Abstract
The previous two chapters dealt with establishing a sound understanding of zinc-related physical and electrochemical processes, with a special focus on controlling electrodeposition in order to achieve optimal performance in the zinc half-cell. A similar approach can be taken for in-depth study of the bromine half-cell, with the aim of developing novel strategies and/or adapting existing methods of optimizing the Br–/Br2 redox to suit the Zn/Br electrochemical environment, thereby significantly improving Zn/Br system performance. This chapter reviews literature pertaining to relevant studies of reactions at the bromine-side electrode (both for within the Zn/Br system as well as different but related environments) to establish strong understanding of the fundamental physical and electrochemical processes that occur during charge and discharge phases of the battery. Materials challenges for conventional Zn/Br systems are highlighted and we review the viability of opportunities to improve electrode functionality through methods such as strategic catalyst doping leading to enhanced electrochemical performance.
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References
White RE (1983) A model of the bromine/bromide electrode reaction at a rotating disk electrode. J Electrochem Soc 130:1096. doi:10.1149/1.2119890
Rubinstein I (1981) Electrode kinetics of the Br 2/Br- couple. J Phys Chem 85:1899–1906
Cooper WD, Parsons R (1970) Kinetics of the bromine/bromide electrode on platinum in aqueous sulphuric acid. Trans Faraday Soc 66:1698. doi:10.1039/tf9706601698
Llopis J, Và zquez M (1962) Study of the impedance of a platinum electrode in the system Br 2/Br– (HClO4, aq.). I. Influence of the surface state. Electrochim Acta 6:167–176. doi:10.1016/0013-4686(62)87034-0
Llopis J, Vazquez M (1962) Study of the impedance of a platinum electrode in the system Br 2/Br– (HClO4, aq.)—II. Mechanism of the electrode reaction. Electrochim Acta 6:177–183. doi:10.1016/0013-4686(62)87035-2
Kautek W (1999) In situ investigations of bromine-storing complex formation in a zinc-flow battery at gold electrodes. J Electrochem Soc 146:3211–3216. doi:10.1149/1.1392456
Faita G, Fiori G, Mussini T (1968) Electrochemical processes of the bromine/bromide system. Electrochim Acta 13:1765–1772. doi:10.1016/0013-4686(68)80084-2
Vogel I, Möbius A (1991) On some problems of the zinc—bromine system as an electric energy storage system of higher efficiency—I. Kinetics of the bromine electrode. Electrochim Acta 36:1403–1408. doi:10.1016/0013-4686(91)85326-3
Mastragostino M, Gramellini C (1985) Kinetic study of the electrochemical processes of the bromine/bromine aqueous system on vitreous carbon electrodes. Electrochim Acta 30:373–380
Janssen LJJ, Hoogland JG (1970) Mechanism of bromine evolution at a graphite electrode. Electrochim Acta 15:1677–1683. doi:10.1016/0013-4686(70)80088-3
Cathro KJ (1986) Zinc-bromine batteries for energy storage applications: volume 541 of end of grant report. Department of Resources and Energy, Canberra
Fabjan C, Hirss G (1986) On the kinetics and mechanism of bromine/bromide redox electrodes. Dechema Monogr 102:149–161
Suresh S, Kesavan T, Munaiah Y et al (2014) Zinc–bromine hybrid flow battery: effect of zinc utilization and performance characteristics. RSC Adv 4:37947. doi:10.1039/C4RA05946H
Cathro KJ, Cedzynska K, Constable DC, Hoobin PM (1986) Selection of quaternary ammonium bromides for use in zinc/bromine cells. J Power Sources 18:349–370. doi:10.1016/0378-7753(86)80091-X
Eustace DJ (1980) Bromine complexation in zinc-bromine circulating batteries. J Electrochem Soc 127:528–532. doi:10.1149/1.2129706
Pichierri F (2011) Structure and bonding in polybromide anions Br–(Br 2)n (n = 1–6). Chem Phys Lett 515:116–121. doi:10.1016/j.cplett.2011.09.003
