Skip to main content

Prevailing Lead-Free Materials

  • Chapter
  • First Online:
Assembly and Reliability of Lead-Free Solder Joints

Abstract

Lead-containing solders, particularly tin-lead solders, have been widely used in electronics industry for a long time. This is primarily due to a combined merit of low cost, good soldering properties, adequate melting temperature range, and proper physical, mechanical, metallurgical, and fatigue resistance properties. However, the concern about the toxicity of lead has led to an increase in controls and legislation on the use of lead. As a result, the use of lead in non-solder related materials such as gasoline, and paint have been banned for years [1, 2]. More recently, lead containing solders have been banned for use in potable water piping, food and beverage cans and automobile bodies where they were used in repair applications. As to the electronic industry, the concern on lead-containing solder mainly resides in the potential pollution from the landfill. Although the use of lead in solders for electronics assembly has not been completely banned yet, the strong trend of moving toward a green world is driving the industry to develop lead-free solder alternatives with an immense enthusiasm. In this chapter, the status of lead-free developmental works are reviewed and briefly discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 99.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 129.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Lee N-C (1996) Getting ready for lead free solders. European Surface Mount Conference, Brighton, UK

    Google Scholar 

  2. Lee N-C (1999) Lead-free soldering—where the world is going. Advancing Microelectronics magazine, September/October 1999

    Google Scholar 

  3. Lee N-C (2019) Achieving high reliability for lead-free solder joints—materials consideration. SMTA International Conference, Professional Development Course, Rosemont, IL, September 22 2019

    Google Scholar 

  4. Ventura T, Gourlay CM, Nogita K, Nishimura T, Rappaz M, Dahle AK (2007) The influence of 0–0.1wt% Ni on the microstructure and fluidity length of Sn-0.7Cu-xNi. J Electron Mater 37

    Google Scholar 

  5. Sn995 Cobalt-Doped Pb-Free Soldering Alloy. Indium Corporation, Product Data Sheet, 98572

    Google Scholar 

  6. Lee N-C, Liu W (2019) Lead-free solder alloys and solder joints thereof with improved drop impact resistance. US Patent 9,260,768

    Google Scholar 

  7. Lead-free solder with low Cu dissolution. WO 2007/081775 A2

    Google Scholar 

  8. Senju, JP Patent JP5050286 covers 3–5%Ag, 0.5–3% Cu, 0–5% Sb, balance Sn

    Google Scholar 

  9. Iowa State University. Sandia patent. US Patent 5,527,628

    Google Scholar 

  10. Huang B, Hwang H-S, Lee N-C (2008) A compliant and creep resistant SAC-Al(Ni) alloy. APEX, Las Vegas, Nevada, 1–3 April 2008

    Google Scholar 

  11. Masazumi Amagai (Texas Instruments, Japan) (2006) A study of nano particles in snag-based lead free solders for intermetallic compounds and drop test performance. 56th ECTC Proceedings, San Diego, CA, 30 May–2 June 2006. pp 1170–1190

    Google Scholar 

  12. AIM REL22 product data sheet

    Google Scholar 

  13. Date M, Shoji T, Fujiyoshi M, Sato K (2005) Pb-free solder ball with higher impact reliability. Intel Pb-free technology forum, 18–20 July 2005, Penang, Malaysia

    Google Scholar 

  14. Vianco P Low temperature solders. SAND2018-3975C

    Google Scholar 

  15. Lee N-C (2000) Lead-free soldering and low alpha solders for wafer level interconnects. SMTA International

    Google Scholar 

  16. Baggio T (1999) The panasonic mini disk player—Turning a new leaf in a lead-free market. IPCWorks’99, Minneapolis, MN, October 27 1999

    Google Scholar 

  17. El-Daly AA, Swilem Y, Makled MH, El-Shaarawy MG, Abdraboh AM (2009) Thermal and mechanical properties of Sn–Zn–Bi lead-free solder alloys. J Alloys Compd 484:134–142

    Google Scholar 

  18. https://silverprice.org/silver-price-history.html, 5 January 2020

  19. Lee N-C (2017) Choosing solders for the new era: low cost high reliability solder alloys. short course, IMAPS, 9–12 October 2017

