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A Study on the Adsorption of 2,4,6, Trichlorophenol by Palm Kernel Cake

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Abstract

In this study, 2,4,6-trichlorophenol (TCP) adsorption on palm kernel cake (PKC) was examined. The effects of the initial concentration, agitation time, solution temperature and pH on TCP adsorption were examined in batch adsorption studies. The adsorption capacity was positively related to the initial concentration and agitation time and negatively related to the pH and solution temperature. Experimental data indicated that the Langmuir isotherm best fits the data (maximum monolayer adsorption capacity of 22.22 mg/g at 30 °C). The adsorption kinetics followed a pseudo-second-order kinetic model. Analysis of various thermodynamic parameters indicated that the adsorption was non-spontaneous and exothermic, whereas the Elovich equation and the pseudo-second-order kinetic model determined that chemisorption was the rate-controlling step.

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References

  • Anisuzzaman, S. M., Joseph, C. G., Krishnaiah, D., Bono, A., & Ooi, L. C. (2015). Parametric and adsorption kinetic studies of methylene blue removal from simulated textile water using durian (Durio zibethinus Murray) skin. Water Science and Technology, 72(6), 896–907.

    Article  CAS  Google Scholar 

  • Anisuzzaman, S. M., Bono, A., Krishnaiah, D., & Tan, Y. Z. (2016). A study on dynamic simulation of phenol adsorption in activated carbon packed bed column. Journal of King Saud University—Engineering Sciences, 28(1), 47–55.

    Article  Google Scholar 

  • Ahmaruzzaman, M. (2008). Adsorption of phenolic compounds on low-cost adsorbents: A review. Advances in Colloid and Interface Science, 143, 48–67.

    Article  CAS  Google Scholar 

  • Bilgili, M. S. (2006). Adsorption of 4-chlorophenol from aqueous solutions by xad-4 resin: Isotherm, kinetic, and thermodynamic analysis. Journal of Hazardous Materials, 137, 157–164.

    Article  CAS  Google Scholar 

  • Chen, G.-C., Shan, X.-Q., Wang, Y.-S., Wen, B., Pei, Z.-G., Xie, Y.-N., et al. (2009). Adsorption of 2,4,6-trichlorophenol by multi-walled carbon nanotubes as affected by Cu(II). Water Research, 43, 2409–2418.

    Article  CAS  Google Scholar 

  • El-Sayed, G. O. (2011). Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber. Desalination, 272, 225–232.

    Article  CAS  Google Scholar 

  • Fan, J., Zhang, J., Zhang, C., Ren, L., & Shi, Q. (2011). Adsorption of 2,4,6-trichlorophenol from aqueous solution onto activated carbon derived from loosestrife. Desalination, 267, 139–146.

    Article  CAS  Google Scholar 

  • Gao, R., & Wang, J. (2007). Effects of pH and temperature on isotherm parameters of chlorophenols biosorption to anaerobic granular sludge. Journal of Hazardous Materials, 145, 398–403.

    Article  CAS  Google Scholar 

  • Hamdaoui, O., & Naffrechoux, E. (2007). Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon: Part II. Models with more than two parameters. Journal of Hazardous Materials, 147, 401–411.

    Article  CAS  Google Scholar 

  • Hameed, B. H. (2007). Equilibrium and kinetics studies of 2,4,6-trichlorophenol adsorption onto activated clay. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 307, 45–52.

    Article  CAS  Google Scholar 

  • Hameed, B. H., Tan, I. A. W., & Ahmad, A. L. (2009). Preparation of oil palm empty fruit bunch-based activated carbon for removal of 2,4,6-trichlorophenol: Optimization using response surface methodology. Journal of Hazardous Materials, 164, 1316–1324.

    Article  CAS  Google Scholar 

  • Hameed, B. H., Tan, I. A. W., & Ahmad, A. L. (2008). Adsorption isotherm, kinetic modeling and mechanism of 2,4,6-trichlorophenol on coconut husk-based activated carbon. Chemical Engineering Journal, 144, 235–244.

    Article  CAS  Google Scholar 

  • Ho, Y.-S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34, 451–465.

    Article  CAS  Google Scholar 

  • Ho, Y. S., & Ofomaja, A. E. (2005). Kinetics and thermodynamics of lead ion biosorption on palm kernel fibre from aqueous solution. Process Biochemistry, 40, 3455–3461.

