Skip to main content
SpringerLink
Log in
SpringerLink
Log in

Synthesis and Characterization of Calcium Iodate, Monohydrate Crystals Grown in Silica Gel

  • Chapter
  • First Online:
Recent Trends in Physics of Material Science and Technology

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 204))

  • 1511 Accesses

Abstract

Simple gel technique was used to grow single crystals of calcium iodate, monohydrate, by single diffusion method. For the growth of crystals, the optimum conditions were established. Crystals having different morphologies like prismatic and prismatic pyramidal were obtained. Few crystals were opaque, some were translucent and some good quality transparent crystals were obtained. Doping of Cu+2 and Fe+3 was done, to study the effect on structure, thermal and nonlinear optical properties. Cell parameters were obtained from the X-ray diffractograms. Structural analysis was done by using FT-IR spectroscopy. TGA and DTA techniques were used to carry out thermal analysis. Nonlinear optical properties were studied using SHG measurements.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Armington AF, O’Connor JJ et al (1968) Gel growth of cuprous halide crystals. J Cryst Growth 3–4:367–371

    Article  ADS  Google Scholar 

  2. Shitole SJ, Saraf KB et al (2001) Growth and study of some gel grown group II single crystals of iodate. Bull Mater Sci 24(5):461–468

    Article  Google Scholar 

  3. Shitole SJ, Saraf KB et al (2002) Growth, structural and microtopographical studies of calcium Iodate, monohydrate crystals grown by silica gel. Cryst Res Technol 37(5):440–445

    Article  Google Scholar 

  4. Shitole SJ, Saraf KB et al (2007) Spherulitic growth of cadmium iodate in silica gel and its XRD and FTIR analysis. J Adv Sci And Tech 10(I & II):42–55

    Google Scholar 

  5. Joshi MS, Trivedi SG et al (1981) Growth of single crystals of barium iodate and strontium iodate in silica gels. Cryst Res Technol 16(1):19–26

    Google Scholar 

  6. Garud SL, Mahajan NK, Saraf KB et al (2009) Study of gel grown mixed crystals of BaxCa (1–x)(IO3)4. Bull Mater Sci 32(2):187–192

    Article  Google Scholar 

  7. Garud SL, Saraf KB et al (2008) Growth and study of mixed crystals of Ca–Cd iodate. Bull Mater Sci 31(4):639–643

    Article  Google Scholar 

  8. Dennis J, Henisch HK et al (1967) Nucleation and growth of crystals in gels. J Electrochem Soc 114:263–266

    Article  Google Scholar 

  9. Dishovsky N, Boncheva – Maladenova Z et al (1981) Doping of gel-grown Ag2SeO4 single crystals. J Cryst Growth 51(1):147–148

    Article  ADS  Google Scholar 

  10. Dake HC (1938) Quartz family minerals: a handbook for the mineral collector. Whittlesey House, New York

    Google Scholar 

  11. Nassau K et al (1978) The origins of color in minerals. Am Mineral 63:219–229

    Google Scholar 

  12. Saraf KB (1980) Ph. D. thesis, Sardar Patel University, Vallabh Vidyanagar, Gujrat, India

    Google Scholar 

  13. JCPDS card for X-ray diffraction data no. 26, p 1405

    Google Scholar 

  14. Nassau K, Shiever JW, Prescot BE et al (1973) Transition metal iodates. I. Preparation and characterization of the 3d iodates. J Solid State Chem 7:186–204

    Article  ADS  Google Scholar 

  15. Dasent WE, Waddington TC et al (1960) Iodine–oxygen compounds. Part I. infrared spectra and structure of iodates. J Chem Soc 2429–2432

    Google Scholar 

  16. Balicheva TG, Petrova VA et al (1973) Vibrational spectra of the IO3-ion in alkali iodates. J Struct Chem 14(3):424–430

    Article  Google Scholar 

  17. Nyquist RA, Kagal RD et al (1971) Infrared spectra of inorganic compounds. Academic Press, New York

    Google Scholar 

  18. Rocchiccioli C et al (1960) Spectroscopie Moleculaire – Etude Par Spectroscopie d’ Absorption Infrarouge de Quelques Iodates Anhydres et Hydrates. Compt Rend 250(1):1232–1234

    Google Scholar 

  19. Dratovsky M, Pacesova L (1968) Russ Chem Rev 37(4):243–254. doi:10.1070/RC1968v037n04ABEH001631

    Article  ADS  Google Scholar 

  20. Nakamoto K (1970) Infrared spectra of inorganic and coordination compounds, 2nd edn. Wiley-Interscience, New York

    Google Scholar 

  21. Sanyal GS, Nag K et al (1977) Thermal studies on the dimesoperiodates and iodates of Ca (II), Sr (II) and Ba (II) preparation and characterization of hexavalent iodates. J Inorg Chem 39:1127–1130

    Google Scholar 

  22. Chemla DS, Zyss J (1987) Nonlinear optical properties of organic molecules and crystals, vol 1–2. Academic Press, New York

    Google Scholar 

  23. Kurtz SK, Perry TT et al (1968) A powder technique for the evaluation of nonlinear optical materials. J Appl Phys 39(8):3798–3813

    Google Scholar 

  24. Bloembergen N, Armstrong JA, Ducuing J, Pershan PS et al (1962) Interactions between light waves in a nonlinear dielectric. Phys Rev Lett 127:1918–1939

    Google Scholar 

  25. Franken PA, Hill AE, Peters CW, Wernreich G et al (1961) Generation of optical harmonics. Phy Rev Lett 7:118–119

    Google Scholar 

  26. Morosin B, Bergman JG, Crane GR et al (1973) Crystal structure, linear and nonlinear optical properties of Ca (IO3)2·6H2O. Acta Cryst B29:1067–1072

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Electronics, Z. B. Patil College, Dhule, 424002, Maharashtra, India

    S. J. Shitole

Authors
  1. S. J. Shitole
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. J. Shitole .

Editor information

Editors and Affiliations

  1. Bina Nusantara University, Jakarta, Indonesia

    Ford Lumban Gaol

  2. University of Malaya, Kuala Lumpur, Malaysia

    Keshav Shrivastava

  3. Sensors & Nano-Technology Group, CEERI Pilani, Pilani, India

    Jamil Akhtar

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer Science+Business Media Singapore

About this chapter

Cite this chapter

Shitole, S.J. (2015). Synthesis and Characterization of Calcium Iodate, Monohydrate Crystals Grown in Silica Gel. In: Gaol, F., Shrivastava, K., Akhtar, J. (eds) Recent Trends in Physics of Material Science and Technology. Springer Series in Materials Science, vol 204. Springer, Singapore. https://doi.org/10.1007/978-981-287-128-2_15

Download citation

  • DOI: https://doi.org/10.1007/978-981-287-128-2_15

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-287-127-5

  • Online ISBN: 978-981-287-128-2

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics

Search

Navigation