    Google Scholar 

  20. Sweatman K (2008) Lead-free alloy alternatives workshop, 1 February 2008

    Google Scholar 

  21. Ventura T, Gourlay CM, Nogita K, Nishimura T, Pappaz M, Dale AK (2007) The influence of 0–0.1 wt.% Ni on the microstructure and fluidity length of Sn-0.7Cu-xNi. J Electron Mater 37

    Google Scholar 

  22. http://link.springer.com/article/10.1007/s11837-015-1595-1

  23. Arfaei B (2016) Third generation Pb free solder alloys: effect of solder composition, volume and PCB surface finish on reliability. Area Consortium, March 2016

    Google Scholar 

  24. Mutuku FM (2016) Effect of processing changes on the microstructure and reliability of new pbfree solder joints: solder composition, cooling rate, and pre-aging. Area Consortium, March 2016

    Google Scholar 

  25. Nowottnick M, Novikov A, Trodler J Processing and reliability of low silver alloys

    Google Scholar 

  26. Nishimura T, Sweatman K, Kita A, Sawada S (2015) A new method of increasing the reliability of lead-free solder. SMTA International, Rosemont, IL, 27 September–1 October 2015

    Google Scholar 

  27. Coyle R, Smetana J, Parker R, Howell K, Sweatman K, Allen A, Benedetto E, Lui W, Silk J (2014) iNEMI PB-free alloy characterization project report: part VII—Thermal fatigue results for low-ag alloys. SMTA International, Rosemont, IL, 28 September–2 October 2014

    Google Scholar 

  28. Coyle R, Parker R, Longgood S, Osterman M, George E, Sweatman K, Howell K, Benedetto E, Allen A, Smetana J, Arnold J (2013) iNEMI lead-free alloy characterization project report: part V—the effect of dwell time on thermal fatigue reliability. SMTA International, Fort Worth, TX, 13–17 October 2013

    Google Scholar 

  29. McKay EG, Nguyen J (2014) Microstructure study of lead-free solder joints reflowed using alternative low silver alloy solder pastes. SMTA International, Rosemont, IL, 28 September–2 October 2014

    Google Scholar 

  30. Lee YJ, Crosbie P, Brown M, Zbrzezny A (2008) Reliability of wafer level chip scale packages (WL-CSP) under dynamic loadings. IEEE ECTC, 2008, Lake Buena Vista, Florida, pp 1782–1786

    Google Scholar 

  31. Lal A, Bradley E, Sharda J (2005) Effect of reflow profiles on the board level drop reliability of Pb-free (SnAgCu) BGA assemblies. IEEE ECTC

    Google Scholar 

  32. Reiff D, Bradley E (2005) A novel mechanical shock test method to evaluate lead-free BGA solder joint reliability. IEEE ECTC

    Google Scholar 

  33. Lim CT, Lim CT, Ang CW, Tan LB, Seah SKW, Wong EH (2003) Drop impact survey of portable electronic products. IEEE ECTC, pp 113–120

    Google Scholar 

  34. Liu W, Lee N-C, Porras A, Ding M, Gallagher A, Huang A, Chen S, Chang J, Lee B (2009). Achieving high reliability low cost lead-free SAC solder joints via Mn Or Ce doping. SMTAI, 4–8 October 2009. pp 920–934

    Google Scholar 

  35. JEITA PG. Leader koji serizawa JEITA 2nd Generation Lead-Free Reflow Solder Paste Standardization Project Group (2013) JEITA’s standardization activity of 2nd generation lead-free solder paste. IPC APEX EXPO, pp S10–01

    Google Scholar 

  36. Daya A, Manian Ramkumar S (2014) Influence of thermal shock on lead free alloy combinations in package on package assemblies. SMTA International, Rosemont, IL, 28 September–2 October 2014

    Google Scholar 

  37. Coyle R, Smetana J, Reed P, Parker R, Allen A, Benedetto E, Howell K, Sweatman K, Longgood S, Arfaei B, Mutuku F (2014) iNEMI PB-free alloy characterization project report: part VIII—thermal fatigue results for high-AG alloys at extended dwell times. SMTA International, Rosemont, IL, 28 September–2 October, 2014

    Google Scholar 

  38. Juarez JM Jr., Robinson M, Heebink J, Snugovsky P, Kosiba E, Kennedy J, Bagheri Z, Suthakaran S, Romansky M (2014) Reliability screening of lower melting point pb-free alloys containing Bi. APEX

