Abstract
Supercapacitors (SCs) are energy storage devices with high power density and robust charge/discharge life cycles. The high power density of these energy storage devices makes them attractive storage devices in conjunction with other reversible electrical energy storage devices such as batteries and conventional capacitors. The common SCs are made of nanostructured carbonous electrode materials, which are limited with their relatively lower operating window and specific energy densities. Nanostructured metal oxide based carbonous composites are widely explored to overcome carbonous SCs. Rare earth (RE) oxides such as Nd2O3, Y2O3, and Eu2O3 are used in conjunction with carbonous/conducting polymers matrix for high specific density and operating voltage supercapacitors. The high band gap of RE oxides assists in achieving higher operating voltage window. The article will review the current status of RE oxide based supercapacitors and their physical properties in conjunction with underlying physical principles.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Liu, J., Wong, C.P.: Recent advances in high-k nanocomposite materials for embedded capacitor applications. IEEE Trans. Dielectr. Electr. Insul. 15(5), 1322–1328 (2008)
Li, J.Y., Zhang, L., Ducharme, S.: Electric energy density of dielectric nanocomposite. Appl. Phys. Lett. 90(13), 132901 (2017)
Saha, S.K.: Nanodielectrics with giant permittivity. Bull. Mater. Sci. 31(3), 473–477 (2008)
Gidwani, M., Bhagwani, A., Rohra, N.: Supercapacitors: the near future of batteries. Int. J. Eng. Inundations 4, 22–27 (2014)
Bikky, R.: Fabrication and Characterization of Polymer-based High-K Nanodielectrics for Embedded Capacitor Applications. Dissertation University of Houston (2010)
Kotz, R., Carlen, M.: Principles and applications of electrochemical capacitors. Electrochim. Acta 45(15-16), 2483–2498 (2000)
Halper, M.S., Ellenbogen, J.C.: Supercapacitors: A Brief Overview. The MITRE Corporation, McLean, Virginia, USA, pp. 1–34 (2006)
Conway, B.: Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications. Kluwer-Plenum (1999)
Burke, A.: Ultracapacitors: why, how, and where is the technology. J. Power Sources 91(1), 37–50 (2000)
Maxwell Technologies, Inc. (https://www.maxwell.com/)
Berenguer, R.: Trends and Research Challenges in Supercapacitors (2015)
Patrice, S., Gogotsi, Y.: Materials for electrochemical capacitors. Nat. Mater. 7(11), 845 (2008)
Majumder, M., Choudhary, R.B., Thakur, A.K., Rout, C.S., Gupta, G.: Rare earth metal oxide (RE2O3, RE = Nd, Gd, and Yb) incorporated polyindole composites: gravimetric and volumetric capacitive performance for supercapacitor applications. New J. Chem. 42(7), 5295–5308 (2018)
Bamidele, Y., Peng, C., George, Z.C.: Redox electrolytes in supercapacitors. J. Electrochem. Soc. 162(5), A5054–A5059 (2015)
Snook, G.A., Kao, P., Best, A.S.: Conducting-polymer-based supercapacitor devices and electrodes. J. Power Sources 196(1), 1–12 (2012)
Li, H.: Effect Nd2O3 content on electrochemical performance of polyaniline/Nd2O3 composites. Polym. Adv. Technol. 25(10), 1163–1168 (2014)
Majumder, M.: Impact of rare-earth metal oxide (Eu2O3) on the electrochemical properties of a polypyrrole/CuO polymeric composite for supercapacitor applications. RSC Adv. 7(32), 20037–20048 (2017)
Thakur, A.K.: In-situ integration of waste coconut shell derived activated carbon/polypyrrole/rare earth metal oxide (Eu2O3): a novel step towards ultrahigh volumetric capacitance. Electrochim. Acta 251, 532–545 (2017)
Shiri, H.M., Ehsani, A., Khales, M.J.: Electrochemical synthesis of Sm2O3 nanoparticles: Application in conductive polymer composite films for supercapacitors. J. Colloid Interface Sci. 505, 940–946 (2017)
Nadarajan, A., Tin, Pan G., Thomas, C.K.Y.: The exploration of Lanthanum based perovskites and their complementary electrolytes for the supercapacitor applications. Results Phys. 7, 920–926 (2017)
Dongyang, D.: Cerium oxide nanoparticles/multi-wall carbon nanotubes composites: facile synthesis and electrochemical performances as supercapacitor electrode materials. Physica E 86, 284–291 (2017)
Shiri, H.M., Ehsani, A.: Pulse electrosynthesis of novel wormlike gadolinium oxide nanostructure and its nanocomposite with conjugated electroactive polymer as a hybrid and high efficient electrode material for energy storage device. J. Colloid Interface Sci. 484, 70–76 (2016)
Naderi, H.R.: Sonochemical preparation of a ytterbium oxide/reduced graphene oxide nanocomposite for supercapacitors with enhanced capacitive performance. RSC Adv. 6(56), 51211–51220 (2016)
Wang, Y.: Mesoporous transition metal oxides for supercapacitors. Nanomaterials 5(4), 1667–1689 (2015)
Zheng, J.P., Cygan, P.J., Jow, T.R.: Hydrous ruthenium oxide as an electrode material for electrochemical capacitors. J. Electrochem. Soc. 142(8), 2699–2703 (1995)
Li, H., Wang, R., Cao, R.: Physical and electrochemical characterization of hydrous ruthenium oxide/ordered mesoporous carbon composites as supercapacitor. Microporous Mesoporous Mater. 111(1–3), 32–38 (2008)
Devaraj, S.: Mesoporous MnO2 and its capacitive behavior. Electrochem. Solid-State Lett. 15(4), A57–A59 (2012)
Zhi and Jian: Highly ordered metal oxide nanorods inside mesoporous silica supported carbon nanomembranes: High performance electrode materials for symmetrical supercapacitor devices. J. Phys. Chem. C 119(16), 8530–8536 (2015)
Yang, M.: Mesoporous slit-structured NiO for high-performance Pseudocapacitors. Phys. Chem. Chem. Phys. 14(31), 11048–11052 (2012)
Wang, X.: Cryogel synthesis of hierarchical interconnected macro-/mesoporous Co3O4 with superb electrochemical energy storage. J. Phys. Chem. C 116(7), 4930–4935 (2012)
Lang, J., Yan, X., Xue, Q.: Facile preparation and electrochemical characterization of cobalt oxide/multi-walled carbon nanotube composites for supercapacitors. J. Power Sources 196(18), 7841–7846 (2011)
Acknowledgements
Author Ajay Tiwari highly acknowledges UGC-DAE Consortium for financial assistance under the project CRS-M-221 for the present work.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Tiwari, A., Dixit, A. (2020). Rare Earth Oxides Based Composites for High Voltage Supercapacitors Applications: A Short Review. In: Deb, D., Dixit, A., Chandra, L. (eds) Renewable Energy and Climate Change. Smart Innovation, Systems and Technologies, vol 161. Springer, Singapore. https://doi.org/10.1007/978-981-32-9578-0_1
Download citation
DOI: https://doi.org/10.1007/978-981-32-9578-0_1
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-32-9577-3
Online ISBN: 978-981-32-9578-0
eBook Packages: EngineeringEngineering (R0)