Easton ME, Ward AJ, Hudson T et al (2015) The formation of high-order polybromides in a room-temperature ionic liquid: from monoanions ([Br 5]–to [Br11]–) to the isolation of [PC16H36]2[Br24] as determined by van der Waals Bonding Radii. Chem Eur J 21:2961–2965. doi:10.1002/chem.201404505
Blöchl PE (1994) Projector augmented-wave method. Phys Rev B 50:17953–17979. doi:10.1103/PhysRevB.50.17953
Kresse G (1999) From ultrasoft pseudopotentials to the projector augmented-wave method. Phys Rev B 59:1758–1775. doi:10.1103/PhysRevB.59.1758
Kresse G, Furthmüller J (1996) Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B: Condens Matter 54:11169–11186
Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77:3865–3868. doi:10.1103/PhysRevLett.77.3865
Ridgway P, Cho KT, Battaglia VS, et al (2011) Redox kinetics of the bromine-bromide reaction for flow batteries. In: 220th ECS meeting and electrochemical energy summit
Will FG, Iacovangelo CD, Jackowski JS, Secor FW (1976) Assessment of zinc-bromine battery for utility load levelling: final report (DOE Contract No. EY-76-C-02-2950)
Kautek W, Conradi A, Fabjan C, Bauer G (2001) In situ FTIR spectroscopy of the Zn–Br battery bromine storage complex at glassy carbon electrodes. Electrochim Acta 47:815–823. doi:10.1016/S0013-4686(01)00762-9
Bauer G, Drobits J, Fabjan C et al (1997) Raman spectroscopic study of the bromine storing complex phase in a zinc-flow battery. J Electroanal Chem 427:123–128. doi:10.1016/S0022-0728(96)04992-3
Conway BE, Phillips Y, Qian SY (1995) Surface electrochemistry and kinetics of anodic bromine formation at platinum. J Chem Soc Faraday Trans 91:283. doi:10.1039/ft9959100283
Mastragostino M, Valcher S, Lazzari P (1981) Mechanism of bromide ion oxidation on Pt electrode in CH2Cl2. J Electroanal Chem Interfacial Electrochem 126:189–198. doi:10.1016/S0022-0728(81)80428-7
Iwasita T, Giordano MC (1969) Kinetics of the bromine-tribromide-bromide redox processes on platinum electrodes in acetonitrile solutions. Electrochim Acta 14:1045–1059. doi:10.1016/0013-4686(69)85038-3
Dryhurst G, Elving PJ (1967) Electrooxidation of halides at pyrolytic graphite electrode in aqueous and acetonitrile solutions. Anal Chem 39:606–615. doi:10.1021/ac60250a014
Tucker MC, Cho KT, Weber AZ et al (2014) Optimization of electrode characteristics for the Br 2/H2 redox flow cell. J Appl Electrochem 45:11–19. doi:10.1007/s10800-014-0772-1
Yoneyama H, Laitinen HA (1977) Oxidation of bromide ion on tin oxide electrodes. J Electroanal Chem Interfacial Electrochem 75:647–663. doi:10.1016/S0022-0728(77)80206-4
Cathro KJ, Cedzynska K, Constable DC (1987) Preparation and performance of plastic-bonded-carbon bromine electrodes. J Power Sources 19:337–356. doi:10.1016/0378-7753(87)87009-X
Lex PJ, Matthews JF (1992) Recent developments in zinc/bromine battery technology at Johnson controls. In: IEEE 35th international power sources symposium. IEEE, pp 88–92
Munaiah Y, Dheenadayalan S, Ragupathy P, Pillai VK (2013) High performance carbon nanotube based electrodes for zinc bromine redox flow batteries. ECS J Solid State Sci Technol 2:M3182–M3186. doi:10.1149/2.024310jss
Singh P, Jonshagen B (1991) Zinc bromine battery for energy storage. J Power Sources 35:405–410. doi:10.1016/0378-7753(91)80059-7
Munaiah Y, Suresh S, Dheenadayalan S et al (2014) Comparative electrocatalytic performance of single-walled and multiwalled carbon nanotubes for zinc bromine redox flow Batteries. J Phys Chem C 118:14795–14804. doi:10.1021/jp503287r
Cedzynska K (1995) Properties of modified electrolyte for zinc-bromine cells. Electrochim Acta 40:971–976. doi:10.1016/0013-4686(94)00372-8
