparation of benzoxazine compounds in solventless systems. US Patent 5,543,516

    Google Scholar 

  9. Ning X, Ishida H (1994) Phenolic materials via ring-opening polymerization: synthesis and characterization of bisphenol-A based benzoxazines and their polymers. J Polym Sci Part B: Polym Phys 32:921–927

    Article  CAS  Google Scholar 

  10. Shen SB, Ishida H (1996) Development and characterization of high-performance polybenzoxazine composites. Polym Compos 17:710–719

    Article  CAS  Google Scholar 

  11. Shen SB, Ishida H (1999) Dynamic mechanical and thermal characterization of high-performance polybenzoxazines. J Polym Sci Part B: Polym Phys 37:3257–3268

    Article  CAS  Google Scholar 

  12. Ishida H, Allen DJ (1996) Physical and mechanical characterization of near-zero shrinkage polybenzoxazines. J Polym Sci Part B: Polym Phys 34:1019–1030

    Article  CAS  Google Scholar 

  13. Ishida H, Low HY (1997) A study on the volumetric expansion of benzoxazine-based phenolic resin. Macromolecules 30:1099–1106

    Article  CAS  Google Scholar 

  14. Wang YX, Ishida H (2002) Development of low-viscosity benzoxazine resins and their polymers. J Appl Polym Sci 86:2953–2966

    Article  CAS  Google Scholar 

  15. Ishida H, Rodriquez Y (1995) Curing kinetics of a new benzoxazine-based phenolic resin by differential scanning calorimetry. Polymer 36:3151–3158

    Article  CAS  Google Scholar 

  16. Rimdusit S, Bangsen W, Kasemsiri P (2011) Chemorheology and thermomechanical characteristics of benzoxazine-urethane copolymers. J Appl Polym Sci 1321:3669–3678

    Article  Google Scholar 

  17. Rimdusit S, Kunopast P, Dueramae I (2011) Thermomechanical properties of arylamine-based benzoxazine resins alloyed with epoxy resin. Polym Eng Sci 51:1797–1807

    Article  CAS  Google Scholar 

  18. Kumar KSS, Nair CPR, Ninan KN (2009) Investigations on the cure chemistry and polymer properties of benzoxazine–cyanate ester blends. Eur Polym J 45:494–502

    Article  CAS  Google Scholar 

  19. Rimdusit S, Ishida H (2000) Development of new class of electronic packaging materials based on ternary systems of benzoxazine, epoxy, and phenolic resins. Polymer 41:7941–7949

    Article  CAS  Google Scholar 

  20. Takeichi T, Guo Y, Agag T (2000) Synthesis and characterization of poly(urethane-benzoxazine) films as novel type of polyurethane/phenolic resin composites. J Polym Sci-A 38:4165–4176

    Article  CAS  Google Scholar 

  21. Rimdusit S, Pirstpindvong S, Tanthapanichakoon W, Damrongsakkul S (2005) Toughening of polybenzoxazine by alloying with urethane prepolymer and flexible epoxy: a comparative study. Polym Eng Sci 45(3):288–296

    Article  CAS  Google Scholar 

  22. Takeichi T, Guo Y (2001) Preparation and properties of poly(urethane-benzoxazine)s based on monofunctional benzoxazine monomer. Polymer J 33(5):437–443

    Article  CAS  Google Scholar 

  23. Rimdusit S, Ishida H (2000) Synergism and multiple mechanical relaxations observed in ternary systems based on benzoxazine, epoxy, and phenolic resins. J Polym Sci Pol Phys 38:1687–1698

    Article  CAS  Google Scholar 

  24. Rimdusit S, Mongkhonsi T, Kamonchaivanich P, Sujirot K, Tiptipakorn S (2008) Effects of polyol molecular weight on properties of benzoxazine-urethane polymer alloys. Polym Eng Sci 48:2238–2246

    Article  CAS  Google Scholar 

  25. Su YC, Kuo SW, Yei DR, Xu H, Chang FC (2003) Thermal properties and hydrogen bonding in polymer blend of polybenzoxazine/poly(N-vinyl-2-pyrrolidone). Polymer 44:2187–2191

    Article  CAS  Google Scholar 

  26. Huang JM, Yang SJ (2005) Studying the miscibility and thermal behavior of polybenzoxazine/poly(3-caprolactone) blends using DSC, DMA, and solid state 13C NMR spectroscopy. Polymer 46:8068–8078

    Article  CAS  Google Scholar 

  27. Ishida H, Lee YH (2001) Synergism observed in polybenzoxazine and poly(ε-caprolactone) blends by dynamic mechanical and thermogravimetric analysis. Polymer 42(16):6971–6979

    Article  CAS  Google Scholar 

  28. Zheng S, Lu H, Guo Q (2004) Thermosetting blends of polybenzoxazine and poly(ε-caprolactone): phase behavior and intermolecular specific interactions. Macromol Chem Phys 205(11):1547–1558

    Article  CAS  Google Scholar 

  29. Taşdelen-Yücedaǧ Ç, Erciyes AT (2013) Preparation of oil-modified polycaprolactone and its further modification with benzoxazine for coating purposes. Prog Org Coat 76:137–146

    Article  Google Scholar 

  30. Ardhyananta H, Wahid MH, Sasak M, Agag T, Kawauchi T, Ismail H, Takeichi T (2008) Performance enhancement of polybenzoxazine by hybridization with polysiloxane. Polymer 49:4585–4591

    Article  CAS  Google Scholar 

  31. Ardhyananta H, Kawauchi T, Ismail H, Takeichi T (2009) Effect of pendant group of polysiloxanes on the thermal and mechanical properties of polybenzoxazine hybrids. Polymer 50:5959–5969

    Article  CAS  Google Scholar 

  32. Takeichi T, Agag T, Zeidam R (2001) Preparation and properties of polybenzoxazine/poly(imide-siloxane) alloys: In situ ring-opening polymerization of benzoxazine in the presence of soluble poly(imide-siloxane). J Poym Sci Pol Chem 39:2633–2641

    Article  CAS  Google Scholar 

  33. Tiptipakorn S, Damrongsakkul S, Ando S, Hemvichian K, Rimdusit S (2007) Thermal degradation behaviors of polybenzoxazine and silicon-containing polyimide blends. Polym Degrad Stabil 92(7):1265–1278

    Article  CAS  Google Scholar 

  34. Takeichi T, Guo Y, Rimdusit S (2005) Performance improvement of polybenzoxazine by alloying with polyimide: effect of preparation method on the properties. Polymer 46:4909–4916

    Article  CAS  Google Scholar 

  35. Rimdusit S, Jubsilp C (2007) Polymer from anhydride modified polybenzoxazine. Thailand Patent pending. Issue Number 5543516

    Google Scholar 

  36. Jubsilp C, Takeichi T, Rimdusit S (2010) Property enhancement of polybenzoxazine modified with dianhydride. Polym Degrad Stabil 96(6):1047–1053

    Article  Google Scholar 

  37. Tuzun A, Kiskan B, Alemdar N, Erciyes AT, Yagci Y (2010) Benzoxazine containing polyester thermosets with improved adhesion and flexibility. J Polym Sci Polym Chem 48:4279–4284

    Article  CAS  Google Scholar 

  38. Jubsilp C, Ramsiri B, Rimdusit S (2012) Effects of aromatic carboxylic dianhydrides on thermomechanical properties of polybenzoxazine-dianhydride copolymers. Polym Eng Sci 52(8):1640–1648

    Article  CAS  Google Scholar 

  39. Nour-Eddine EM, Yuan Q, Huang F (2012) Investigation of curing and thermal behavior of benzoxazine and lignin mixtures. J Appl Polym Sci 125:1773–1781

    Article  CAS  Google Scholar 

  40. Emranul Haque HM, Islam Z, Kawauchi T, Takeichi T (2012) Preparation and properties of polybenzoxazine/lignin alloy. Adv Mater Process Technol 217–219:571–577

    Google Scholar 

  41. Ishida H (1999) Composition for forming high thermal conductivity polybenzoxazine-based material and method. US Patent 5900447

    Google Scholar 

  42. Ishida H, Rimdusit S (2001) Ternary systems of benzoxazine, epoxy, and phenolic resins. US Patent 6207786

    Google Scholar 

  43. Chen LC (2010) Halogen-free varnish and prepreg thereof. US patent 7842401

    Google Scholar 

  44. Kim SK, Kim KH, Park JO, Kim K, Ko T, Choi SW, Pak C, Chang H, Lee JC (2013) Highly durable polymer electrolyte membranes at elevated temperature: Cross-linked copolymer structure consisting of poly(benzoxazine) and poly(benzimidazole). J Power Sour 226:346–353

    Google Scholar 

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Correspondence to Sarawut Rimdusit .

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Rimdusit, S., Jubsilp, C., Tiptipakorn, S. (2013). Polybenzoxazine Alloys. In: Alloys and Composites of Polybenzoxazines. Engineering Materials. Springer, Singapore. https://doi.org/10.1007/978-981-4451-76-5_2

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