    Article  CAS  Google Scholar 

  • Joseph, C. G., Bono, A., Krishnaiah, D., & Soon, K. O. (2007). Sorption studies of methylene blue dye in aqueous solution by optimised carbon prepared from guava seeds (Psidium guajava L.). Journal Materials Science, 13, 83–87.

    Google Scholar 

  • Joseph, C. G., Li Puma, G., Bono, A., Taufiq-Yap, Y. H., & Krishnaiah, D. (2011). Operating parameters and synergistic effects of combining ultrasound and ultraviolet irradiation in the degradation of 2,4,6-trichlorophenol. Desalination, 276, 303–309.

    Article  CAS  Google Scholar 

  • Kara, M., Yuzer, H., Sabah, E., & Celik, M. S. (2003). Adsorption of cobalt from aqueous solutions onto sepiolite. Water Research, 37, 224–232.

    Article  CAS  Google Scholar 

  • Krishnaiah, D., Joseph, C. G., Anisuzzaman, S. M., Daud, M., & Sundang, M. (2017). Removal of chlorinated phenol from aqueous solution utilizing activated carbon derived from papaya (Carica Papaya) seeds. Korean Journal of Chemical Engineering, 34(5), 1377–1384.

    Article  CAS  Google Scholar 

  • Li Puma, G., Bono, A., Krishnaiah, D., & Collin, J. G. (2008). Preparation of titanium dioxide photocatalyst loaded onto activated carbon support using chemical vapor deposition: A review paper. Journal of Hazardous Materials, 157, 209–219.

    Article  CAS  Google Scholar 

  • Mahmoud, D. K., Salleh, M. A. M., & Karim, W. A. (2012). Langmuir model application on solid-liquid adsorption using agricultural wastes: Environmental application review. Journal of Purity, Utility Reaction and Environment, 1, 200–229.

    Google Scholar 

  • Panday, K. K., Prasad, G., & Singh, V. N. (1986). Use of wollastonite for the treatment of Cu (II) rich effluents. Water, Air, and Soil pollution, 27, 287–296.

    Article  CAS  Google Scholar 

  • Qiu, H., Lv, L., Pan, B., Zhang, Q., Zhang, W., & Zhang, Q. (2009). Critical review in adsorption kinetic models. Journal of Zhejiang University Science A, 10, 716–724.

    Article  CAS  Google Scholar 

  • Radhika, M., & Palanivelu, K. (2006). Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbent—Kinetics and isotherm analysis. Journal of Hazardous Materials, 138, 116–124.

    Article  CAS  Google Scholar 

  • Siva Kumar, N., Woo, H.-S., & Min, K. (2012). Equilibrium and kinetic studies on biosorption of 2,4,6-trichlorophenol from aqueous solutions by Acacia leucocephala bark. Colloids and Surfaces B: Biointerfaces, 94, 125–132.

    Article  Google Scholar 

  • Subramanyam, B., & Das, A. (2009). Linearized and non-linearized isotherm models comparative study on adsorption of aqueous phenol solution in soil. International Journal of Environmental Science and Technology, 6, 633–640.

    Article  CAS  Google Scholar 

  • Tan, I. A., Ahmad, A. L., & Hameed, B. H. (2009). Fixed-bed adsorption performance of oil palm shell-based activated carbon for removal of 2,4,6-trichlorophenol. Bioresource Technology, 100, 1494–1496.

    Article  CAS  Google Scholar 

  • Wang, S.-L., Tzou, Y.-M., Lu, Y.-H., & Sheng, G. (2007). Removal of 3-chlorophenol from water using rice-straw-based carbon. Journal of Hazardous Materials, 147(1–2), 313.

    Article  CAS  Google Scholar 

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Acknowledgements

This research was supported by the Center of Research and Innovation, Universiti Malaysia Sabah (Grant No. FRG0203-SG-1/2010) and is gratefully acknowledged.

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Correspondence to Duduku Krishnaiah .

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Krishnaiah, D., Bono, A., Joseph, C.G., Anisuzzaman, S.M., Venantius, L. (2020). A Study on the Adsorption of 2,4,6, Trichlorophenol by Palm Kernel Cake. In: Yaser, A. (eds) Advances in Waste Processing Technology. Springer, Singapore. https://doi.org/10.1007/978-981-15-4821-5_6

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