Abstract
Fly ash (FA), a fine powder obtained during the combustion of coal at a thermal power station, possesses several environmental issues, including atmosphere contamination and huge land area for dumping. One potential use of FA is as filler in polymers in order to improve their properties and to reduce production costs. Polyvinyl chloride (PVC) is a well-known thermoplastic and the most commonly used polymers in building industries due to its advantageous properties. This study investigated the influences of the FA as filler material on the mechanical properties of PVC/FA composites. PVC in powder form was mixed with addictive substances (Tribasic Lead Sulfate, Normal Lead Stearate, Calcium Stearate, and Stearate Acid) at a temperature of 100 °C. Following this, the FA was added to the mixed PVC in various compositions (0, 8, 10, 20, and 30 phr) and shook. The Hot Press Molding machine fabricated the PVC/FA composites under pressure of 13 MPa at a temperature of 200 °C for 300 s. Tensile and impact tests were carried out in accordance with ASTM D638-02A type IV and ASTM D6110-04, respectively. The results revealed that the incorporation of FA had significantly improved the tensile strength, Young’s Modulus, and the elongation at break of the composites. The composite containing 8 phr FA showed the highest value of the respective properties. Those properties tended to decrease with the increase of FA content. The impact properties also showed a similar phenomenon. The value of impact strength and impact energy for the composite containing 10 phr were found the highest. Scanning electron microscopy images showed that FA particles were precipitated and mechanically interlocked in the PVC matrix. Particle agglomeration was found in the composites containing higher amounts of FA. The study indicates a remarkable potential for FA to produce useful PVC/VA composite.
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References
Anandhan S, Sundar SM, Senthil T, Mahendran A, Shibulal G (2012) Extruded poly (ethylene-co-octene)/fly ash composites–value added products from an environmental pollutant. J Polym Res 19(3):9840
Awad WH, Beyer G, Benderly D, Ijdo WL, Songtipya P, del Mar Jimenez-Gasco M et al (2009) Material properties of nanoclay PVC composites. Polymer 50(8):1857–1867
Bose S, Mahanwar P (2004) Effect of flyash on the mechanical, thermal, dielectric, rheological and morphological properties of filled nylon 6. J Min Mater Charact Eng 3(2):65–89
Deepthi M, Sharma M, Sailaja R, Anantha P, Sampathkumaran P, Seetharamu S (2010) Mechanical and thermal characteristics of high density polyethylene–fly ash cenospheres composites. Mater Des 31(4):2051–2060
Eaves D (2004) Handbook of polymer foams. polimeri 25(6):1–2
Joshi PS, Marathe DS (2018) Experimental investigation of mechanical properties of impact modified polyvinyl chloride-fly ash composites. J Min Mater Charact Eng 7(1):34–47
Khoshnoud P, Abu-Zahra N (2015) Effect of cenosphere fly ash on the thermal, mechanical, and morphological properties of rigid PVC foam composites. J Res Updates Polym Sci 4(1):1
Khoshnoud P, Abu-Zahra N (2018) The effect of particle size of fly ash (FA) on the interfacial interaction and performance of PVC/FA composites. J Vinyl Add Tech 25(2):134–143
Khoshnoud P, Gunashekar S, Jamel MM, Abu-Zahra N (2014) Comparative analysis of rigid PVC foam reinforced with class C and class F fly ash. J Min Mater Charact Eng 2(06):554
Kulkarni M, Bambole V, Mahanwar P (2014) Effect of particle size of fly ash cenospheres on the properties of acrylonitrile butadiene styrene-filled composites. J Thermoplast Compos Mater 27(2):251–267
Kulkarni S (2002) Effects of surface treatments and size of fly ash particles on the compressive properties of epoxy based particulate composites. J Mater Sci 37(20):4321–4326
Nath DCD, Bandyopadhyay S, Boughton P, Yu A, Blackburn D, White C (2010) Chemically modified fly ash for fabricating super-strong biodegradable poly (vinyl alcohol) composite films. J Mater Sci 45(10):2625–2632
Nath DCD, Bandyopadhyay S, Yu A, Zeng Q, Das T, Blackburn D et al (2009) Structure–property interface correlation of fly ash–isotactic polypropylene composites. J Mater Sci 44(22):6078–6089
Parvaiz MR, Mohanty S, Nayak SK, Mahanwar P (2011) Effect of surface modification of fly ash on the mechanical, thermal, electrical and morphological properties of polyetheretherketone composites. Mater Sci Eng, A 528(13–14):4277–4286
Petchwattana N, Covavisaruch S (2013) Effects of rice hull particle size and content on the mechanical properties and visual appearance of wood plastic composites prepared from poly (vinyl chloride). J Bionic Eng 10(1):110–117
Qiao J, Amirkhizi AV, Schaaf K, Nemat-Nasser S (2011) Dynamic mechanical analysis of fly ash filled polyurea elastomer. J Eng Mater Technol 133(1):011016
Rabinovitch EB, Isner JD, Sidor JA, Wiedl DJ (1997) Effect of extrusion conditions on rigid PVC foam. J Vinyl Add Tech 3(3):210–215
Satapathy BK, Das A, Patnaik A (2011) Ductile-to-brittle transition in cenosphere-filled polypropylene composites. J Mater Sci 46(6):1963–1974
Sengupta S, Pal K, Ray D, Mukhopadhyay A (2011) Furfuryl palmitate coated fly ash used as filler in recycled polypropylene matrix composites. Compos B Eng 42(7):1834–1839
Sushma SP, Kumar AK (2014) Hardness and tensile testing of PVC and fly ash composite. In: Advance research and innovations in mechanical, material science, industrial engineering and management-ICARMMIEM, pp 273–277
Thomas N, Eastupy JR, Quirk P (2004) Rigid PVC foam. In: Formulating for sustainability, blowing agent and foaming process
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Nugroho, A.W., Prasetyo, M.K.P., Budiyantoro, C. (2020). Effect of Fly Ash on the Mechanical Properties of Polyvinyl Chloride-Fly Ash Composite. In: Sabino, U., Imaduddin, F., Prabowo, A. (eds) Proceedings of the 6th International Conference and Exhibition on Sustainable Energy and Advanced Materials. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-15-4481-1_63
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DOI: https://doi.org/10.1007/978-981-15-4481-1_63
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