Cedzynska K (1989) Some properties of zinc-bromine cell electrolytes containing symmetrical ammonium bromides. Electrochim Acta 34:1439–1442. doi:10.1016/0013-4686(89)87185-3
Donepudi VS (1984) Electrochemical calorimetry of the zinc and bromine electrodes in zinc-bromine and zinc-air batteries. J Electrochem Soc 131:1477–1485. doi:10.1149/1.2115877
Nguyen TV, Kreutzer H, Yarlagadda V et al (2013) HER/HOR catalysts for the H2-Br 2 fuel cell system. ECS Trans 53:75–81. doi:10.1149/05307.0075ecst
Zhang R, Stanford TG, Wolters L, Weidner J (2011) Development of non-Pt electrocatalysts towards hydrogen evolution reaction for gas-phase Br. In: Zaghib K, Julien C, Ramani V (eds) 218th ECS meeting: electrochemistry of novel materials for energy storage and conversion (October 10–15, 2010). Las Vegas, pp 169–178
Cho KT, Ridgway P, Weber AZ et al (2012) High performance hydrogen/bromine redox flow battery for grid-scale energy Storage. J Electrochem Soc 159:A1806–A1815. doi:10.1149/2.018211jes
Van Zee J (1983) An analysis of a back fed porous electrode for the Br[sub 2]∕Br[sup −] redox reaction. J Electrochem Soc 130:2003. doi:10.1149/1.2119510
Cameron DS, Cooper SJ, Dodgson IL et al (1990) Carbons as supports for precious metal catalysts. Catal Today 7:113–137. doi:10.1016/0920-5861(90)85012-D
Ge SH, Yi BL, Zhang HM (2004) Study of a high power density sodium polysulfide/bromine energy storage cell. J Appl Electrochem 34:181–185. doi:10.1023/B:JACH.0000009936.82613.ad
Zhao P, Zhang H, Zhou H, Yi B (2005) Nickel foam and carbon felt applications for sodium polysulfide/bromine redox flow battery electrodes. Electrochim Acta 51:1091–1098. doi:10.1016/j.electacta.2005.06.008
Harrison JA, Hermijanto SD (1987) The oxidation of chloride ions and bromide ions on ruthenium dioxide electrodes. J Electroanal Chem Interfacial Electrochem 225:159–175. doi:10.1016/0022-0728(87)80011-6
Maniatakou A, Parsons S, Karaliota A (2007) Photosensitized oxidation of bromide to bromine catalyzed by niobium pentachloride in methanol solution. J Photochem Photobiol A :Chem 192:29–35. doi:10.1016/j.jphotochem.2007.02.032
Gratzel M, Halmann M (1990) Photosensitized oxidation of bromide to bromine with phthalic acid derivatives in aqueous solutions. Solar Energy Mater 20:117–129. doi:10.1016/0165-1633(90)90023-T
Besson M, Gallezot P (2003) Deactivation of metal catalysts in liquid phase organic reactions. Catal Today 81:547–559. doi:10.1016/S0920-5861(03)00153-6
Meille V (2006) Review on methods to deposit catalysts on structured surfaces. Appl Catal A: Gen 315:1–17. doi:10.1016/j.apcata.2006.08.031
Qu L, Dai L (2005) Substrate-enhanced electroless deposition of metal nanoparticles on carbon nanotubes. J Am Chem Soc 127:10806–10807. doi:10.1021/ja053479+
Rui X, Parasuraman A, Liu W et al (2013) Functionalized single-walled carbon nanotubes with enhanced electrocatalytic activity for redox reactions in vanadium bromide redox flow batteries. Carbon 64:464–471. doi:10.1016/j.carbon.2013.07.099
Kumar K, Margerum DW (1987) Kinetics and mechanism of general-acid-assisted oxidation of bromide by hypochlorite and hypochlorous acid. Inorg Chem 26:2706–2711. doi:10.1021/ic00263a030
Ferro S, Orsan C, De Battisti A (2005) The bromine electrode part II: reaction kinetics at polycrystalline Pt. J Appl Electrochem 35:273–278. doi:10.1007/s10800-004-6773-8
Ferro S (2005) The bromine electrode part III: reaction kinetics at highly boron-doped diamond electrodes. J Appl Electrochem 35:279–283. doi:10.1007/s10800-004-6774-7
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Rajarathnam, G.P., Vassallo, A.M. (2016). Bromine-Side Electrode Functionality. In: The Zinc/Bromine Flow Battery. SpringerBriefs in Energy. Springer, Singapore. https://doi.org/10.1007/978-981-287-646-1_5
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