    Google Scholar 

  39. Lee JH, Kumar S, Kim HJ, Lee YW, Jeong, Moon T (2014) High thermo-mechanical fatigue and drop impact resistant Ni-Bi doped lead free solder. ECTC, Orlando, FL, 27–30 May 2014. pp 712–716

    Google Scholar 

  40. Geng J, Zhang H, Mutuku F, Lee N-C (2015) Novel lead-free solder alloys development for automotive applications. SMTA International, Rosemont, IL, 27 September–1 October 2015

    Google Scholar 

  41. Parker R, Coyle R, Henshall G, Smetana J, Benedetto E (2012) iNEMI Pb-free alloy characterization project report: part II—thermal fatigue results for two common temperature cycles. SMTAI, Orlando, FL, 14–18 October 2012. pp 348–358

    Google Scholar 

  42. Bradley E, Handwerker CA, Bath J, Parker RD, Gedney RW (2007) Lead-free electronics: iNEMI projects lead to successful manufacturing. Wiley-IEEE, Piscataway

    Google Scholar 

  43. Wengenroth K, Yau Y, Fudala F, Prendergast R, Abys J (2004) Alternative final finishes for PWB. QuickStart Lead-free Workshop, Ft. Lauderdale, FL, 27 July 2004

    Google Scholar 

  44. Horaud W, Leroux S, Frémont H, and Navarro D (2004) PCB materials behaviours towards Humidity. Apex, S07–2, Anaheim, CA, February 2004

    Google Scholar 

  45. Shina S, Harriman L, MacFadden T, Abbott D, Anderson R, Pasquito H, Wilkish G, Kistler M, Pinsky D, Quealy M, Walters K, McCann R, Grusby A (2004) Lead free conversion analysis for multiple pwb/component materials and finishes using quality and reliability testing. Apex, S29-4, Anaheim, CA

    Google Scholar 

  46. Saeki K, Carano M (2004) Next generation organic solderability preservatives (OSP) for lead-free soldering and mixed metal finish PWB’s and BGA substrates. Apex, S10-2, Anaheim, CA

    Google Scholar 

  47. Ray U, Artaki I, Finley DW, Wenger GM, Pan T, Blair HD, Nicholson JM, Vianco PT (1996) Assessment of circuit board surface finishes for electronic assembly with lead-free solders. SMI 96, 10–12 September 1996

    Google Scholar 

  48. Mukadam M, Armendariz N, Aspandiar R, Witkowski M, Alvarez V, Tong A, Phillips B, Long G (2006) Planar microvoiding in lead-free second-level interconnect solder joints. SMTAI, September 2006

    Google Scholar 

  49. Swanson J, Cullen D (2007) Verifying microvoid elimination and prevention via an optimized immersion silver process. APEX, 20–22 February 2007, pp S18-01

    Google Scholar 

  50. Yau Y-H, Wengenroth K, Abys J (2007) A study of planar microvoiding in Pb-free solder joints. APEX, 20–22 February 2007, pp S18-02

    Google Scholar 

  51. Fang JL, Chan DK (2007) The advantages of mildly alkaline immersion silver as a final finish for solderability. APEX, 20–22 February 2007. pp S23–02

    Google Scholar 

  52. Indium Corporation product data sheet on Sn995

    Google Scholar 

  53. Goudarzi V, Brown M, Liu W, Lee N-C, Lee JCB (2013) The second generation shock resistant and thermally reliable low Ag SAC solder doped with Mn. SMTA International, Fort Worth, TX, 13–17 October 2013

    Google Scholar 

  54. Bath J, Nakatsuma M, Wada T, Mori K, Shimokawa K, Shira T, Irisawa A, Garcia R (2013) A study of lead-free, low silver solder alloys with nickel additions. SMTA International, Fort Worth, TX, 13–17 October 2013

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2020 The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Lau, J.H., Lee, NC. (2020). Prevailing Lead-Free Materials. In: Assembly and Reliability of Lead-Free Solder Joints. Springer, Singapore. https://doi.org/10.1007/978-981-15-3920-6_2

Download citation

  • DOI: https://doi.org/10.1007/978-981-15-3920-6_2

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-3919-0

  • Online ISBN: 978-981-15-3920-6

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics